Abstract
Syngas produced from biomass and biowaste gasification is a versatile renewable fuel and feedstock for chemical synthesis or heat and power production. Bio-syngas can be produced from different biomass feedstock (e.g. lignocellulosic biomass, pyrolysis oil, bioethanol, biogas) through thermal and/or catalytic reforming and gasification processes. The typical components of raw syngas can be classified into three groups: non-condensable gases (e.g. H2, CO, CH4 and CO2), condensable gases (e.g. H2O and tars) and impurities (e.g. HCl, NH3, H2S and particulates). Depending on the application, raw syngas may need to be cleaned of impurities and conditioned to adjust the H2/CO ratio in order to meet the requirements of environmental regulations and downstream processes respectively. Hence, an accurate characterization of the syngas chemical composition, at the different processing stages, is important to control and optimize the process efficiency. In this chapter, various methods and equipment for sampling, preconditioning and analyzing the three groups of syngas components will be discussed. Analyses of the equipment detection limits, gas matrix sensitivity, and overall accuracy will also be made.
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References
Richardson, Y., Blin, J., Julbe, A.: A short overview on purification and conditioning of syngas produced by biomass gasification: catalytic strategies, process intensification and new concepts. Prog. Energy Combust. Sci. 38(6), 765–781 (2012)
Sikarwar, V.S., Zhao, M., Fennell, P.S., Shah, N., Anthony, E.J.: Progress in bio-fuel production from gasification. Prog. Energy Combust. Sci. 61, 189–248 (2017)
Watson, J., Zhang, Y., Si, B., Chen, W.-T., de Souza, R.: Gasification of biowaste: a critical review and outlooks. Renew. Sustain. Energy Rev. 83, 1–17 (2018)
Huber, G.W., Iborra, S., Corma, A.: Synthesis of transportation fuels from bio-mass: chemistry, catalysts, and engineering. Chem. Rev. 106(9), 4044–4098 (2006)
Mota, N., Alvarez-Galvan, C., Navarro, R.M., Fierro, J.L.: Biogas as a source of renewable syngas production: advances and challenges. Biofuels 2(3), 325–343 (2011)
Rossetti, I., Compagnoni, M., Finocchio, E., Ramis, G., Di Michele, A., Zucchini, A., Dzwigaj, S.: Syngas production via steam reforming of bioethanol over Ni–BEA catalysts: a BTL strategy. Int. J. Hydrog. Energy 41(38), 16878–16889 (2016)
Zhang, Y., Brown, T.R., Hu, G., Brown, R.C.: Comparative techno-economic analysis of biohydrogen production via bio-oil gasification and bio-oil reforming. Biomass Bioenergy 51, 99–108 (2013)
Chew, J.J., Doshi, V.: Recent advances in biomass pretreatment-Torrefaction fundamentals and technology. Renew. Sustain. Energy Rev. 15(8), 4212–4222 (2011)
Zhang, W.: Automotive fuels from biomass via gasification. Fuel Process. Technol. 91(8), 866–876 (2010)
Richardson, Y., Drobek, M., Julbe, A., Blin, J., Pinta, F.: Chapter 8—Biomass Gasification to Produce Syngas. In: Pandey, A., Bhaskar, T., Stöcker, M., Sukumaran, R.K. (eds.) Recent Advances in Thermo-Chemical Conversion of Biomass, pp. 213–250. Elsevier, Boston (2015)
Rios, M.L.V., González, A.M., Lora, E.E.S., del Olmo, O.A.A.: Reduction of tar generated during biomass gasification: a review. Biomass Bioenergy 108, 345–370 (2018)
Woolcock, P.J., Brown, R.C.: A review of cleaning technologies for biomass-derived syngas. Biomass Bioenergy 52, 54–84 (2013)
Bartels, M., Lin, W., Nijenhuis, J., Kapteijn, F., van Ommen, J.R.: Agglomeration in fluidized beds at high temperatures: mechanisms, detection and prevention. Prog. Energy Combust. Sci. 34(5), 633–666 (2008)
DD CEN/TS 15439: Biomass gasification—Tar and particles in product gases—Sampling and analysis. https://shop.bsigroup.com/ProductDetail/?pid=000000000030163214 (2006) Accessed Mar 2007
Sigma-Aldrich: Gas sampling bags and samplers. https://www.sigmaaldrich.com/analytical-chromatography/air-monitoring/gas-sampling-bags.html#foilbags. Accessed Mar 2018
Restek: Sacs Tedlar. http://www.restek.fr/catalog/view//22052-3795. Accessed March 2018
Poole, C.F.: Gas Chromatography. 1st edn. Elsevier (2012)
