Abstract
Copper and manganese additives for pressureless sintering of Ce-TZP have been studied, the former because its atomic radius is close to that of Ce4+, the latter because its atomic radius is close to that of Zr4+. The temperature at which shrinkage begins did not decrease when using CuO or MnO2, but at a given temperature, the sintering rate was higher. CuO and MnO2 were also very effective in improving both the tetragonal phase content retained at room temperature and the mechanical properties (hardness, bending strength and toughness).
Similar content being viewed by others
References
R. L. K. Matsumoto, J. Amer. Ceram. Soc. 71 (1978) C128.
K. Tsukuma and M. Shimada, J. Mater. Sci. 20 (1985) 1178.
S. Meriani, Mater. Sci. Engng 71 (1985) 369.
T. Sato, T. Endo and M. Shimada, in “Zirconia.'88: Advances in Zirconia Science and Technology”, edited by S. Meriani and C. Palmonari, (Eisevier Applied Science, London, 1989) pp. 293–300.
L. Pauling, “The nature of the Chemical Bond” (Cornell University Press, Ithaca, NY, 1940).
F. F. Lange and M. M. Hirlinger, J. Amer. Ceram. Soc. 67 (1984) 164.
R. C. Garvie and P. S. Nicholson, J. Amer. Ceram. Soc. 55 (1972) 303.
R. J. Brook, in “Science and technology of zirconia”, edited by A. H. Heuer and L. W. Hobbs (American Ceramic Society, Columbus, OH, 1981) pp. 272.
S. Wu and R. J. Brook, Trans. J. Ceram. Soc. 82 (1983) 200.
H. M. Cahn, Acta Metall. 10 (1962) 789.
R. H. J. Hannink and M. Swain, J. Amer. Ceram. Soc. 72 (1989) 90.
P. E. Reyes-Morel, J. S. Cherng and I. Chen, ibid. 71 (1989) 648.
C. Schmid, H. Schubert, S. Meriani, “The role of alumina in zirconia-ceria composite alloys”, “Euro Ceramics” Vol. 1, edited by G. de With, R. A. Terpstra and R. Metselaar (Elsevier Applied Science, London, NY, 1989) pp. 1547–53.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Maschio, S., Sbaizero, O., Meriani, S. et al. Sintering aids for ceria zirconia alloys. J Mater Sci 27, 2734–2738 (1992). https://doi.org/10.1007/BF00540698
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF00540698