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Catalytic Transformations of Molecular Dinitrogen by Iron and Cobalt–Dinitrogen Complexes as Catalysts

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Nitrogen Fixation

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 60))

Abstract

This chapter describes the recent advances of the iron and cobalt-catalyzed transformations of molecular dinitrogen into not only silylamine but also ammonia and hydrazine under mild reaction conditions. In both reaction systems, reaction pathways are proposed based on the experimental and theoretical studies on iron and cobalt–dinitrogen complexes.

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References

  1. Liu H (2013) Ammonia synthesis catalysts. Chemical Industry Press & World Scientific, Singapore & Beijing

    Book  Google Scholar 

  2. Hoffman BM, Lukoyanov D, Yang ZH, Dean DR, Seefeldt LC (2014) Chem Rev 114:4041

    Article  CAS  Google Scholar 

  3. Spatzal T, Aksoyoglu M, Zhang L, Andrade SLA, Schleicher E, Weber S, Rees DC, Einsle O (2011) Science 334:940

    Article  CAS  Google Scholar 

  4. Lancaster KM, Roemelt M, Ettenhuber P, Hu Y, Ribbe MW, Neese F, Bergmann U, DeBeer S (2011) Science 334:974

    Article  CAS  Google Scholar 

  5. Lancaster KM, Hu Y, Bergmann U, Ribbe MW, DeBeer S (2013) J Am Chem Soc 135:610

    Article  CAS  Google Scholar 

  6. Wiig JA, Hu Y, Lee CC, Ribbe MW (2012) Science 337:1672

    Article  CAS  Google Scholar 

  7. Köthe C, Limberg C (2015) Z Anorg Allg Chem 641:18

    Article  Google Scholar 

  8. Khoenkhoen N, de Bruin B, Reek JNH, Dzik WI (2015) Eur J Inorg Chem 567

    Google Scholar 

  9. Nishibayashi Y (2015) Inorg Chem 54:9234

    Article  CAS  Google Scholar 

  10. Tanabe Y, Nishibayashi Y (2016) Chem Rec 16:1549

    Article  CAS  Google Scholar 

  11. Crossland JL, Tyler DR (2010) Coord Chem Rev 254:1883

    Article  CAS  Google Scholar 

  12. Hazari N (2010) Chem Soc Rev 39:4044

    Article  CAS  Google Scholar 

  13. MacLeod KC, Holland PL (2013) Nat Chem 5:559

    Article  CAS  Google Scholar 

  14. Fryzuk MD (2013) Chem Commun 49:4866

    Article  CAS  Google Scholar 

  15. Yamamoto A, Kitazume S, Pu LS, Ikeda S (1967) Chem Commun 79

    Google Scholar 

  16. Sacco A, Aresta M (1968) Chem Commun 1223

    Google Scholar 

  17. Tyler DR (2015) Z Anorg Allg Chem 641:31

    Article  CAS  Google Scholar 

  18. Shiina K (1972) J Am Chem Soc 94:9266

    Article  CAS  Google Scholar 

  19. Kawaguchi M, Hamaoka S, Mori M (1993) Tetrahedron Lett 34:6907

    Article  CAS  Google Scholar 

  20. Mori M (2004) J Organomet Chem 689:4210

    Article  CAS  Google Scholar 

  21. Komori K, Oshita H, Mizobe Y, Hidai M (1989) J Am Chem Soc 111:1939

    Article  CAS  Google Scholar 

  22. Komori K, Sugiura S, Mizobe Y, Yamada M, Hidai M (1989) Bull Chem Soc Jpn 62:2953

    Article  CAS  Google Scholar 

  23. Oshita H, Mizobe Y, Hidai M (1993) J Organomet Chem 456:213

    Article  CAS  Google Scholar 

  24. Tanaka H, Sasada A, Kouno T, Yuki M, Miyake Y, Nakanishi H, Nishibayashi Y, Yoshizawa K (2011) J Am Chem Soc 133:3498

