Abstract
The ZnFe2O4/C nanofibers were synthesized by electrospinning method combined with heat treatment. The crystal structure, elemental valence, and morphology of expected compounds were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and scanning electron microscopy (SEM) techniques, respectively. The electrochemical performances of ZnFe2O4/C were tested by battery comprehensive testing system. The test results showed that ZnFe2O4/C owned high specific capacities under different current densities. At current density of 0.2 A g−1, the specific capacity was 624.5 mAh g−1 after 100 cycles. And when current density was increased to 0.5 A g−1, its capacity could maintain at 479.3 mAh g−1 after 500 cycles. The ZnFe2O4/C exhibited excellent cycle stability, too. So the ZnFe2O4/C composite is a potential anode material for lithium ion battery application.
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Song J, Kim H, Jae W, Kim T, Futalan CM, Kim J (2020) Porous ZnO/C microspheres prepared with maleopimaric acid as an anode material for lithium-ion batteries. Carbon 165:55–66
Jin S, Wang C (2014) Synthesis and first investigation of excellent lithium storage performances of Fe2GeO4/reduced graphene oxide nanocomposite. Nano Energy 7:63–71
Yabuuchi N, Nakayama M, Takeuchi M, Komaba S, Yu H, Mukai T, Shiiba H, Sato K, Kobayashi Y, Nakao A, Yonemura M, Yamanaka K, Mitsuhara K, Ohta T (2016) Origin of stabilization and destabilization in solid-state redox reaction of oxide ions for lithium-ion batteries. Nat Commun 7:13816
Liu W, Yuanyuan F, Li Y, Chen S, Song Y, Wang L (2019) Three-dimensional carbon foam surrounded by carbon nanotubes and co-Co3O4 nanoparticles for stable lithium-ion batteries. Composites Part B 163:464–470
Huang R, Li Y, Liu W, Song Y, Wang L (2020) N-doped honeycomb-like carbon networks loaded with ultra-fine Fe2O3 nanoparticles for lithium-ion batteries. Ceram Int 46:17478–17485
Xiao F, Chen X, Zhang J, Huang C, Hu T, Hong B, Xu J (2020) Large-scale production of holey graphite as high-rate anode for lithium ion batteries. J Energy Chem 48:122–127
Angamuthu G, Rengarajan V (2020) MoS2 mediated nitrogen enriched composite material for high and fast Li-ion storage. Appl Surf Sci 525:146437
Yue L, Zhao H, Wu Z, Liang J, Lu S, Chen G, Gao S, Zhong B, Guo X, Sun X (2020) Recent advances in electrospun one-dimensional carbon nanofiber structures/heterostructures as anode materials for sodium ion batteries. J Mater Chem A 8:11493–11510
Xue J, Wu T, Dai Y, Xia Y (2019) Electrospinning and electrospun nanofibers: methods, materials, and applications. Chem Rev 119:5298–5415
Kim C, Yang KS, Kojima M, Yoshida K, Kim YJ, Kim YA, Endo M (2006) Fabrication of electrospinning-derived carbon nanofiber webs for the anode material of lithium-ion secondary batteries. Adv Funct Mater 16:2393–2397
Qiao L, Wang X, Qiao L, Sun X, Li X, Zheng Y, He D (2013) Single electrospun porous NiO–ZnO hybrid nanofibers as anode materials for advanced lithium-ion batteries. Nanoscale 5:3037–3042
Ren P, Wang Z, Liu B, Lu Y, Jin Z, Zhang L, Lu L, Li X, Wang C (2020) Highly dispersible hollow nanospheres organized by ultra-small ZnFe2O4 subunits with enhanced lithium storage properties. J Alloys Compd 812:152014
Wu J, Song Y, Zhou R, Chen S, Li Z, Hou H, Wang L (2015) Zn-Fe-ZIF-derived porous ZnFe2O4/C@NCNTs nanomposites as anode for lithium-ion batteries. J Mater Chem A 3:7793–7798
Wang J, Yang G, Wang L, Yan W (2016) Fabrication of the ZnFe2O4 fiber-in-tube and tubular mesoporous nanostructures via single-spinneret electrospinning: characterization, mechanism and performance as anodes for Li-ion batteries. Electrochim Acta 222:1176–1185
Wu L, Wu T, Mao M, Zhang M, Wang T (2016) Electrospinning synthesis of Ni°, Fe° codoped ultrafine-ZnFe2O4/C nanofibers and their properties for lithium ion storage. Electrochim Acta 194:357–366
Jiang Y, Chen S, Daobin M, Zhao Z, Li C, Ding Z, Xie C, Wu F (2018) Flexible TiO2/SiO2/C film anodes for lithium-ion batteries. ChemSusChem 11:2040–2044
Lin W, Moon K-S, Zhang S, Ding Y, Shang J, Chen M, Wong C-p (2010) Microwave makes carbon nanotubes less defective. ACS Nano 4:1716–1722
Bresser D, Paillard E, Kloepsch R, Krueger S, Fiedler M, Schmitz R, Baither D, Winter M, Passerini S (2013) Carbon coated ZnFe2O4 nanoparticles for advanced lithium-ion anodes. Adv Energy Mater 3:513–523
Yue H, yuehongyun QW, Shi Z, Ma C, Ding Y, Huo N, Zhang J, Yang S (2015) Porous hierarchical nitrogen-doped carbon coated ZnFe2O4 composites as high performance anode materials for lithium ion batteries. ElectrochimicaActa 180:622–628
Yu W, Jin Y, Zhang R, Ji M (2017) Facile synthesis of ZnFe2O4–graphene aerogels composites as high-performance anode materials for lithium ion batteries. Appl Surf Sci 413:50–55
Zhou G, Wang D-W, Li F, Zhang L, Li N, Wu Z-S, Wen L, Lu GQ(M), Cheng H-M (2010) Graphene-wrapped Fe3O4 anode material with improved reversible capacity and cyclic stability for lithium ion batteries. Chem Mater 22:5306–5313
Hao S, Zhang B, Ball S, Wu J, Srinivasan M, Huang Y (2016) Phase transition of hollow-porous α-Fe2O3 microspheres based anodes for lithium ion batteries during high rate cycling. J Mater Chem A 4:16569–16575
Li Y, Yuanyuan F, Chen S, Huang Z, Wang L, Song Y (2019) Porous Fe2O3/Fe3O4@carbon octahedron arrayed on three-dimensional graphene foam for lithium-ion battery. Composites Part B 171:130–137
Bai J, Chen X, Olsson E, Wu H, Wang S, Cai Q, Feng C (2020) Synthesis of Bi2S3/carbon nanocomposites as anode materials for lithium-ion batteries. J Mater Sci Technol 50:92–102
Liu Y, Yi-Jing G, Luo G-Y, Chen Z-L, Wu F-Z, Dai X-Y, Mai Y, Li J-Q (2020) Ni-doped LiFePO4/C as high-performance cathode composites for Li-ion batteries. Ceram Int 46:14857–14863
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This work was supported by the National Natural Science Foundation of China (NSFC−U1903217).
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Xiao, Y., Zhang, Z., Ma, Z. et al. Synthesis and electrochemical properties of ZnFe2O4/C as novel anode material for lithium ion battery. Ionics 27, 1377–1384 (2021). https://doi.org/10.1007/s11581-021-03931-3
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DOI: https://doi.org/10.1007/s11581-021-03931-3