Ephraim, A.: Valorization of wood and plastic waste by pyro-gasification and syn-gas cleaning. Ph.D. Thesis, Ecole nationale des Mines d’Albi-Carmaux, France (2016)
Andersson, R., Boutonnet, M., Järås, S.: On-line gas chromatographic analysis of higher alcohol synthesis products from syngas. J. Chromatogr. A 1247, 134–145 (2012)
Rauch, R., Bosch, K., Hofbauer, H., Świerczyński, D., Courson, C., Kiennemann, A.: Comparison of different olivines for biomass steam gasification, pp. 799–809. CPL Press (2004)
Kübel, M.: Teerbildung und Teerkonversion bei der Biomassevergasung—Anwen-dung der nasschemischen Teerbestimmung nach CEN-Standard. Cuvillier Verlag (2007)
Neubert, M., Reil, S., Wolff, M., Pöcher, D., Stork, H., Ultsch, C., Meiler, M., Mes-ser, J., Kinzler, L., Dillig, M., Beer, S., Karl, J.: Experimental comparison of solid phase adsorption (SPA), activated carbon test tubes and tar protocol (DIN CEN/TS 15439) for tar analysis of biomass derived syngas. Biomass Bioenergy 105, 443–452 (2017)
Brage, C., Sjöström, K.: An outline of R&D work supporting the tar guideline. Royal Institute of Technology (KTH). Technical report (2002)
Prando, D., Shivananda Ail, S., Chiaramonti, D., Baratieri, M., Dasappa, S.: Characterisation of the producer gas from an open top gasifier: assessment of different tar analysis approaches. Fuel 181, 566–572 (2016)
van de Kamp, W., de Wild, P., Zielke, U., Suomalainen, M., Knoef, H., Good, J., Liliedahl, T., Unger, C., Whitehouse, M., Neeft, J., van de Hoek, H., Kiel, J.: Tar measurement standard for sampling and analysis of tars and particles in biomass gasification product gas. In: 4th European Biomass Conference and Exhibition, Paris, France (2015)
Grootjes, A. J.: Tar measurement by the Solid Phase Adsorption (SPA) method. In: 19th European Biomass Conference and Exhibition (2011)
Israelsson, M., Seemann, M., Thunman, H.: Assessment of the solid-phase adsorption method for sampling biomass-derived tar in industrial environments. Energy Fuels 27(12), 7569–7578 (2013)
Osipovs, S.: Comparison of efficiency of two methods for tar sampling in the syn-gas. Fuel 103, 387–392 (2013)
Engvall, K., Whitty, K.: Measurement and characterization of tars using the spa method: on-going developments on tar analysis. In: Workshop IEA Bioenergy Task 33, Lucerne University of Applied Sciences (2016)
Hasler, P., Nussbaumer, T.: Sampling and analysis of particles and tars from bio-mass gasifiers. Biomass Bioenergy 18(1), 61–66 (2000)
Brage, C., Yu, Q.C., Chen, G., Sjöström, K.: Tar evolution profiles obtained from gasification of biomass and coal. Biomass Bioenergy 18(1), 87–91 (2000)
Brage, C., Yu, Q.C., Chen, G., Sjöström, K.: Use of amino phase adsorbent for biomass tar sampling and separation. Fuel 76(2), 137–142 (1997)
Dufour, A., Girods, P., Masson, E., Normand, S., Rogaume, Y., Zoulalian, A.: Comparison of two methods of measuring wood pyrolysis tar. J. Chromatogr. A 1164(1), 240–247 (2007)
Reil, S., Karl, J., Beer, S.: Impact of gasification conditions on the tar yield of stratified downdraft gasifiers. In: Papers of the 22nd European Biomass Conference, 585–590 (2014)
Osipovs, S.: Sampling of benzene in tar matrices from biomass gasification using two different solid-phase sorbents. Anal. Bioanal. Chem. 391(4), 1409–1417 (2008)
González, I.O., Pastor, R.M.P., Hervás, J.M.S.: Sampling of tar from sewage sludge gasification using solid phase adsorption. Anal. Bioanal. Chem. 403(7), 2039–2046 (2012)
Sun, R., Zobel, N., Neubauer, Y., Cardenas Chavez, C., Behrendt, F.: Analysis of gas-phase polycyclic aromatic hydrocarbon mixtures by laser-induced fluorescence. Opt. Lasers Eng. 48(12), 1231–1237 (2010)
Carpenter, D.L., Deutch, S.P., French, R.J.: Quantitative measurement of biomass gasifier tars using a molecular-beam mass spectrometer: comparison with traditional impinger sampling. Energy Fuels 21(5), 3036–3043 (2007)
Fendt, A., Streibel, T., Sklorz, M., Richter, D., Dahmen, N., Zimmermann, R.: On-line process analysis of biomass flash pyrolysis gases enabled by soft photoionization mass spectrometry. Energy Fuels 26(1), 701–711 (2012)
Neubauer, Y.: Online-analyse von teer aus der biomassevergasung mit lasermassen-spektrometrie. Ph.D. Thesis, Technische Universität Berlin, Berlin (2008)