    Article  CAS  Google Scholar 

  25. Yuki M, Tanaka H, Sasaki K, Miyake Y, Yoshizawa K, Nishibayashi Y (2012) Nat Commun 3:1254

    Article  Google Scholar 

  26. Ung G, Peters JC (2015) Angew Chem Int Ed 2015:532

    Google Scholar 

  27. Moret ME, Peters JC (2011) Angew Chem Int Ed 50:2063

    Article  CAS  Google Scholar 

  28. Anderson JS, Rittle J, Peters JC (2013) Nature 501:84

    Article  CAS  Google Scholar 

  29. Del Castillo TJ, Thompson NB, Peters JC (2016) J Am Chem Soc 138:5341

    Article  CAS  Google Scholar 

  30. Creutz SE, Peters JC (2014) J Am Chem Soc 136:1105

    Article  CAS  Google Scholar 

  31. Lee Y, Mankad NP, Peres JC (2010) Nat Chem 2:558

    Article  CAS  Google Scholar 

  32. Rittle J, McCrory CCL, Peters JC (2014) J Am Chem Soc 136:13853

    Article  CAS  Google Scholar 

  33. Creutz SE, Peters JC (2015) J Am Chem Soc 137:7310

    Article  CAS  Google Scholar 

  34. Anderson JS, Moret ME, Peters JC (2013) J Am Chem Soc 135:534

    Article  CAS  Google Scholar 

  35. Anderson JS, Cutsail III GE, Rittle J, Connor BA, Gunderson WA, Zhang L, Hoffman BM, Peters JC (2015) J Am Chem Soc 137:7803

    Article  CAS  Google Scholar 

  36. Rittle J, Peters JC (2016) J Am Chem Soc 138:4243

    Article  CAS  Google Scholar 

  37. Kuriyama S, Arashiba K, Nakajima K, Matsuo Y, Tanaka H, Ishii K, Yoshizawa K, Nishibayashi Y (2016) Nat Commun 7:12181

    Article  CAS  Google Scholar 

  38. Yamamoto A, Miura Y, Ito T, Chen HL, Iri K, Ozawa F, Miki K, Sei T, Tanaka N, Kasai N (1983) Organometallics 2:1429

    Article  CAS  Google Scholar 

  39. Siedschlag RB, Bernales V, Vogiatzis KD, Planas N, Clouston LJ, Bill E, Gagliardi L, Lu CC (2015) J Am Chem Soc 137:4638

    Article  CAS  Google Scholar 

  40. Imayoshi R, Tanaka H, Matsuo Y, Yuki M, Nakajima K, Yoshizawa K, Nishibayashi Y (2015) Chem Eur J 21:8905

    Article  CAS  Google Scholar 

  41. Del Castillo TJ, Thompson NB, Suess DLM, Ung G, Peters JC (2015) Inorg Chem 54:9256

    Article  CAS  Google Scholar 

  42. Kuriyama S, Arashiba K, Tanaka H, Matsuo Y, Nakajima K, Yoshizawa K, Nishibayashi Y (2016) Angew Chem Int Ed 55:14291

    Article  CAS  Google Scholar 

  43. Hill PJ, Doyle LR, Crawford AD, Myers WK, Ashley AE (2016) J Am Chem Soc 138: 13521

    Google Scholar 

  44. Imayoshi R, Nakajima K, Nishibayashi Y (2017) Chem Lett 46:466

    Google Scholar 

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Authors and Affiliations

  1. Department of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan

    Shogo Kuriyama & Yoshiaki Nishibayashi

Authors
  1. Shogo Kuriyama
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  2. Yoshiaki Nishibayashi
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Corresponding author

Correspondence to Yoshiaki Nishibayashi .

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Editors and Affiliations

  1. The University of Tokyo, Department of Systems Innovation, School of Engineering, Hongo, Tokyo, Japan

    Yoshiaki Nishibayashi

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Kuriyama, S., Nishibayashi, Y. (2017). Catalytic Transformations of Molecular Dinitrogen by Iron and Cobalt–Dinitrogen Complexes as Catalysts. In: Nishibayashi, Y. (eds) Nitrogen Fixation. Topics in Organometallic Chemistry, vol 60. Springer, Cham. https://doi.org/10.1007/3418_2016_5

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