Abstract
FeS2 is thought to be a kind of promising anode materials used for lithium-ion batteries (LIBs), but the intrinsic low electrical conductivity and remarkable volume change hinder its practical application. In the present work, we proposed a strategy by introducing mesoporous carbon (MPC) to obtain a FeS2/MPC composite electrode for LIBs. The FeS2/MPC composite was prepared by hydrothermal method. The results indicated that the FeS2/MPC composite electrode exhibited better electrochemical performance than pristine FeS2. Especially, the discharge capacity of composite electrode reached 650 mAh g−1 at 0.5 C current density, and this was significantly higher than that of pristine FeS2.
Graphic abstract
References
L. Xu, Y. Hu, H. Zhang, H. Jiang, C. Li, Confined synthesis of FeS2 nanoparticles encapsulated in carbon nanotube hybrids for ultrastable lithium-ion batteries. ACS Sustain. Chem. Eng. 4, 4251–4255 (2018). https://doi.org/10.1021/acssuschemeng.6b00741
F. Zhang, C. Wang, G. Huang, D. Yin, L. Wang, FeS2@ C nanowires derived from organic-inorganic hybrid nanowires for high-rate and long-life lithium-ion batteries. J. Power Sources 328, 56–64 (2016). https://doi.org/10.1016/j.jpowsour.2016.07.117
Y. Liu, W. Wang, Q. Chen, C. Xu, D. Cai, H. Zhan, Resorcinol-formaldehyde resin-coated prussian blue core-shell spheres and their derived unique yolk-shell FeS2@ C spheres for lithium-ion batteries. Inorg. Chem. 58, 1330–1338 (2019). https://doi.org/10.1021/acs.inorgchem.8b02897
Z. Zhao, Z. Hu, R. Jiao, Z. Tang, P. Dong, Y. Li, Tailoring multi-layer architectured FeS2@ C hybrids for superior sodium-, potassium-and aluminum-ion storage. Energy Storage Mater. 22, 228–234 (2019). https://doi.org/10.1016/j.ensm.2019.01.022
G.X. Pan, F. Cao, X.H. Xia, Y.J. Zhang, Exploring hierarchical FeS2/C composite nanotubes arrays as advanced cathode for lithium ion batteries. J. Power Sources 332, 383–388 (2016). https://doi.org/10.1016/j.jpowsour.2016.09.126
Y. Zhao, J. Zhu, S. Jun, H. Ong, Q. Yao, X. Shi, K. Hou, L. Guan, High-rate and ultralong cycle-life potassium ion batteries enabled by in situ engineering of yolk-shell FeS2@ C structure on graphene matrix. Adv. Energy Mater. 8, 1802565 (2018). https://doi.org/10.1002/aenm.201802565
X. Xu, T. Cai, Z. Meng, H. Ying, Y. Xie, X. Zhu, W.-Q. Han, FeS2 nanocrystals prepared in hierarchical porous carbon for lithium-ion battery. J. Power Sources 331, 366–372 (2016). https://doi.org/10.1016/j.jpowsour.2016.09.015
Z. Lu, N. Wang, Y. Zhang, P. Xue, M. Guo, B. Tang, Z. Bai, S. Dou, Pyrite FeS2@ C nanorods as smart cathode for sodium ion battery with ultra-long lifespan and notable rate performance from tunable pseudocapacitance. Electrochim. Acta 260, 755–761 (2018). https://doi.org/10.1016/j.electacta.2017.12.031
Q. Su, Y. Lu, S. Liu, X. Zhang, Y. Lin, R. Fu, D. Wu, Nanonetwork-structured yolk-shell FeS2@ C as high-performance cathode materials for Li-ion batteries. Carbon 140, 433–440 (2018). https://doi.org/10.1016/j.carbon.2018.08.049
Q. Xu, J. Li, H. Xue, S. Guo, Effective combination of FeS2 microspheres and Fe3S4 microcubes with rGO as anode material for high-capacity and long-cycle lithium-ion batteries. J. Power Sources 396, 675–682 (2018). https://doi.org/10.1016/j.jpowsour.2018.06.088
X. Xu, H. Ying, S. Zhang, Z. Meng, X. Yan, W.-Q. Han, Biomass-derived 3D interconnected porous carbon-encapsulated nano-FeS2 for high-performance lithium-ion batteries. ACS Appl. Energy Mater. 3, 5589–5596 (2018). https://doi.org/10.1021/acsaem.0c00537
