Abstract
Co3O4 has been widely investigated as a promising candidate anode material for lithium-ion batteries. We report on the porous Co3O4 column synthesized via a simple liquid phase method for reversible electrochemical lithium storage. The porous column structures are constructed by nanoparticles of 0.5 μm -2 μm in diameter. The porous structure improves the structure stability, shortens the diffusion path of ion/electron, and stabilize the interface of the electrolyte and active material. Impressively, a high discharge capacity of 992 mAh g−1 is obtained at 200 mA g−1 after 100 cycles. This implies the as-synthesized porous Co3O4 column demonstrates remarkable potential as an excellent anode material for lithium-ion batteries.
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References
M.R. Palacín, Recent Advances in Rechargeable Battery Materials: A Chemist’s Perspective. Chem. Soc. Rev. 38, 2565–2575 (2009)
Y. Tang, Y. Zhang, W. Li, B. Ma, X. Chen, Rational Material Design for Ultrafast Rechargeable Lithium-ion Batteries. Chem. Soc. Rev. 44, 5926–5940 (2015)
G. Zhou, J. Ma, L. Chen, Selective Carbon Coating Techniques for Improving Electrochemical Properties of NiO Nanosheets. Electrochim. Acta. 133, 93–99 (2014)
X. Liu, J. Xu, M. Lin, Z. Zhan, C. Cui, H. Liu, J. Ma, S. Dou, Electrospinning of Crystalline MoO3@C Nanofibers for High-rate Lithium Storage. J. Mater. Chem. A 3, 3257–3260 (2015)
S. Zhang, Q. Fan, H. Gao, Y. Huang, X. Liu, J. Li, X. Xu, X. Wang, Formation of Fe3O4 @MnO2 Ball-in-ball Hollow Spheres as A High Performance Catalyst with Enhanced Catalytic Performances. J. Mater. Chem. A. 4, 1414–1422 (2016)
M. Jing, M. Zhou, G. Li, Z. Chen, W. Xu, X. Chen, Z. Hou, Graphene-Embedded Co3O4 Rose-Spheres for Enhanced Performance in Lithium Ion Batteries. ACS Appl. Mater. Interfaces. 9, 9662–9668 (2017)
J. Xie, L. Liu, J. Xia, Y. Zhang, M. Li, Y. Ouyang, S. Nie, X. Wang, Template-Free Synthesis of Sb2S3 Hollow Microspheres as Anode Materials for Lithium-Ion and Sodium-Ion Batteries. Nano-Micro Letters. 10, 105–116 (2018)
Z. Zhang, Li. Li, Qi. Xu, B. Cao, 3D Hierarchical Co3O4 Microspheres with Enhanced Lithium-ion Battery Performance. RSC Adv. 5, 61631–61638 (2015)
W. Kang, Yu. Zhang, L. Fan, L. Zhang, F. Dai, R. Wang, D. Sun, Metal-Organic Framework Derived Porous Hollow Co3O4/N-C Polyhedron Composite with Excellent Energy Storage Capability. ACS Appl. Mater. Interfaces. 9, 10602–10609 (2017)
L. Li, Z. Zichao, R. Sijia, Z. Bingke, Y. Shuhua, C. Bingqiang, Construction of Hollow Co3O4 Cubes as A High Performance Anode for Lithium Ion Batteries. New J. Chem. 41(16), 7960–7965 (2017)
Y. Li, B. Tan, Y. Wu, Mesoporous Co3O4 Nanowire Arrays for Lithium Ion Batteries with High Capacity and Rate Capability. Nano Lett. 8, 265–270 (2008)
D. Zhao, Q. Hao, C. Xu, Nanoporous TiO2/Co3O4 Composite as an Anode Material for Lithium-Ion Batteries. Electrochim. Acta. 211, 83–91 (2016)
B. Yan, L. Chen, Y. Liu, G. Zhu, H. Zhang, G. Yang, H. Ye, A. Yuan, Co3O4 Nanostructures with a High Rate Performance as Anode Materials for Lithium-ion Batteries, Prepared via Book-like Cobalt–organic Frameworks. CrystEngComm 16(44), 10227–10234 (2014)
D. Tian, X. Zhou, Y. Zhang, Z. Zhou, X. Bu, MOF-Derived Porous Co3O4 Hollow Tetrahedra with Excellent Performance as Anode Materials for Lithium-Ion Batteries. Inorg. Chem. 54, 8159–8161 (2015)
Y. Han, M. Zhao, L. Dong, J. Feng, Y. Wang, D. Li, X. Li, MOF-derived Porous Hollow Co3O4 Parallelepipeds for Building High-performance Li-ion Batteries. J. Mater. Chem. A. 3, 22542–22546 (2015)
Z. Li, X. Yu, U. Paik, Facile Preparation of Porous Co3O4 Nanosheets for High-performance Lithium Ion Batteries and Oxygen Evolution Reaction. J. Power Sources. 310, 41–46 (2016)
L. Jin, X. Li, H. Ming, H. Wang, Z. Jia, Fu, yu; Adkins, Jason; Zhou, qun; Zheng, Junwei; Hydrothermal Synthesis of Co3O4 with Different Morphologies Towards Efficient Li-ion Storage. RSC Adv. 4, 6083–6089 (2014)
Z. Zhang, L. Li, Q. Ren, Q. Xu, B. Cao, Hierarchical Co3O4 Nanowires as Binder Free Electrodes for Reversible Lithium Storage. Chin. J. Chem. 34(6), 631–636 (2016)
S. Chen, Y. Zhao, B. Sun, Z. Ao, X. Xiao, Y. Wei, G. Wang, Microwave-assisted Synthesis of Mesoporous Co3O4 Nanoflakes for Applications in Lithium Ion Batteries and Oxygen Evolution Reactions. ACS Appl. Mater. Interfaces 7, 3306–3313 (2015)
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This work was financially supported by (MPS) Technical Research Program (2015JSYJC26) and Cultivation Project of NSFC (ZRJJPY202101).
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Sun, J., Wang, H., Li, Y. et al. Porous Co3O4 column as a high-performance Lithium anode material. J Porous Mater 28, 889–894 (2021). https://doi.org/10.1007/s10934-021-01041-z
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DOI: https://doi.org/10.1007/s10934-021-01041-z