Abstract
4Ni–Al layered double hydroxide (LDH) precursors were prepared by the following three methods: constant pH coprecipitation, variable pH coprecipitation and urea hydrolysis. The 4Ni–Al mixed metal oxide (MMO) catalysts were obtained by the calcination of LDH precursors at 600 °C, and their catalytic performances in ODHP from 350 to 550 °C were tested. The 4Ni–Al MMO from the urea hydrolysis method showed a higher and more stable propylene selectivity of ca. 40% with propylene yield of ca.11% at 500 °C, and that from the constant pH coprecipitation method was followed, while oxidative cracking of propane occurred on the 4Ni–Al MMO from the variable pH coprecipitation method. It is considered to be closely related to the dispersion and stability of the surface Ni(II) species through comprehensive analysis of XRD, N2-adsorption-desorption, TEM, XPS, H2-TPR and In-situ electrical conductivity. The urea hydrolysis method with a low salt concentration, leading to an excellent stability of the surface Ni(II) species at high reaction temperature, should be selected to prepare Ni–Al MMO catalysts for ODHP instead of the traditional variable pH coprecipitation method with a high salt concentration.
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Fan XQ, Liu DD, Zhao Z, Li JM, Liu J (2020) Catal Today 339:67–78
Wang L, Chu W, Jiang CF, Liu YF, Wen J, Xie ZK (2012) J Nat Gas Chem 21:43–48
Sattler JJHB, Ruiz-Martinez J, Santillan-Jimenez E, Weckhuysen BM (2014) Chem Rev 114:10613–10653
Védrine JC, Fechet I (2016) C R Chimie 19:1203–1225
Rostom S, de Lasa HI (2017) Ind Eng Chem Res 56:13109–13124
Fang KG, Liu LL, Zhang MW, Zhao L, Zhou J, Li WB, Mu XL, Yang C (2018) Catalysts 8:19–30
Grabowski R (2006) Catal Rev 48:199–268
Li ZY, Peters AW, Platero-Prats AE, Liu J, Kung CW, Noh H, De Stefano MR, Schweitzer NM, Chapman KW, Hupp JT, Farha OK (2017) J Am Chem Soc 139:15251–15258
Sun M, Zhang J, Putaj P, Caps V, Lefebvre F, Pelletier J, Basset JM (2014) Chem Rev 114:981–1019
Vedrine JC (2016) J Energy Chem 25:936–946
D’Alnoncourt RN, Csepei LI, Hävecker M, Girgsdies F, Schuster ME, Schlögl R, Trunschke A (2014) J Catal 311:369–385
Liu QL, Li JM, Zhao Z, Gao ML, Kong L, Liu J, Wei YC (2016) J Catal 344:38–52
Xie QH, Zhang HM, Kang JC, Cheng J, Zhang QH, Wang Y (2018) ACS Catal 8:4902–4916
Dula R, Wcisło K, Stoch J, Grzybowska B, Serwicka EM, Kooli F, Bahranowski K, Gaweł A (2002) Appl Catal A 230:281–291
Smoláková L, Čapek L, Botková Š, Kovanda F, Bulánek R, Pouzar M (2011) Top Catal 54:1151–1162
Valverde JA, Echavarría A, Ribeiro MF, Palacio LA, Eon JG (2012) Catal Today 192:36–43
Huang MX, Wu X, Yi XD, Han GB, Xia WS, Wan HL (2017) RSC Adv 7:14846–14856
Álvarez MG, Urdă A, Rives V, Carrazán SR, Martín C, Tichit D, Marcu IC (2018) C R Chimie 21:210–220
Mitran G, Cacciaguerra T, Loridant S, Tichit D, Marcu IC (2012) Appl Catal A 417:153–162
Skoufa Z, Xantri G, Heracleous E, Lemonidou AA (2014) Appl Catal A 471:107–117
Xu M, Wei M (2018) Adv Funct Mater 28:1802943–1802962
Lv Z, Duan X (2008) Chin J Catal 29:839–856
Zhao SZ, Yi HH, Tang XL, Kang DJ, Gao FY, Wang JG, Huang YH, Yang ZY (2018) J Hazard Mater 344:797–810
Lin GH, Zhu L, Duan T, Zhang L, Liu B, Lei JH (2019) Chem Eng J 378:122181–122188
Jing C, Huang YC, Xia LH, Chen YX, Wang X, Liu XY, Dong BQ, Dong F, Li SC, Zhang YX (2019) Appl Surf Sci 496:143700–143709