X. Shen, Z. Tian, R. Fan, L. Shao, D. Zhang, G. Cao, L. Kou, Y. Bai, Research progress on silicon/carbon composite anode materials for lithium-ion battery. J. Energy Chem. 27, 1067–1090 (2018). https://doi.org/10.1016/j.jechem.2017.12.012
C. Zhang, H. Song, C. Liu, Y. Liu, C. Zhang, X. Nan, G. Cao, Fast and reversible Li ion insertion in carbon-encapsulated Li3VO4 as anode for lithium-ion battery. Adv. Funct. Mater. 25, 2497–3504 (2015). https://doi.org/10.1002/adfm.201500644
J. Hwang, C. Jo, M.G. Kim, J. Chun, E. Lim, S. Kim, S. Jeong, Y. Kim, J. Lee, Mesoporous Ge/GeO2/carbon lithium-ion battery anodes with high capacity and high reversibility. ACS Nano 9, 5299–5309 (2015). https://doi.org/10.1021/acsnano.5b00817
H. Liu, W. Li, D. Shen, D. Zhao, G. Wang, Graphitic carbon conformal coating of mesoporous TiO2 hollow spheres for high-performance lithium-ion battery anodes. J. Am. Chem. Soc. 137, 13161–13166 (2015). https://doi.org/10.1021/jacs.5b08743
K. Feng, W. Ahn, G. Lui, H.W. Park, A.G. Kashkooli, G. Jiang, X. Wang, X. Xiao, Z. Chen, Implementing an in situ carbon network in Si/reduced graphene oxide for high performance lithium ion battery anodes. Nano Energy 19, 187–197 (2016). https://doi.org/10.1016/j.nanoen.2015.10.025
H. Liu, L. Shi, D. Li, J. Yu, H.-M. Zhang, S. Ullah, B. Yang, C. Li, C. Zhu, J. Xu, Rational design of hierarchical ZnO@ Carbon nanoflower for high performance lithium ion battery anodes. J. Power Sources 387, 64–71 (2018). https://doi.org/10.1016/j.jpowsour.2018.03.047
Z. Li, Q. He, L. He, P. Hu, W. Li, H. Yan, X. Peng, C. Huang, L. Mai, Self-sacrificed synthesis of carbon-coated SiOx nanowires for high capacity lithium ion battery anodes. J. Mater. Chem. A 5, 4183–4189 (2017). https://doi.org/10.1039/C6TA10583A
X. Zhang, R. Zhao, Q. Wu, W. Li, C. Shen, L. Ni, H. Yan, G. Diao, M. Chen, Petal-like MoS2 nanosheets space-confined in hollow mesoporous carbon spheres for enhanced lithium storage performance. ACS Nano 11, 8429–8436 (2017). https://doi.org/10.1021/acsnano.7b04078
J. Xie, B.-Q. Li, H.-J. Peng, Y.-W. Song, M. Zhao, X. Chen, Q. Zhang, J.-Q. Huang, Implanting atomic cobalt within mesoporous carbon toward highly stable lithium–sulfur batteries. Adv. Mater. 31, 1903813 (2019). https://doi.org/10.1002/adma.201903813
G.-H. An, H. Kim, H.-J. Ahn, Improved ionic diffusion through the mesoporous carbon skin on silicon nanoparticles embedded in carbon for ultrafast lithium storage. ACS Appl. Mater. Interfaces. 10, 6235–6244 (2018). https://doi.org/10.1021/acsami.7b15950
J. Wang, Y. Xia, Y. Liu, W. Li, D. Zhao, Mass production of large-pore phosphorus-doped mesoporous carbon for fast-rechargeable lithium-ion batteries. Energy Storage Mater. 22, 147–153 (2019). https://doi.org/10.1016/j.ensm.2019.01.008
S. Prakash, C. Zhang, J.-D. Park, F. Razmjooei, J.-S. Yu, Silicon core-mesoporous shell carbon spheres as high stability lithium-ion battery anode. J. Colloid Interface Sci. 534, 47–54 (2019). https://doi.org/10.1016/j.jcis.2018.09.004
T. Kesavan, T. Partheeban, M. Vivekanantha, N. Prabu, M. Kundu, P. Selvarajan, S. Umapathy, A. Vinu, M. Sasidharan, Design of P-doped mesoporous carbon nitrides as high-performance anode materials for Li-ion battery. ACS Appl. Mater. Interfaces. 12, 24007–24018 (2020). https://doi.org/10.1021/acsami.0c05123
L. Wang, C. Yang, S. Dou, S. Wang, J. Zhang, X. Gao, J. Ma, Y. Yu, Nitrogen-doped hierarchically porous carbon networks: synthesis and applications in lithium-ion battery, sodium-ion battery and zinc-air battery. Electrochim. Acta 219, 592–603 (2016). https://doi.org/10.1016/j.electacta.2016.10.050
J. Li, D. Yan, T. Lu, Y. Yao, L. Pan, An advanced CoSe embedded within porous carbon polyhedra hybrid for high performance lithium-ion and sodium-ion batteries. Chem. Eng. J. 325, 14–24 (2017). https://doi.org/10.1016/j.cej.2017.05.046
