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Extraction and characterization of indigenous Ethiopian castor oil bast fibre

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Abstract

Bast natural fibers have gained importance in the recent years mainly due to their ecofriendliness and their potential availability as raw materials for textile industries. In the present study extraction and characterization of fibers from the stem of Ethiopian indigenous castor oil plant is conducted for possible utilization in textile and related industrial applications. Among the different fiber extraction methods chemical retting using aqueous alkaline media (NaOH) is used for the extraction of the bast fiber. In this study the extraction was carried out by setting appropriate retting conditions of concentration of alkali, temperature and time. The extracted fibers for experimental analysis under the combined conditions were tested for chemical composition, gross morphology, mechanical and thermal properties. The analysis on chemical composition revealed that the castor oil bast [COB] fiber is composed of 64.5–67.3% cellulose, 16.4–21.5% hemicellulose, 15.8–17.2% lignin, 0.3–0.9% extractive with 4.9–5.3% ash content. FTIR spectra of the extracted fibers also confirmed the presence of cellulose, hemicellulose, lignin and extractives. Analysis on dimensional characteristics of the fiber showed that the extracted fiber has a diameter of 14.2–30.8 µm and fineness of 4.5–13.5 tex with fiber length ranging from 1.3 to 10 cm; the moisture content and moisture regain of the fiber are 7.0–9% and 8.1–10% respectively. Tests on mechanical properties of the extracted COB fiber show a tensile strength of 250–700 MPa with tenacity in the range of 57.80–86.89 cN/tex, elongation of 1.2–5% and elastic modulus of 2114.55–2625.44 cN/tex. TGA results for thermal property analysis indicated that the COB fiber has very good thermal stability with a thermal decomposition temperature in the range of 386.5–498.9 °C. The reasonably high cellulose content, good dimensional and moisture characteristics of COB fiber and its very good mechanical and thermal properties in comparison with conventional natural fibers such as jute, flax, hemp and cotton indicate the possibility for versatile conventional and non-conventional applications of COB fiber such as in textiles and in fiber reinforced composites.

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References

  • Adeeyo O, Oresegun OM, Oladimeji TE (2015) Compositional analysis of lignocellulosic materials: evaluation of an economically viable method suitable for woody and non-woody biomass. Am J Eng Res (AJER) 4:14–19

    Google Scholar 

  • Alemaw G, Mengesha Kassahun B, Taye G, Endalamaw C (2014) Phenotypic variability in Ethiopian castor (Ricinus communis L.) accessions. Int J Adv Biol Biomed Res (IJABBR) 2:2909–2914

    Google Scholar 

  • Alix S, Marais S, Morvan C, Lebrun L (2008) Biocomposite materials from flax plants: preparation and properties. Compos A Appl Sci Manuf 39:1793–1801

    Article  Google Scholar 

  • Altaher AA (2014) Preparation of poly-anhydride from azelaic acid. Sudan University of Science and Technology, Khartoum

    Google Scholar 

  • Anwar A (2014) Recovery of an early evidence of castor plant, Ricinus communis L. from the Central Sudan and its positioning within a world-wide context. J Arts Soc Sci [JASS] 5:45–73

    Article  Google Scholar 

  • Ashraf MA, Zwawi M, Taqi Mehran M, Kanthasamy R, Bahadar A (2019) Jute based bio and hybrid composites and their applications. Fibers 7:77

    Article  CAS  Google Scholar 

  • Bakar NA, Sultan MTH, Azni ME, Hazwan MH, Ariffin AH (2018) Extraction and surface characterization of novel bast fibers extracted from the Pennisetum purpureum plant for composite application. Mater Today Proc 5:21926–21935

    Article  CAS  Google Scholar 

  • Chain TV (2019) Processing of castor oil fibers in textile industries. Taiwan Textiles Sustainable Innovation.

