Abstract
Superconducting YBa2Cu4O8 ceramics were synthesized by the sol-gel method using corresponding metal acetates as starting materials, water as solvent, and tartaric acid under 1 atm oxygen pressure. YBa2Cu4O8 powder was obtained as a single phase by heating the gel at 780 °C for 30 h in flowing oxygen. Tc was 80 K from magnetic susceptibility measurements. Pelletizing and sintering this powder revealed Tc (onset) of 87 K and Tc (end) of 78 K from resistance measurements. YBa2Cu4O8 pellets sintered at 780 °C for 30 h in O2 also consist of a single phase with Tc (onset) of 85 K and Tc (end) of 75 K.
Similar content being viewed by others
References
H. W. Zandbergen, R. Gronsky, K. Wang, and G. Thomas, Nature 331, 596 (1988).
A.F. Marshall, R.W. Barton, K. Char, A. Kapitulnik, B. Oh, R.H. Hammond, and S.S. Laderman, Phys. Rev. B 37, 9353 (1988).
H. W. Zandbergen and G. Thomas, Phys. Status Solidi A 105, 207 (1988).
J. Karpinski, E. Kaldis, E. Jilek, S. Rusiecki, and B. Bucher, Nature 336, 660 (1988).
R.J. Cava, J.J. Kiajewski, W.F. Peck, Jr. B. Batlogg, L.W. Rupp, Jr. R. M. Fleming, A. C. W. P. James, and P. Marsh, Nature 338, 328 (1989).
M.K. Wu, J.R. Ashburn, C.J. Torng, P.H. Hor, R.L. Meng, L. Gao, Z.J. Huang, Y.Q. Wang, and C.W. Chu, Phys. Rev. Lett. 58, 908 (1987).
K. Char, M. Lee, R. W. Barton, A. F. Marshall, I. Bozovic, R. H. Hammond, M. R. Beasley, T. H. Geballe, A. Kapitulnik, and S. S. Laderman, Phys. Rev. B 38, 834 (1988).
T. Miyatake, S. Gotoh, N. Koshizuka, and S. Tanaka, Nature 341, 41 (1989).
K. Kourtakis, M. Robbins, P. K. Gallagher, and T. Tiefel, J. Mater. Res. 4, 1289 (1989).
H. Murakami, S. Yaegashi, J. Nishino, Y. Shiohara, and S. Tanaka, Jpn. J. Appl. Phys. 29, L445 (1990).
H. Mazaki, M. Kakihana, and H. Yasuoka, J. Jpn. Soc. Powder and Powder Metall. 38, 211 (1991).
H. Kozuka, T. Umeda, J. Jin, F. Miyaji, and S. Sakka, J. Ceram. Soc. Jpn. 96, 355 (1988).
H.R. Zhuang, H. Kozuka, and S. Sakka, J. Mater. Sci. 25, 4762 (1990).
H. R. Zhuang, H. Kozuka, and S. Sakka, Jpn. J. Appl. Phys. 28, L1805 (1989).
H. R. Zhuang, H. Kozuka, T. Yoko, and S. Sakka, Jpn. J. Appl. Phys. 29, LI107 (1990).
R. K. Cannan and A. Kibrick, J. Am. Chem. Soc. 60, 2314 (1938).
L. Meites, J. Am. Chem. Soc. 71, 3269 (1949).
I. Halasz, V. Fulop, I. Kirschner, and T. Porjesz, J. Cryst. Growth 91, 444 (1988).
J.G. Thompson, J.D. FitzGerald, R.L. Withers, P.J. Barlow, and J. S. Anderson, Mater. Res. Bull. XXIV, 505 (1989).
D.M. Pooke, R. G. Buckley, M.R. Presland, and J.L. Tallon, Phys. Rev. B 41, 6616 (1990).
S. Fujihara, H. Kozuka, T. Yoko, and S. Sakka (to be submitted).
J. Jin, H. Kozuka, and S. Sakka, J. Soc. Mater. Sci. Jpn. 40, 374 (1991).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Fujihara, S., Zhuang, H., Yoko, T. et al. Preparation of superconducting YBa2Cu4O8 by the sol-gel method. Journal of Materials Research 7, 2355–2359 (1992). https://doi.org/10.1557/JMR.1992.2355
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.1992.2355