Skip to main content
SpringerLink
Log in

Hydrotalcite-like compounds obtained by anion exchange reactions

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The synthesis of nickel aluminium hydroxypicrate, [Ni3Al(OH)8] (C6O7N3H2)·nH 2O, and lithium aluminium hydroxypicrate, [Al2Li(OH)6] (C6O7N3H2)·nH 2O by anion exchange is described. Picric acid and the corresponding hydroxycarbonates were used as starting materials. The new compounds were characterized by chemical analyses, electron microscopy, infrared spectroscopy and X-ray diffraction. The results obtained indicate that both are hydrotalcite-like compounds where the picrate anion lies between the basic layers. The thermal decomposition of the compounds was studied by differential thermal and thermogravimetric analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. Allmann, Acta Crystallogr. B24 (1968) 972.

    Article  Google Scholar 

  2. H. F. W. Taylor, Mineral. Mag. 39 (1973) 377.

    Article  CAS  Google Scholar 

  3. S. Miyata, Clays & Clay Miner. 23 (1975) 369.

    Article  CAS  Google Scholar 

  4. C. J. Serna, J. L. Rendon and J. E. Iglesias, ibid. 30 (1982) 180.

    Article  CAS  Google Scholar 

  5. M. J. Hernandez, M. A. Ulibarri, J. L. Rendon and C. J. Serna, Phys. Chem. Miner. 12 (1985) 34.

    Google Scholar 

  6. I. Sissoko, E. T. Iyagba, R. Sahai and P. Biloen, J. Solid State Chem. 60 (1985) 283.

    Article  CAS  Google Scholar 

  7. D. L. Bish, Bull. Mineral. 103 (1980) 170.

    CAS  Google Scholar 

  8. S. Miyata, Clays & Clay Miner. 31 (1983) 305.

    Article  CAS  Google Scholar 

  9. M. A. Ulibarri, M. J. Hernandez, J. Cornejo and C. J. Serna, Mater. Chem. Phys. 14 (1986) 569.

    Article  CAS  Google Scholar 

  10. T. Kown, G. A. Tsigdinos and T. J. Pinnavaia, J. Amer. Chem. Soc. 110 (1988) 3653.

    Article  Google Scholar 

  11. E. Suzuki, S. Idemura and Y. Ono, Clays & Clay Miner. 37 (1989) 173.

    Article  CAS  Google Scholar 

  12. M. J. Hernandez, M. A. Ulibarri, J. L. Rendon and C. J. Serna, Thermochim. Acta 81 (1984) 311.

    Article  CAS  Google Scholar 

  13. M. A. Ulibarri, J. Cornejo and M. J. Hernandez, J. Mater. Sci. 22 (1987) 1168.

    Article  CAS  Google Scholar 

  14. A. Schutz and P. Biloen, J. Solid State Chem. 68 (1987) 360.

    Article  CAS  Google Scholar 

  15. E. Pretsch, T. Clerc, J. Seibl and W. Simon, “Tablas para la elucidación estructural de compuestos orgánicos por métodos espectroscópicos” (Alhambra, Madrid, 1980).

    Google Scholar 

  16. M. J. Hernandez, minor thesis, Cordoba, Spain, 1982.

  17. M. A. Ulibarri, J. M. Luque and J. Cornejo, Mater. Chem. Phys. 25 (1990) 81.

    Article  CAS  Google Scholar 

  18. G. Mascolo, Thermochim. Acta 102 (1986) 67.

    Article  CAS  Google Scholar 

  19. K. R. Poeppelmeier and S.-J. Hwu, Inorg. Chem. 26 (1987) 3297.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Departamento de Química Inorgánica e Ingeniería Química, Facultad de Ciencias, Universidad de Córdoba, 14004, Córdoba, Spain

    M. A. Ulibarri & M. J. Hernandez

  2. Instituto de Recursos Naturales y Agrobiologia, CSIC, Sevilla, Spain

    J. Cornejo

Authors
  1. M. A. Ulibarri
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. J. Hernandez
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. Cornejo
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ulibarri, M.A., Hernandez, M.J. & Cornejo, J. Hydrotalcite-like compounds obtained by anion exchange reactions. J Mater Sci 26, 1512–1516 (1991). https://doi.org/10.1007/BF00544660

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00544660

Keywords

Search

Navigation