  • Chen J, Liu F, Tang Y, Yuan Y, Guo Q (2014) Transcriptome sequencing and profiling of expressed genes in phloem and xylem of ramie (Boehmeria nivea L. Gaud). PLoS ONE 9:e110623

    Article  Google Scholar 

  • Co SA (2003) Aldrich handbook of fine chemicals and laboratory equipment. Sigma-Aldrich, St. Louis

    Google Scholar 

  • Coats A, Redfern J (1963) Thermogravimetric analysis. A review. Analyst 88:906–924

    Article  CAS  Google Scholar 

  • Dai D, Fan M (2010) Characteristic and performance of elementary hemp fibre. Mater Sci Appl 1:336

    CAS  Google Scholar 

  • García-García D, Balart R, Lopez-Martinez J, Ek M, Moriana R (2018) Optimizing the yield and physico-chemical properties of pine cone cellulose nanocrystals by different hydrolysis time. Cellulose 25:2925–2938

    Article  Google Scholar 

  • Gebino G, Muhammed N (2018) Extraction and characterization of Ethiopian pineapple leaf fiber

  • Gómez JJM, Saadaoui E, Cervantes E (2016) Seed shape of castor bean (Ricinus communis L.) grown in different regions of Tunisia. J Agric Ecol Res Int 8:1–11

    Google Scholar 

  • Harzallah O, Benzina H, Drean J (2010) Physical and mechanical properties of cotton fibers: single-fiber failure. Text Res J 80:1093–1102

    Article  CAS  Google Scholar 

  • Hernandez A, Westerhuis W, Van Dam JE (2007) Microscopic study on hemp bast fibre formation. J Nat Fibers 3:1–12

    Article  Google Scholar 

  • Jung MR, Horgen FD, Orski SV, Rodriguez V, Beers KL, Balazs GH, Jones TT, Work TM, Brignac KC, Royer S-J (2018) Validation of ATR FT-IR to identify polymers of plastic marine debris, including those ingested by marine organisms. Mar Pollut Bull 127:704–716

    Article  CAS  Google Scholar 

  • Kale RD, Alemayehu TG, Gorade VG (2018) Extraction and characterization of lignocellulosic fibers from girardinia bullosa (Steudel) wedd. (Ethiopian Kusha Plant). J Nat Fibers 17:906–920

    Article  Google Scholar 

  • Koiel S (2011) Sues science and history, more about bast fiber plants

  • Konczewicz W, Zimniewska M, Valera MA (2018) The selection of a retting method for the extraction of bast fibers as response to challenges in composite reinforcement. Text Res J 88:2104–2119

    Article  CAS  Google Scholar 

  • Malkapuram R, Kumar V, Negi YS (2009) Recent development in natural fiber reinforced polypropylene composites. J Reinf Plast Compos 28:1169–1189

    Article  CAS  Google Scholar 

  • Mohamed AL, Hassabo AG (2015) Flame retardant of cellulosic materials and their composites. In: Visakh PM, Arao Y (eds) Flame retardants. Springer, Berlin, pp 247–314

    Chapter  Google Scholar 

  • Morgan D, Barnes P, Charsley E, Rumsey J, Warrington S, Howes R, Jackson A, Raper E, Gardiner D, Baker RR (1984) Experimental techniques in thermal analysis. Anal Proc 21:3–13

    Article  CAS  Google Scholar 

  • Mubofu EB (2016) Castor oil as a potential renewable resource for the production of functional materials. Sustain Chem Process 4:1–12

    Article  Google Scholar 

  • Nakajima T, Kajiwara K, Mcintyre JE (1994) Advanced fiber spinning technology. Woodhead Publishing, Cambridge

    Google Scholar 

  • Oktaee J, Lautenschläger T, Günther M, Neinhuis C, Wagenführ A, Lindner M, Winkler A (2017) Characterization of willow bast fibers (Salix spp.) from short-rotation plantation as potential reinforcement for polymer composites. BioResources 12:4270–4282

    Article  CAS  Google Scholar 

  • Oushabi A, Sair S, Hassani FO, Abboud Y, Tanane O, El Bouari A (2017) The effect of alkali treatment on mechanical, morphological and thermal properties of date palm fibers (DPFs): study of the interface of DPF–Polyurethane composite. S Afr J Chem Eng 23:116–123

