Skip to main content
SpringerLink
Log in

Fe2+- and Er2+-intercalative modification of porous and electron structure of activated carbon and its influence on supercapacitor parameters

  • Research Article
  • Published:
Materials Science-Poland

Abstract

An influence of both porous and electron structure on the processes in an electric double layer (EDL) determining the main working parameters of carbon-based supercapacitors has been studied in order to improve them. The investigations involved impedance spectroscopy, X-ray small angle scattering, confocal micro-Raman spectroscopy, infra-red and Mössbauer spectroscopy. Fe2+- and Er2+-intercallative modifications of nanoporous carbon were performed. It was found that the modification process characteristics correlated with the structure parameters of the EDL.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Conway B.E., Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications, Kluwer Academic/Plenum Publishing, New York, 1999.

    Book  Google Scholar 

  2. Candelaria S.L., Chen R., Jeong Y.-H., Cao G., Energ. Environ. Sci., 5 (2012), 5619.

    Article  Google Scholar 

  3. Taberna P.-L., Chevallier G., Simon P., Plée D., Aubert T., Mater. Res. Bull., 41 (2006), 478.

    Article  Google Scholar 

  4. Liang C., Li Z., Dai S., Angew. Chem. Int. Edit., 47 (2008), 3696.

    Article  Google Scholar 

  5. Xing W., Huang C.C., Zhuo S.P., Yuan X., Wang G.Q., Hulicova-Jurcakova D., Yan Z.F., Lu G.Q., Carbon, 47 (2009), 1715.

    Article  Google Scholar 

  6. Seredych M., Hulicova-Jurcakova D., Lu G.Q., Bandosz T.J., Carbon, 46 (2008), 1475.

    Article  Google Scholar 

  7. Venhryn B.Y., Stotsko Z.A., Grygorchak I.I., Bakhmatyuk B.P., Mudry S.I., Ultrason. Sonochem., 20 (2013), 1302.

    Article  Google Scholar 

  8. Guo S., Peng J., Li W., Yang K., Zhang L., Zhang S., Xia H., Appl. Surf. Sci., 255 (2009), 8443.

    Article  Google Scholar 

  9. Tseng R.-L., Tseng S.-K., J. Colloid Interf. Sci., 287 (2005), 428.

    Article  Google Scholar 

  10. Armandi M., Bonelli B., Geobaldo F., Garrone E., Micropor. Mesopor. Mat., 132 (2010), 414.

    Article  Google Scholar 

  11. Venhryn B.Y., Grygorchak I.I., Kulyk Y.O., Mudry S.I., Mater. Sci.-Poland, 31 (2013), 126.

    Article  Google Scholar 

  12. Gerischer H., J. Phys. Chem., 89 (1985), 4249.

    Article  Google Scholar 

  13. Chernysh I.H., Karpov I.E., Prykhodko H.P., Shy V.M., Physico-chemical properties of graphite and its compounds, Naukova Dumka, Kiev, 1990.

    Google Scholar 

  14. Zolotukhin I.V., Kalinin Y.E., Loginova V.I., International Scientific Journal for Alternative Energy and Ecology (ISJAEE), 9 (2005), 56.

    Google Scholar 

  15. Langford J.I., Wilson A.J.C., J. Appl. Cryst., 11 (1978), 102.

    Article  Google Scholar 

  16. Ravagnan L., Siviero F., Lenardi C., Piseri P., Barborini E., Milani P., Casari C.S., Li B.A., Bottani C.E., Phys. Rev. Lett., 89 (2002), 285506.

    Article  Google Scholar 

  17. Dovbeshko G.I., Gnatyuk O.P., Nazarova A.N., Sementsov Yu.i., Obraztsova E.D., Fuller. Nanotub. Car. N., 13 (2005), 393.

    Article  Google Scholar 

  18. Ferrari A.C., Robertson J., Phys. Rev. B, 64 (2001), 075414.

    Article  Google Scholar 

  19. Benner D.C., Rinsland C.P., Devi V.M., Smith M.A.H., Atkins D., J. Quant. Spectrosc. Ra., 53 (1995), 705.

    Article  Google Scholar 

  20. Ferrari A.C., Robertson J., Phys. Rev. B, 61 (2000), 14095.

    Article  Google Scholar 

  21. Cuesta A., Dhamelincourt P., Laureyns J., Martínez-Alonso A., Tascón J.M.D., Carbon, 32 (1994), 1523.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Lviv Polytechnic National University, Vul. S. Bandery 12, Lviv, 79013, Ukraine

    B. Ya. Venhryn & I. I. Grygorchak

  2. Ivan Franko National University of Lviv, Vul. Kyryla i Mefodia 8, Lviv, 79005, Ukraine

    Yu. O. Kulyk & S. I. Mudry

  3. V. Lashkaryov Institute of Semiconductor Physics, National Academy of Science of Ukraine, pr. Nauky 41, Kyiv, 03028, Ukraine

    V. V. Strelchuk & S. I. Budzulyak

  4. Institute of Physics, National Academy of Science of Ukraine, pr. Nauky 46, Kyiv, 03028, Ukraine

    G. I. Dovbeshko & O. M. Fesenko

Authors
  1. B. Ya. Venhryn
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. I. Grygorchak
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. O. Kulyk
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. I. Mudry
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. V. Strelchuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. S. I. Budzulyak
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. G. I. Dovbeshko
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. O. M. Fesenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to B. Ya. Venhryn.

Additional information

This paper was presented at the Conference Functional and Nanostructured Materials, FNMA 11, 6–9 September 2011, Szczecin, Poland.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Venhryn, B.Y., Grygorchak, I.I., Kulyk, Y.O. et al. Fe2+- and Er2+-intercalative modification of porous and electron structure of activated carbon and its influence on supercapacitor parameters. Mater Sci-Pol 32, 272–280 (2014). https://doi.org/10.2478/s13536-013-0178-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2478/s13536-013-0178-5

Keywords

Search

Navigation