Abstract
Currently, the use of membrane techniques has undergone dynamic growth, particularly due to the diversification of their fields of application. This trend is expected to increase owing to new environmental protection requirements and thanks to the increasingly competitive energy and technical-economic performances offered by membrane processes. New research is constantly being carried out to better understand the functioning of membranes, to create more efficient or more specific membranes, and also to develop processes for new applications. The aim of this work is to improve the performance of a polyamide reverse osmosis membrane by chemical modification of its surface. Thin film polyamide reverse osmosis membranes are widely used for desalination. However, these membranes face a fouling issue that results in low permeation flux, which is undesirable in the reverse osmosis process. An interesting alternative to improve the properties of these polyamide composite membranes is the use of chemical surface modification. In this context, we studied the chemical grafting of vinyl acetate monomer on the surface of a polyamide membrane in order to improve the selectivity towards sodium ion. The chemical grafting was carried out by radical polymerization of vinyl acetate monomer in the presence of benzoil peroxide as an initiator in an organic medium. Unmodified, modified membranes and evolution of the polymerization reaction were analyzed by Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), interferometric electron microscopy, and contact angle. An application with a front filtration module was investigated to confirm the improved selectivity for sea water. This study revealed an improved efficiency of the reverse osmosis PA membrane after the grafting of polyacetate monomer on the active layer of this membrane.
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REFERENCES
Zhang, Y., Wan, Y., Pan, G., Shi, H., Yan, H., Xu, J., Guo, M., Wang, Zh., and Liu, Y., Surface modification of polyamide reverse osmosis membrane with sulfonated polyvinyl alcohol for antifouling, J. Appl. Surf. Sci., 2017, vol. 419, pp. 177–187.
Raman, L.P., Cheryna, M., and Rajagopalan, N., Consider nanofiltration for membrane separations, J. Chem. Eng. Prog., 1994, vol. 90, pp. 68–74.
Kang, G. and Cao, Y., Development of antifouling reverse osmosis membranes for water treatment: A review, J. Water. Res., 2012, vol. 46, pp. 584–600.
Nikkola, J.J., Sievanen, J.M., Raulio, M.J., Wei, J., Vuorinen, J., and Tang, C.Y., Surface modification of thin film composite polyamide membrane using atomic layer deposition method, J. Membr. Sci., 2014, vol. 450, pp. 174–180.
Sagle, A.C., Van Wagner, E.M., Ju, H., McCloskey, B.D., Freeman, B.D., and Sharma, M.M., PEG-coated reverse osmosis membranes: Desalination properties and fouling resistance, J. Membr. Sci., 2009, vol. 340, pp. 92–108.
Wilbert, M.C., Pellegrino, J., and Zydney, A., Bench-scale testing of surfactant-modified reverse osmosis/nanofiltration membranes, Desalination, 1998, vol. 115, pp. 15–32.
Louie, J.S., Pinnau, I., Ciobanu, I., Ishida, K.P., Ng, A., and Reinhard, M., Effects of polyether-polyamide block copolymer coating on performance and fouling of reverse osmosis membranes, J. Membr. Sci., 2006, vol. 280, pp. 762–770.
Kim, I.C. and Lee, K.H., Dyeing process wastewater treatment using fouling resistant nanofiltration and reverse osmosis membranes, Desalination, 2006, vol. 192, pp. 246–251.
Upadhyaya, L., Qian, X., and Wickramasinghe, S.R., Chemical modification of membrane surface—Overview, J. Curr. Opin. Chem. Eng., 2018, vol. 20, pp. 13–18.
She, Q., Wang, R., Fane, A.G., and Tang, C.Y., Membrane fouling in osmotically driven membrane processes: A review, J. Memb. Sci., 2016, vol. 499, pp. 201–233.
Asadollahi, M., Bastani, D., and Musavi, S.A., Enhancement of surface properties and performance of reverse osmosis membranes after surface modification: A review, Desalination, 2017, vol. 420, pp. 330– 383.
