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Stability of single-wall carbon nanotubes under hydrothermal conditions

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Abstract

The stability of single-wall carbon nanotubes under hydrothermal conditions (100 MPa pressure, from 30 min to 48 h in the temperature range from 200 to 800 °C) has been investigated. The resultant products were characterized by Raman spectroscopy, x-ray diffraction, and transmission electron microscopy. The stability range of single-wall carbon nanotubes (SWCNTs) under hydrothermal conditions suggests that they, similar to fullerenes, can only survive mild and short-term treatment in high-temperature, high-pressure water. SWCNTs gradually transform into multiwall carbon nanotubes (MWCNTs) and polyhedral graphitic nanoparticules. After 48 h at 750 °C only the Raman spectra characteristic of graphitic carbon were observed. Transmission electron microscopy revealed that after 800 °C and 48 h of treatment SWCNTs fully transformed into MWCNTs and polyhedral carbon nanoparticles.

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References

  1. H.W. Kroto, J.R. Heath, S.C. O’Brien, R.F. Curl, and R.E. Smalley, Nature 318, 162 (1985).

    Article  CAS  Google Scholar 

  2. S. Iijima, Nature 354, 56 (1991).

    Article  CAS  Google Scholar 

  3. K. Livingston, Science., 268, 1637 (1995).

    Article  Google Scholar 

  4. A. Thess, R. Lee, P. Nikolaev, H. Dai, P. Petit, J. Robert, C. Xu, Y.H. Lee, S.G. Kim, A.G. Rintzler, D.T. Colbert, G. Scuseria, D. Tomanek, J.E. Fischer, and R.E. Smalley, Science 273, 483 (1996).

    Article  CAS  Google Scholar 

  5. M.S. Dresselhaus, G. Dresselhaus, and P.C. Eklund, Science of Fullerene and Carbon Nanotubes (Academic Press, New York, 1996).

    Google Scholar 

  6. M.S. Dresselhaus and G. Dresselhaus, Annu. Rev. Mater. Sci. 25, 487 (1995).

    Article  CAS  Google Scholar 

  7. R. Saito, M. Fujita, M.S. Dresselhaus, and G. Dresselhaus, Appl. Phys. Lett., 60, 2204 (1992).

    Article  CAS  Google Scholar 

  8. K. Tanaka, T. Yamabe, and K. Fukui, The Science and Technology of Carbon Nanotubes (Elsevier, Amsterdam, The Netherlands, 1999).

    Google Scholar 

  9. P.M. Ajayan and S. Iijima, Nature 361, 333 (1993).

    Article  CAS  Google Scholar 

  10. A.C. Dillon, K.M. Jones, T.A. Bekkadahl, C.H. Kiang, D.S. Bethune, and M.J. Heben, Nature 386, 377 (1997).

    Article  CAS  Google Scholar 

  11. C. Dekker, Physics Today 52, 22 (1999).

    Article  CAS  Google Scholar 

  12. J. Kong, H.T. Sog, A.M. Cassell, C.F. Quate, and H. Dai, Nature 395, 878 (1998).

    Article  CAS  Google Scholar 

  13. J. Lefebvre, J.F. Lynch, M. Llaguno, M. Radosavljevic, and A.T. Johnson, Appl. Phys. Lett. 75, 3014 (1999).

    Article  CAS  Google Scholar 

  14. H. Takahashi, B. Jeydevan, K. Tohji, I. Matsuoka, A. Kasuya, Y. Nishina, and T. Nirasawa, Proc. Electrochem. Soc. 96–10, 72 (1996).

    Google Scholar 

  15. H. Takahashi, T. Goto, Y. Akiyama, B. Jeyadevan, K. Tohji, and I. Matosuka, Mater. Sci. Eng. A 217/218, 42 (1996).

    Article  Google Scholar 

  16. K. Tohji, T. Goto, H. Takahashi, Y. Shindo, N. Shimizu, B. Jeyadevan, and I. Matsuoka, Nature 383, 679 (1996).

    Article  CAS  Google Scholar 

  17. K. Tohji, H. Takahashi, Y. Shinoda, B. Jeyadevan, I. Matsuoka, Y. Saito, A. Kasuya, S. Ito, and Y. Nishina, J. Phys. Chem. 101(11), 1974 (1997).

    Article  CAS  Google Scholar 

  18. J. Liu, A.G. Rinzler, H. Dai, J.H. Hafner, R.K. Bradley, P.J. Boul, A. Lu, T. Iverson, K. Shelimov, C.B. Huffman, F. Rodriguez-Macias, Y.S. Shion, T.R. Lee, D.T. Colbert, and R.E. Smalley, Science 280, 1253 (1998).

    Article  CAS  Google Scholar 

  19. W.L. Suchanek, M. Yoshimura, and Y.G. Gogotsi, J. Mater. Res. 14, 322 (1999).

    Article  Google Scholar 

  20. R. Saito, G. Dresselhaus, and M.S. Dresselhaus, Physical Properties of Carbon Nanotube (Imperial College Press, London, United Kingdom, 1998).

    Book  Google Scholar 

  21. M.A. Pimenta, A. Marucci, S.D.M. Brown, M.J. Mathews, A.M. Rao, P.C. Eklund, R.E. Smalley, G. Dresselhus, and M.S. Dresselhaus, J. Mater. Res. 13, 2396 (1998).

    CAS  Google Scholar 

  22. M. Lamy de la Chapell, S. Lefrant, C. Journet, W. Maser, and P. Bernier, Carbon 36, 705 (1998).

    Article  Google Scholar 

  23. A.M. Rao, S. Bandow, E. Richter, and P.C. Eklund, Thin Solid Films 331, 141 (1998).

    Article  CAS  Google Scholar 

  24. M.J. Pelletier, Analytical Applications of Raman Spectroscopy, (Blackwell Science, Oxford, United Kingdom, 1999).

    Google Scholar 

  25. V. Ivanov, A. Fonseca, J.B. Nagy, A. Lucas, P. Lambin, D. Bernaerts, and X.B. Zhang, Carbon 33(12), 1727 (1995).

    Article  CAS  Google Scholar 

  26. Y.G. Gogotsi, J. Libera, and M. Yoshimura, J. Mater. Res. 15,2591 (2000).

    Article  CAS  Google Scholar 

  27. E. Osawa, Fullerene Sci. