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The Flip-Flop Effect on Anodized Aluminum Oxide Films

  • NANOSCALE AND NANOSTRUCTURED MATERIALS AND COATINGS
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Abstract

A flip-flop effect has been revealed at the anodization of aluminum oxide and subsequent electrochemical deposition of Co/Ni nanoparticles. The angle dependences of the reflection spectra of metallized anodized aluminum oxide films have been measured. Using the conditions of light interference in a thin film, the values of the effective refraction index and film thickness in dependence on the anodization time have been calculated by the recorded interference reflection spectra. The quantitative evaluation of the flip-flop effect has been carried out based on the spectral shifts and the values of spectral changes in the tristimulus values of the CIE L*a*b* system. It has been shown that the effectiveness of the flip-flop effect depended on the acid nature (sulfuric, phosphoric, or chromic) of the anodizing solution. It has been demonstrated that the greatest flip-flop effect is attained at double anodization in chromic and phosphoric acids.

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REFERENCES

  1. Makshanchikov, I.A., Vliyanie tolshchiny oksidnoi plenki i posleduyushchei ee okraski v organicheskikh krasitelyakh na otrazhayushchuyu sposobnost' (How Oxide Film Thickness and its Following Coloration in Organic Pigments Influences onto Reflectance), no. 929-B200805.12.2008.

  2. Rudnev, V.S., Yarovaya, T.P., Nedozorov, P.M., and Boguta, D.L., RF Patent 2263164, 2004.

  3. Strel'tsov, E.A., Shchukin, G.L., and Savenko, V.P., Zashch. Met., 1985, no. 3, pp. 457–469.

  4. Pogrebnyak, A.D., Kylyshkanov, M.K., Tyurin, Yu.N., et al., Tech. Phys., 2012, vol. 57, no. 6, pp. 840–848.

    Article  CAS  Google Scholar 

  5. Atrashchenko, A.V., Krasilin, A.A., Kuchuk, I.S., Aryslanova, E.M., Chivilikhin, S.A., and Belov, P.A., Nanosist.: Fiz., Khim., Mat., 2012, vol. 3, no. 3, pp. 31–51.

    Google Scholar 

  6. Ivanov, D.K., Ivanova, Yu.A., and Strel’tsov, E.A., Izv. Nats. Akad. Nauk Belarusi, 2012, no. 2, pp. 5–8.

  7. Nielsch, K., Muller, F., Li, A., et al., Adv. Mater., 2000, vol. 12, p. 582.

    Article  CAS  Google Scholar 

  8. Moon, J. and Wei, A., J. Phys. Chem. B, 2005, vol. 109, p. 23336.

    Article  CAS  Google Scholar 

  9. Xu, D.S., Chen, D.P., Xu, Y.J., et al., Pure Appl. Chem., 2000, vol. 72, p. 127.

    Article  CAS  Google Scholar 

  10. Sauer, G., Brehm, G., Schneider, S., et al., J. Appl. Phys., 2005, vol. 97, p. 024308.

    Article  Google Scholar 

  11. Gorokh, G.G., Mozalev, A.M., Solovei, D.V., and Sakharuk, V.N., Materialy Mezhdunarodnoi Krymskoi konferentsii “SVCh-Tekhnika i telekommunikatsionnye tekhnologii” (Proc. Int. Crimean Conference “Microwave Technique and Telecommunication Technologies”), Sevastopol, 2006, vol. 2, p. 673.

  12. Shelkovnikov, V.V., Lyubas, G.A., and Korotaev, S.V., Prot. Met. Phys. Chem. Surf., 2016, vol. 52, no. 2, pp. 227–231.

    Article  CAS  Google Scholar 

  13. Odinokov, S.B., Zherdev, A.Yu., Lushnikov, D.S., Markin, V.V., Shishova, M.V., Smirnov, A.V., and Akimov, B.V., Fotonika, 2017, no. 5, p. 62.

  14. Yasui, A., Kawahara, T., Iwasaki, M., Karuppuchamy, S., Tada, H., and Ito, S., J. Jpn. Soc. Colour Mater., 2006, vol. 79, no. 5, pp. 190–196.

    Article  CAS  Google Scholar 

  15. Muratova, E.N., Extended Abstract of Cand. Sci. (Eng.) Dissertation, St. Petersburg, 2014.

  16. Devyatkina, T.I., Spasskaya, M.M., Moskvichev, A.N., Rogozhin, V.V., and Mikhalenko, M.G., Vestn. Nizhegorod. Univ. im. N. I. Lobachevskogo, 2013, no. 6 (1), pp. 109–114.

  17. Fandeev, V.P. and Samokhina, K.S., Internet-Zh. Naukoved., 2015, vol. 7, no. 4.

  18. Gorbunova, E.V. and Chertov, A.N., Tipovye raschety po kolorimetrii istochnikov izlucheniya. Uchebnoe posobie (Routine Calculations on Radiation Sources Colorimetry. Student’s Book), St. Petersburg: St. Petersburg National Research University of Information Technologies, Mechanics and Optics, 2014.

  19. Bobrikova, I.G. and Selivanov, V.N., Tekhnologii elektrokhimicheskoi i khimicheskoi khudozhestvenno-dekorativnoi obrabotki metallov i ikh splavov (Technologies for Electrochemical and Chemical Artistic-Decorative Processing of Metals and their Alloys), Novocherkassk: South-Russian State Technic Univ., 2009.

  20. Ershov, A.V. and Mashin, A.I., Mnogosloinye opticheskie pokrytiya. Proektirovanie, materialy, osobennosti tekhnologii polucheniya metodom elektronnoluchevogo ispareniya. Uchebno-metodicheskii material “Novye materialy elektroniki i optoelektroniki dlya informatsionno-telekomunikatsionnykh sistem” (Multilayer Optical Coatings. Design, Materials, Peculiarities of Synthesizing Technology by the Method of Electron-Ray Evaporation. Educational and Methodological Material “New Materials for Electronics and Opto-Electronics Intended for Information and Telecommunication Systems”), Nizhny Novgorod, 2006.

  21. Lyubas, G.A., Shelkovnikov, V.V., and Korotaev, S.V., Nanotechnol. Russ., 2016, vol. 11, nos. 1–2, pp. 29–40.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    V. V. Shelkovnikov, N. V. Vasil’eva & S. V. Korotaev

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  1. V. V. Shelkovnikov
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  2. N. V. Vasil’eva
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  3. S. V. Korotaev
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Correspondence to V. V. Shelkovnikov.

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Translated by D. Marinin

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Shelkovnikov, V.V., Vasil’eva, N.V. & Korotaev, S.V. The Flip-Flop Effect on Anodized Aluminum Oxide Films. Prot Met Phys Chem Surf 57, 313–320 (2021). https://doi.org/10.1134/S207020512102009X

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  • DOI: https://doi.org/10.1134/S207020512102009X

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