Stengaard, F.F., Characteristics and performance of new types of ultrafiltration membranes with chemically modified surfaces, Desalination, 1988, vol. 70, pp. 207–224.
Shultz, S., Bass, M., Semiat, R., and Freger, V., Modification of polyamide membranes by hydrophobic molecular plugs for improved boron rejection, J. Membr. Sci., 2018, vol. 546, pp. 165–172.
Hu, Y.T., Lu, K., Yan, F., Shi, Y.L., Yu, P., Yu, S., Li, S., and Gao, C., Enhancing the performance of aromatic polyamide reverse osmosis membrane by surface modification via covalent attachment of polyvinyl alcohol (PVA), J. Membr. Sci., 2016, vol. 501, pp. 209–219.
Bernstein, R., Belfer, S., and Freger, V., Improving performance of spiral wound RO elements by in situ concentration polarization-enhanced radical graft polymerization, J. Membr. Sci., 2012, vols. 405–406, pp. 79–84.
Dražević, E., Košutić, K., and Freger, V., Permeability and selectivity of reverse osmosis membranes: Correlation to swelling revisited, Water Res., 2014, vol. 49, pp. 444–452.
Williams, M.E., Hestekin, J.A., Smothers, C.N., and Bhattacharyya, D., Separation of organic pollutants by reverse osmosis and nanofiltration membranes: Mathematical models and experimental verification, Ind. Eng. Chem. Res., 1999, vol. 38, pp. 3683–3695.
Drazevic, E., Bason, S., Kosutic, K., and Freger, V., Enhanced partitioning and transport of phenolic micropollutants within polyamide composite membranes, Environ. Sci. Technol., 2012, vol. 46, pp. 3377–3383.
Kiso, Y., Sugiura, Y., Kitao, T., and Nishimura, K., Effects of hydrophobicity and molecular size on rejection of aromatic pesticides with nanofiltration membranes, J. Membr. Sci., 2001, vol. 192, pp. 1–10.
Hong, S., Kim, I.C., Tak, T., and Kwon, Y.N., Interfacially synthesized chlorine-resistant polyimide thin film composite (TFC) reverse osmosis (RO) membranes, Desalination, 2013, vol. 309, pp. 18–26.
Khulbe, K.C., Feng, C., and Matsuura, T., The art of surface modification of synthetic polymeric membranes, J. Appl. Polym. Sci., 2010, vol. 115, pp. 855–895.
Galvin, C.J. and Genzer, J., Applications of surface-grafted macromolecules derived from post-polymerization modification reactions, Prog. Polym. Sci., 2012, vol. 37, pp. 871–906.
Belfer, S., Purinson, Y., Fainshtein, R., Radchenko, Y., and Kedem, O., Surface modification of commercial composite polyamide reverse osmosis membranes, J. Membr. Sci., 1998, vol. 139, pp. 175–181.
Freger, V., Gilron, J., and Belfer, S., TFC polyamide membranes modified by grafting of hydrophilic polymers: An FT-IR/AFM/TEM study, J. Membr. Sci., 2002, vol. 209, pp. 283–292.
Liu, M.H., Chen, Q., Wang, L.Z., Yu, S.C., and Gao, C.J., Improving fouling resistance and chlorine stability of aromatic polyamide thin-film composite RO membrane by surface grafting of polyvinyl alcohol (PVA), Desalination, 2015, vol. 367, pp. 11–20.
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Bouraoui, H., Khemakhem, A., Ben Romdhane, M.R. et al. Chemical Modification of Polyamide Thin-Film Composite Membrane by Surface Grafting of a Vinyl-Based Monomer. J. Water Chem. Technol. 44, 108–115 (2022). https://doi.org/10.3103/S1063455X22020023
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DOI: https://doi.org/10.3103/S1063455X22020023