Defoort, F., Thiery, S., Ravel, S.: A promising new on-line method of tar quantification by mass spectrometry during steam gasification of biomass. Biomass Bioenergy 65, 64–71 (2014)
Ahmadi, M., Knoef, H., Van de Beld, B., Liliedahl, T., Engvall, K.: Development of a PID based on-line tar measurement method—Proof of concept. Fuel 113, 113–121 (2013)
Gredinger, A., Spörl, R., Scheffknecht, G.: Comparison measurements of tar content in gasification systems between an online method and the tar protocol. Biomass Bioenergy 111 (2017)
Abdoulmoumine, N., Adhikari, S., Kulkarni, A., Chattanathan, S.: A review on biomass gasification syngas cleanup. Appl. Energy 155, 294–307 (2015)
Chiche, D., Diverchy, C., Lucquin, A.-C., Porcheron, F., Defoort, F.: Synthesis Gas Purification. Oil Gas Sci. Technol. Rev. D’IFP Energ. Nouv 8(4), 707–723 (2013)
Hoekman, S.K., Robbins, C., Wang, X., Zielinska, B., Schuetzle, D., Schuetzle, R.: Characterization of trace contaminants in syngas from the thermochemical conversion of biomass. Biomass Convers. Biorefinery 3(4), 271–282 (2013)
Norton, G.A., Brown, R.C.: Wet chemical method for determining levels of ammonia in syngas from a biomass gasifier. Energy Fuels 19(2), 618–624 (2005)
Stahlberg, P., Lappi, M., Kurkela, E., Simell, P., Oesch, P.: Sampling of Contaminants from Biomass Gasifiers. IEA Thermal Gasification of Biomass Task. Brussels, Belgium (1998)
Zhou, J., Masutani, S.M., Ishimura, D.M., Turn, S.Q., Kinoshita, C.M.: Release of fuel-bound nitrogen during biomass gasification. Ind. Eng. Chem. Res. 39(3), 626–634 (2000)
De Jong, W., Ünal, Ö., Andries, J., Hein, K.R.G., Spliethoff, H.: Biomass and fossil fuel conversion by pressurised fluidised bed gasification using hot gas ceramic filters as gas cleaning. Biomass Bioenergy 25(1), 59–83 (2003)
Agilent Technologies Inc.: Dual Plasma Sulfur and Nitrogen Chemiluminescence Detectors Dual Plasma Technology Dual Plasma Burner and Controller. https://www.agilent.com/cs/library/selectionguide/public/5989-6119EN.pdf (2006). Accessed 9 Jan 2018
Broer, K.M., Johnston, P.A., Haag, A., Brown, R.C.: Resolving inconsistencies in measurements of hydrogen cyanide in syngas. Fuel 140, 97–101 (2015)
Vriesman, P., Heginuz, E., Sjöström, K.: Biomass gasification in a laboratory-scale AFBG: influence of the location of the feeding point on the fuel-N conversion. Fuel 79(11), 1371–1378 (2000)
Cui, H., Turn, S.Q., Keffer, V., Evans, D., Tran, T., Foley, M.: Contaminant estimates and removal in product gas from biomass steam gasification. Energy Fuels 24(2), 1222–1233 (2010)
Meng, X.: Biomass gasification: The understanding of sulfur, tar, and char reaction in fluidized bed gasifiers. In: TU Delft Repositories, Delft University of Technology (2012)
Balas, M., Lisy, M., Skala, Z., Jiri, P.: Wet scrubber for cleaning of syngas from bi-omass gasification. Adv. Environ. Sci. Dev. Chem. 195–201 (2014)
ECN: Biomass gasification—Tar and particles in product gases—Sampling and analysis. http://www.eeci.net/results/pdf/CEN-Tar-Standard-draft-version-2_1-new-template-version-05-11-04.pdf (2004). Accessed 10 Oct 2004
Gustafsson, E.: Characterization of particulate matter from atmospheric fluidized bed biomass gasifiers. Doctoral Dissertation, Linnaeus University (2011)
Akudo, C.O., Theegala, C.S.: Quantification of tars, particulates, and higher heating values in gases produced from a biomass gasifier. BioResources 9(3), 5627–5635 (2014)
Wang, Robbins, C., Hoekman, S.K., Chow, J.C., Watson, J.G., Schuetzle, D.: Dilution sampling and analysis of particulate matter in biomass-derived syngas. Front. Environ. Sci. Eng. China 5(3), 320–330 (2011)
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Ephraim, A., Munirathinam, R., Nzihou, A., Pham Minh, D., Richardson, Y. (2020). Syngas. In: Nzihou, A. (eds) Handbook on Characterization of Biomass, Biowaste and Related By-products. Springer, Cham. https://doi.org/10.1007/978-3-030-35020-8_11
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DOI: https://doi.org/10.1007/978-3-030-35020-8_11
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