M.-S. Baloguna, W. Qiu, F. Lyu, Y. Luo, H. Meng, J. Li, W. Mai, L. Mai, Y. Tong, All-flexible lithium ion battery based on thermally-etched porous carbon cloth anode and cathode. Nano Energy 26, 446–455 (2016). https://doi.org/10.1016/j.nanoen.2016.05.017
H. Liu, X. Liu, W. Li, X. Guo, Y. Wang, G. Wang, D. Zhao, Porous carbon composites for next generation rechargeable lithium batteries. Adv. Energy Mater. 7, 1700283 (2017). https://doi.org/10.1002/aenm.201700283
Z. Li, C. Wang, X. Chen, X. Wang, X. Li, Y. Yamauchi, X. Xue, J. Wang, C. Lin, D. Luo, X. Wang, X. Zhao, MoOx nanoparticles anchored on N-doped porous carbon as Li-ion battery electrode. Chem. Eng. J. 381, 122588 (2020). https://doi.org/10.1016/j.cej.2019.122588
X. Sun, J. Gao, C. Wang, X. Gao, J. Liu, N. Gao, H. Li, Y. Wang, K. Yu, A hybrid ZnO/Si/porous-carbon anode for high performance lithium ion battery. Chem. Eng. J. 383, 123198 (2020). https://doi.org/10.1016/j.cej.2019.123198
S. Lu, T. Zhu, Z. Li, Y. Pang, L. Shi, S. Ding, G. Gao, Ordered mesoporous carbon supported Ni3V2O8 composites for lithium-ion batteries with long-term and high-rate performance. J. Mater. Chem. A 6, 7005–7013 (2018). https://doi.org/10.1039/C7TA11268H
P. Xue, Y. Zhai, N. Wang, Y. Zhang, Z. Lu, Y. Liu, Z. Bai, B. Han, G. Zou, S. Dou, Selenium@ Hollow mesoporous carbon composites for high-rate and long-cycling lithium/sodium-ion batteries. Chem. Eng. J. 392, 123676 (2020). https://doi.org/10.1016/j.cej.2019.123676
G. Zhang, Z. Hao, J. Yin, C. Wang, J. Zhang, Z. Zhao, D. Wei, H. Zhou, Z. Li, FeS2 crystal lattice promotes the nanostructure and enhances the electrocatalytic performance of WS2 nanosheets for the oxygen evolution reaction. Dalton Trans. 49, 9804–9810 (2020). https://doi.org/10.1039/D0DT01660H
X. Zhang, C. Wang, P. Yang, X. Zhang, W. Chen, J. Liu, Y. Cui, X. Liu, X. Li, Mechanism and kinetics characteristic of self-discharge of FeS2 cathodes for thermal batteries. Phys. Chem. Chem. Phys. 23, 196–203 (2021). https://doi.org/10.1039/d0cp04576d
Q. Xu, H. Xue, FeS2 walnut-like microspheres wrapped with rGO as anode material for high-capacity and long-cycle lithium-ion batteries. Electrochim. Acta 292, 1–9 (2018). https://doi.org/10.1016/j.electacta.2018.09.135
H. Fan, H. Li, K. Huang, C. Fan, X. Zhang, X. Wu, J. Zhang, Metastable marcasite-FeS2 as a new anode material for lithium ion batteries: CNFs-improved lithiation/delithiation reversibility and Li-storage properties. ACS Appl. Mater. Interfaces. 9, 10708–10716 (2017). https://doi.org/10.1021/acsami.7b00578
Acknowledgments
This work was partly supported by the National Natural Science Foundation of China (NO. 51802258), project funded by the China Postdoctoral Science Foundation (NO.2020T130525), Shaanxi Province Postdoctoral Science Foundation (NO.2018BSHEDZZ113), the National Natural Science Foundation of China (No. 51771145), ISF-NSFC Joint Research Program (No. 51961145305), and Shaanxi Natural Science Basic Research Plan, China (No. 2020JM-464).
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Supplementary material 1 (DOCX 1563 kb) Supplementary Material Available: [The microstructure and morphology of as-prepared MPC sample is presented in Figure S1.].
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Liu, H., Jing, R., Wang, Z. et al. FeS2 encapsulated with mesoporous carbon for high-performance lithium-ion batteries. MRS Communications 11, 418–424 (2021). https://doi.org/10.1557/s43579-021-00048-6
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DOI: https://doi.org/10.1557/s43579-021-00048-6