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Symmetry, topology and faceting in bicontinuous lyotropic crystals

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Abstract.

Phase diagrams of phytantriol/ethanol/water and phytantriol/DSPG/ethanol/water systems are explored and experiments on facetings of Pn3m-in-L1 and Im3m-in-L1 crystals are performed. Observed crystal habits do not agree with the Friedel-Donnay-Harker rules. We argue that this paradox can be explained in terms of constraints imposed on Pn3m/L1 and Im3m/L1 interfaces by the bicontinuous topology of the cubic phases. We point out that when free edges of the surfactant bilayer are prohibited at these interfaces, the two labyrinthes separated by the bilayer cannot anymore be equivalent. The corresponding \( {\rm Pn3m}\rightarrow {\rm Fd3m}\) and \( {\rm Im3m}\rightarrow {\rm Pm3m}\) symmetry breakings are unveiled by the abnormal facetings.

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Authors and Affiliations

  1. Laboratoire de Physique des Solides, Université Paris-Sud, Bât. 510, 91405, Orsay Cedex, France

    L. Latypova & P. Pieranski

  2. Institute of Physical Chemistry, Kasprzaka 44/52, 01-224, Warsaw, Poland

    L. Latypova & W. Góźdź

Authors
  1. L. Latypova
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  2. W. Góźdź
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  3. P. Pieranski
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Correspondence to P. Pieranski.

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Latypova, L., Góźdź, W. & Pieranski, P. Symmetry, topology and faceting in bicontinuous lyotropic crystals. Eur. Phys. J. E 36, 88 (2013). https://doi.org/10.1140/epje/i2013-13088-9

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