Abstract
This work is focused on studying the chemical equilibrium phenomena of precursor solutions used to growth hybrid inorganic–organic MAPbI3 perovskite films. Special emphasis was made on the effect of important variables such as solvents type, ligands, temperature, and concentration on the chemical equilibrium and subsequent effect on film morphology. These results provided important information to develop a novel synthesis route based on chemical bath deposition (CBD) method that allowed to grow thin films of MAPbI3 with grain sizes greater than 10 μm and high degree of crystalline ordering, features that led to getting MAPbI3 films with improved stability. The proposed CBD method, in addition to being novel for the growth in solution of MAPbI3 thin films, is scalable, low cost, and promising, since it offers great prospects for the manufacture of highly stable perovskite hybrid solar cells.
Similar content being viewed by others
References
A. Binek, M.L. Petrus, N. Huber, H. Bristow, Y. Hu, T. Bein, P. Docampo, Appl. Mater. Interfaces 8(20), 12881–12886 (2016)
National Center for Photovoltaics at the National NREL, Research cell efficiency records. https://www.nrel.gov/pv/assets/pdfs/best-research-cell-efficiencies.20200925.pdf
J.P. Correa-Baena, M. Saliba, T. Buonassisi, M. Grätzel, A. Abate, W. Tress, A. Hagfeldt, Science 358, 739–744 (2017)
F. Matteocci, L. Cinà, E. Lamanna, S. Cacovich, G. Divitini, P.A. Midgley, C. Ducati, A. Di Carlo, Nano Energy 30, 162–172 (2016)
Y. Sun, X. Fang, Z. Ma, L. Xu, Y. Lu, Q. Yu, N. Yuan, J.J. Ding, J. Ding. Mater. Chem. C. 5, 8682–8687 (2017)
G. Liu, H. Zheng, X. Xu, L.-Z. Zhu, X. Zhang, X. Pan, Chem. Mater 30(21), 7691–7698 (2018)
C. Zhang, L. Gao, S. Teo, Z. Guo, Z. Xu, S. Zhao, T. Ma, Sustain. Energy Fuels 2, 2419–2428 (2018)
X. Li, J. Yang, Q. Jiang, H. Lai, S. Li, J. Xin, W. Chu, J. Hou, ACS Nano 12(6), 5605–5614 (2018)
S.N. Habisreutingera, D.P. McMeekin, H.J. Snaith, R.J. Nicholas, APL Mater. 4, 091503 (2016)
Q. Wang, B. Chen, Y. Liu, Y. Deng, Y. Bai, Q. Dong, J. Huang, Energy Environ. Sci. 10, 516–522 (2017)
X.Z. Chen, B. Turedi, A.Y. Alsalloum, C. Yang, X. Zheng, I. Gereige, A. AlSaggaf, O.F. Mohammed, O.M. Bakr, ACS Energy Lett. 4(6), 1258–1259 (2019)
J.C. Hamill Jr., J. Schwartz, Y.-L. Loo, Influence of solvent coordination on hybrid organic–inorganic Perovskite formation. ACS Energy Lett. 3(1), 92–97 (2018)
N.J. Jeon, J.H. Noh, Y.C. Kim, W.S. Yang, S. Ryu, S.I. Seok, Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells. Nat. Mater. 13, 897–903 (2014)
V. Gutmann, Coordination Chemistry in Non-Aqueous Solutions (Springer, Viena, 1968), p. 19
S. Paek, P. Schouwink, E.N. Athanasopoulou, K.T. Cho, G. Grancini, Y. Lee, Y. Zhang, F. Stellacci, M.K. Nazeeruddin, P. Gao, Chem. Mater. 29, 3490–3498 (2017)
M.I. Saidaminov, A.L. Abdelhady et al., Nat. Commun. 6(7586), 1–6 (2015)
D. Shi, V. Adinolfi, Sci. Rep. 347(6261), 519–522 (2015)
J.M. Frost, K.T. Butler, F. Brivio, C.H. Hendon, M. van Schilfgaarde, A. Walsh, Atomistic origins of high-performance in hybrid halide perovskite solar cells. Nano Lett. 14, 2584 (2014)
Acknowledgements
This work was supported by Colciencias (Contract #184/2016), Universidad Nacional de Colombia, Sede Bogotá, (Proy. 20287 supported by DIB), and Universidad Industrial de Santander (Postdoctoral supporting program of VIE).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Otálora, C.A., Gordillo, G., Herrera, L. et al. Effect of the solution chemistry on the film growth of hybrid MAPbI3 perovskites. J Mater Sci: Mater Electron 32, 6912–6918 (2021). https://doi.org/10.1007/s10854-021-05397-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-021-05397-5