    Google Scholar 

  • Pejic BM, Kostic MM, Skundric PD, Praskalo JZ (2008) The effects of hemicelluloses and lignin removal on water uptake behavior of hemp fibers. Bioresour Technol 99:7152–7159

    Article  CAS  Google Scholar 

  • Punyamurthy R, Sampathkumar D, Srinivasa CV, Bennehalli B (2012) Effect of alkali treatment on water absorption of single cellulosic abaca fiber. BioResources 7:3515–3524

    CAS  Google Scholar 

  • Ray P, Datta M (2004) Jute in technical textile. In: 1st China international bast fibrous plants and textile conference (China)

  • Ray R, Das SN, Mohapatra A, Das HC (2020) Comprehensive characterization of a novel natural Bauhinia vahlii stem fiber. Polym Compos 41:3807–3816

    Article  CAS  Google Scholar 

  • Rihouey C, Paynel F, Gorshkova T, Morvan C (2017) Flax fibers: assessing the non-cellulosic polysaccharides and an approach to supramolecular design of the cell wall. Cellulose 24:1985–2001

    Article  CAS  Google Scholar 

  • Sadrmanesh V, Chen Y (2018) Simulation of tensile behavior of plant fibers using the discrete element method (DEM). Compos A Appl Sci Manuf 114:196–203

    Article  CAS  Google Scholar 

  • Sadrmanesh V, Chen Y (2019) Bast fibres: structure, processing, properties, and applications. Int Mater Rev 64:381–406

    Article  CAS  Google Scholar 

  • Salihu B, Gana A, Gbadeyan T, Alabi M (2014a) Castor oil plant (Ricinus communis L.): a potential oil crop for agribusiness in Africa. Int J Appl Res Technol 3:29–35

    Google Scholar 

  • Salihu B, Gana AK, Apuyor B (2014b) Castor oil plant (Ricinus communis L.): botany, ecology and uses. Int J Sci Res 3:1333–1341

    Google Scholar 

  • Sen T, Reddy HJ (2011) Various industrial applications of hemp, kinaf, flax and ramie natural fibres. Int J Innov Manag Technol 2:192

    Google Scholar 

  • Severino LS, Auld DL, Baldanzi M, Cândido MJ, Chen G, Crosby W, Tan D, He X, Lakshmamma P, Lavanya C (2012) A review on the challenges for increased production of castor. Agron J 104:853–880

    Article  Google Scholar 

  • Shah DU (2013) Developing plant fibre composites for structural applications by optimising composite parameters: a critical review. J Mater Sci 48:6083–6107

    Article  CAS  Google Scholar 

  • Sparnins E (2009) Mechanical properties of flax fibers and their composites. Luleå tekniska universitet

  • Summerscales J, Dissanayake NP, Virk AS, Hall W (2010) A review of bast fibres and their composites. Part 1—fibres as reinforcements. Compos A Appl Sci Manuf 41:1329–1335

    Article  Google Scholar 

  • Thomsen AB, Rasmussen S, Bohn V, Nielsen KV, Thygesen A (2005) Hemp raw materials: the effect of cultivar, growth conditions.

  • Vinayaka D, Guna V, Madhavi D, Arpitha M, Reddy N (2017) Ricinus communis plant residues as a source for natural cellulose fibers potentially exploitable in polymer composites. Ind Crops Prod 100:126–131

    Article  CAS  Google Scholar 

  • Yang H, Yan R, Chen H, Lee DH, Zheng C (2007) Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel 86:1781–1788

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors would like to acknowledge the Higher Education and TVET program Ethiopia-Phase 3, PE479-Higher Education, KFW Project No. 51235 and BMZ No. 201166305 for the financial support of this research.

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Correspondence to Terefe Belachew.

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Belachew, T., Gebino, G. & Haile, A. Extraction and characterization of indigenous Ethiopian castor oil bast fibre. Cellulose 28, 2075–2086 (2021). https://doi.org/10.1007/s10570-020-03667-9

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