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Local Electronic Structure in Ordered Aggregates of Carbon Nanotubes: Scanning Tunneling Microscopy/scanning Tunneling Spectroscopy Study

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Abstract

The recent application of tunneling probes in electronic structure studies of carbon nanotubes has proven both powerful and challenging. Using scanning tunneling microscopy (STM) and scanning tunneling spectroscopy (STS), local electronic properties in ordered aggregates of carbon nanotubes (multiwalled nanotubes and ropes of single walled nanotubes) have been probed. In this report, we present evidence for interlayer (concentric tube) interactions in multiwalled tubes and tube-tube interactions in singlewalled nanotube ropes. The spatially resolved, local electronic structure, as determined by the local density of electronic states, is shown to clearly reflect tube-tube interactions in both of these aggregate forms.

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References

  1. S. Iijima, Nature (London) 354, 56 (1991).

    Article  CAS  Google Scholar 

  2. T.W. Ebbesen and P. M. Ajayan, Nature (London) 358, 220 (1992).

    Article  CAS  Google Scholar 

  3. D. S. Bethune, C. H. Kiang, M. S. de Vires, G. Gorman, R. Savoy, J. Vazquez, and R. Beyers, Nature (London) 363, 605 (1993).

    Article  CAS  Google Scholar 

  4. S. Iijima and T. Ichihashi, Nature (London) 363, 603 (1993).

    Article  CAS  Google Scholar 

  5. M. S. Dresselhaus, G. Dresselhaus, P. Eklund, and R. Saito, Physics World, 33–38 (January, 1998).

  6. M. S. Dresselhaus, G. Dresselhaus, and P. Eklund, Science of Fullerenes and Carbon Nanotubes (Academic Press, New York, 1997).

    Google Scholar 

  7. A. Thess, R. Lee, P. Nikolaev, H. Dai, P. Petit, J. Robert, C. Xu, Y.H. Lee, S. G. Kim, A. G. Rinzler, D. T. Colbert, G. E. Scuseria, D. Tomanek, J. E. Fischer, and R. E. Smalley, Science 273, 483 (1996).

    Article  CAS  Google Scholar 

  8. P. Delaney, H. J. Choi, J. Ihm, S.G. Louie, and M.L. Cohen, Nature (London) 391, 466 (1998).

    Article  CAS  Google Scholar 

  9. D. L. Carroll, Ph. Redlich, P. M. Ajayan, J-C. Charlier, X. Blase, A. De Vita, and R. Car, Phys. Rev. Lett. 78, 2881 (1997).

    Article  Google Scholar 

  10. D. L. Carroll, Ph. Redlich, X. Blase, J-C. Charlier, S. Curran, P. M. Ajayan, S. Roth, and M. Rühle, unpublished.

  11. C. Journet, W. K. Maser, P. Bernier, A. Loiseau, M. Lamy della Chappelle, S. Lefrant, P. Deniard, R. Lee, and J.E. Fischer, Nature (London) 388, 756 (1997).

    Article  CAS  Google Scholar 

  12. Ph. Redlich, J. Loeffler, P. M. Ajayan, J. Bill, F. Aldinger, and M. Ruhle, Chem. Phys. Lett. 260, 465 (1996).

    Article  CAS  Google Scholar 

  13. T. R. Albrecht, H. A. Mizes, J. Nogami, S-I. Park, and C. Quate, Appl. Phys. Lett. 52, 362 (1988).

    Article  CAS  Google Scholar 

  14. S. Curran, D. L. Carroll, P. Redlich, P. M. Ajayan, S. Roth, and M. Rühle, Adv. Mater. 3 (4), 311 (1998).

    Article  Google Scholar 

  15. D. L. Carroll, P. Kinlen, S. Raman, P. Redlich, M. Rühle, X. Blase, J. C. Charlier, S. Curran, S. Roth, and P. M. Ajayan, in Molecular Nanostructures, edited by H. Kuzmany (World Scientific Publishers, Singapore, 1997), p. 290.