Li T, Miras HN, Song YF (2017) Catalysts 7:260–276
Munonde TS, Zheng H, Nomngongo PN (2019) Ultrason Sonochem 59:104716–104724
Seida Y, Nakano Y, Nakamura Y (2002) Clay Miner 50:525–532
Milagres JL, Bellato CR, Ferreira SO, Guimarães LDM, Tonon GJDP, Bolandini A (2019) Colloids Surf A 582:123890–123901
Bendinelli EV, Aoki IV, Barcia O, Margarit-Mattos ICP (2019) Mater Chem Phys 238:121883–121893
Zhaorigetu B, Li WZ, Xu HY, Kieffer R (2004) Catal Lett 94:125–129
Zhao L, Li X, Quan X, Chen GH (2011) Environ Sci Technol 45:5373–5379
Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KS (2015) Pure Appl Chem 87:1051–1069
Kovanda F, Rojka T, Bezdička P, Jirátová K, Obalová L, Pacultová K, Bastl Z, Grygar T (2009) J Solid State Chem 182:27–36
Zhao L, Duan J, Yang SW, Li XY, Liu QF, Martyniuk CJ (2018) Sep Purif Technol 207:231–239
Rotan M, Tolchard J, Rytter E, Einarsrud MA, Grande T (2009) J Solid State Chem 182:3412–3415
Jitianu M, Balastu M, Marchidan R, Zaharescu M, Crisan D, Craiu M (2000) Int J Inorg Mater 2:287–300
Huang PP, Cao CY, Wei F, Sun YB, Song WG (2015) RSC Adv 5:10412–10417
Duan X, Evans DG (2006) Layered Double Hydroxides, 1st edn. Publisher, Springer, pp 1–87
Zhang T, Li QR, Xiao HY, Lu HX, Zhou YM (2012) Ind Eng Chem Res 51:11490–11498
Solsona B, Nieto JML, Concepción P, Dejoz A, Ivars F, Vazquez MI (2011) J Catal 280:28–39
Solsona B, Concepción P, Demicol B, Hernández S, Delgado JJ, Calvino JJ, Nieto JML (2012) J Catal 295:104–114
Heracleous E, Lee AF, Wilson K, Lemonidou AA (2005) J Catal 231:159–171
Biju V, Khadar MA (2002) J Nanopart Res 4:247–253
Van Veenendaal MA, Alders D, Sawatzky GA (1995) Phys Rev B 51:13966–13971
Alders D, Voogt FC, Hibma T, Sawatzky GA (1996) Phys Rev B 54:7716–7719
Van Veenendaal MA, Sawatzky GA (1993) Phys Rev Lett 70:2459–2462
Wang J, Lang XJ, Zhaorigetu B, Jia ML, Wang J, Guo XF, Zhao JC (2014) ChemCatChem 6:1737–1747
Ivan ŞB, Popescu I, Fechete I, Garin F, Pârvulescu VI, Marcu IC (2016) Catal Sci Technol 6:6953–6964
Popescu I, Heracleous E, Skoufa Z, Lemonidou A, Marcu IC (2014) Phys Chem Chem Phys 16:4962–4970
Skoufa Z, Heracleous E, Lemonidou AA (2015) J Catal 322:118–129
Popescu I, Skoufa Z, Heracleous E, Lemonidou AA, Marcu IC (2015) Phys Chem Chem Phys 17:8138–8147
Herrmann JM, Vernoux P, Béré KE, Abon M (1997) J Catal 167:106–117
Millet JMM (2006) Top Catal 38:83–92
Mars P, Van Krevelen DW (1954) Chem Eng Sci 3:41–59
Skoufa Z, Heracleous E, Lemonidou AA (2012) Catal Today 192:169–176
Acknowledgements
This research was supported by the Collaborative Innovation Center for Water Environmental Security of Inner Mongolia Autonomous Region (XTCX003), the Natural Science Foundation of Inner Mongolia Autonomous Region of China (2019MS02016), the University Science Research Project of Inner Mongolia Autonomous Region of China (NJZY19024) and Inner Mongolia Normal University Graduate Student’ Research & Innovation Fund (CXJJS18084).
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Gao, X., Wang, J., Xu, A. et al. Oxidative Dehydrogenation of Propane over Ni–Al Mixed Oxides: Effect of the Preparation Methods on the Activity of Surface Ni(II) Species. Catal Lett 151, 497–506 (2021). https://doi.org/10.1007/s10562-020-03317-6
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DOI: https://doi.org/10.1007/s10562-020-03317-6