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Structure and Properties of Ionomers

  • Book
  • © 1987

Overview

Editors:
  1. Michel Pineri

    1. Service de Physique, Departement de Recherche Fondamentale, Centre d’Etudes Nucléaires de Grenoble, France

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    You can also search for this editor in PubMed   Google Scholar

  2. Adi Eisenberg

    1. McGill University, Montreal, Canada

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    You can also search for this editor in PubMed   Google Scholar

Part of the book series: Nato Science Series C: (ASIC, volume 198)

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Table of contents (53 chapters)

  1. Front Matter

    Pages i-xvi
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  2. Available Ionomers

    • W. J. MacKnight
    Pages 1-9

  3. A Review and Critical Analysis of Theories of Polar/Nonpolar Aggregation in Ionomers

    • Kenneth A. Mauritz
    Pages 11-26

  4. Simple Considerations on the Morphology of Ionomers

    • B. Dreyfus
    Pages 27-37

  5. Statistical Mechanics of Ion-Pair Association in Ionomers

    • William C. Forsman
    Pages 39-50

  6. The Exafs Spectroscopy Applied to the Ionic Aggregates of Halato-Telechelic Polymers

    • Gilberto Vlaic
    Pages 51-72

  7. Exafs Analysis of Ion Containing Polymers

    • Y. S. Ding, S. L. Cooper
    Pages 73-86

  8. Chemistry in Ionomers

    • William M. Risen Jr.
    Pages 87-96

  9. Chromium (III) and Cobalt (II) Aquo Complexes in PFSA (Nafion) Ionomer Films

    • S. P. Koinis, A. T. Tsatsas
    Pages 97-105

  10. EPR of Mn2+, Fe3+ and Cu2+ in Ionomers

    • D. Galland
    Pages 107-116

  11. Magnetization and Susceptibility of Ion-Containing Polymers

    • J. M. D. Coey
    Pages 117-126

  12. Electronic Spectra and Photophysical Properties of Ions as Probes for the Properties and Structure of Perfluorinated Ionomer Membranes

    • John M. Kelly
    Pages 127-140

  13. Structural Studies of Ionomers by Infrared Spectroscopy

    • Michael Falk
    Pages 141-148

  14. An NMR Study of α, ω-Dicarboxylatopolybutadiene

    • V. J. McBrierty, G. Smyth, D. C. Douglass
    Pages 149-161

  15. Structure of Ionomers : Use and Abuse of Saxs

    • Claudine E. Williams
    Pages 163-170

  16. Small Angle Neutron Scattering Studies of Ionomers in the Bulk State

    • J. S. Higgins
    Pages 171-180

  17. Labelling and Misinterpretation

    • R. Duplessix
    Pages 181-188

  18. Roundtable Discussion Concerning the Relations between the Results Obtained from Local and Macroscopic Studies

    • Stuart L. Cooper
    Pages 189-190

  19. Viscoelastic Behavior of Ionomers in Bulk and Solution

    • Martin R. Tant, Garth L. Wilkes
    Pages 191-226

  20. Dielectric and Related Molecular Processes in Ion Containing Polymers

    • Gisèle Boiteux
    Pages 227-245
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Keywords

About this book

Ionomers, that is polymers containing a low concentration of charged units along the chain, have been the subject of increasing interest during the past twenty years. The presence of ionic groups in the poly­ mer changes some of its properties dramatically. Increases in the modu­ lus and the viscosity of several orders of magnitude have been observed, and changes in the glass transition of hundreds of degrees are possible. In addition, diffusion coefficients can be modified drastically. These changes are due primarily to the presence of reversible ionic cross­ links in these materials. Because of the low dielectric constant of most organic polymers, the ions or ionic dipoles tend to aggregate ; this aggregation process, however, is limited, because the ionic groups are covalently bonded to the organic chain. Host of the fundamental research done on these materials has been devoted to a determination of the extent of association, the structure of the aggregates, the limi­ ting factors, and the correlations between molecular and supermolecular structure and the resul ting properties.

Editors and Affiliations

  • Service de Physique, Departement de Recherche Fondamentale, Centre d’Etudes NuclĂ©aires de Grenoble, France

    Michel Pineri

  • McGill University, Montreal, Canada

    Adi Eisenberg

Bibliographic Information

  • Book Title: Structure and Properties of Ionomers

  • Editors: Michel Pineri, Adi Eisenberg

  • Series Title: Nato Science Series C:

  • DOI: https://doi.org/10.1007/978-94-009-3829-8

  • Publisher: Springer Dordrecht

  • eBook Packages: Springer Book Archive

  • Copyright Information: D. Reidel Publishing Company, Dordrecht, Holland 1987

  • Hardcover ISBN: 978-90-277-2458-8Published: 31 May 1987

  • Softcover ISBN: 978-94-010-8204-4Published: 03 November 2011

  • eBook ISBN: 978-94-009-3829-8Published: 06 December 2012

  • Series ISSN: 1389-2185

  • Edition Number: 1

  • Number of Pages: XVI, 581

  • Topics: Organic Chemistry, Characterization and Evaluation of Materials

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