    Google Scholar 

  16. D. J. Keller and F. Franke, Surf. Sci. 294, 409 (1993); D. Keller, Surf. Sci. 253, (1991); G. Reiss, J. Vancea, H. Wittmann, J. Zweck, and H. Hoffmann, J. Appl. Phys. 67(3), 1156 (1990).

    Article  CAS  Google Scholar 

  17. Y. Liang, D. L. Carroll, and D. A. Bonnell, in Structure and Properties of Interfaces in Ceramics, edited by D. A. Bonnell, M. Rühle, and U. Chowdhry (Mater. Res. Soc. Symp. Proc. 357, Pittsburgh, PA, 1995), p. 3.

  18. For an excellent reference comparing the various spectroscopic techniques, see R. Wiesendanger, Scanning Probe Microscopy and Spectroscopy (Cambridge University Press, Cambridge, UK, 1994).

    Book  Google Scholar 

  19. R. M. Feenstra, Phys. Rev. B 50, 4561 (1994).

    Article  CAS  Google Scholar 

  20. D. Sarid, Exploring Scanning Probe Microscopy with Mathematica (John Wiley & Sons Publishers, New York, 1997).

    Google Scholar 

  21. J. Chen, Introduction to Scanning Tunneling Microscopy (Oxford University Press, New York, 1993), p. 301.

    Google Scholar 

  22. W. Rivera, J. Perez, R. Ruoff, D. Lorents, R. Malhotra, S. Lim, Y. Rho, E. Jacobs, and R. Pinizzotto, in Atomic Force Microscopy/Scanning Tunneling Microscopy, edited by S. Cohen (Plenum Press, New York, 1994), p. 137; M. Gallagher, D. Chen, B. Jacobsen, D. Sarid, L. Lamb, F. Tnkler, J. Jiao, D. Huffman, S. Seraphin, and D. Zhou, Surf. Sci. Lett. 281, L335 (1993); W. Rivera, J. Perez, R. Ruoff, D. Lorents, R. Malhotra, S. Lim, Y. Rho, E. Jacobs, and R. Pinizzotto, J. Vac. Sci. Technol. B 13, 327 (1995).

    Chapter  Google Scholar 

  23. C. Wang, X. Li, G. Shang, X. Qiu, and C. Bai, J. Vac. Sci. Technol. B 15, 1378 (1997).

    Article  CAS  Google Scholar 

  24. N. Holzwarth, S. Louie, and S. Rabii, Phys. Rev. B 26, 5382 (1982).

    Article  CAS  Google Scholar 

  25. T. Fauster, F. Himpsel, J. Fisher, and W. Plummer, Phys. Rev. Lett. 51, 430 (1983).

    Article  CAS  Google Scholar 

  26. B. Reihl, J. Gimzewski, J. Nichols, and E. Tosatti, Phys. Rev. B 33, 5770 (1986).

    Article  CAS  Google Scholar 

  27. H. Ajiki and T. Ando, Solid State Commun. 102, 135 (1997).

    Article  CAS  Google Scholar 

  28. J. W. G. Wildöer, L. Venema, A. Rinzler, R. Smalley, and C. Dekker, Nature (London) 391, 59 (1998); T. Odom, J. Huang, P. Kim, and C. Lieber, Nature (London) 391, 62 (1998).

    Article  Google Scholar 

  29. O. Stephan, P.M. Ajayan, C. Colliex, F. Cyrot-Lackman, and E. Sandre, Phys. Rev. B 53, 13 824 (1996).

    Article  CAS  Google Scholar 

  30. J-C. Charlier and J. P. Michenaud, Phys. Rev. Lett. 70, 1858 (1993).

    Article  CAS  Google Scholar 

  31. J-C. Charlier, X. Gonze, and J. P. Michenaud, Europhys. Lett. 29, 43 (1995).

    Article  CAS  Google Scholar 

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Carroll, D.L., Ajayan, P.M. & Curran, S. Local Electronic Structure in Ordered Aggregates of Carbon Nanotubes: Scanning Tunneling Microscopy/scanning Tunneling Spectroscopy Study. Journal of Materials Research 13, 2389–2395 (1998). https://doi.org/10.1557/JMR.1998.0332

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  • DOI: https://doi.org/10.1557/JMR.1998.0332

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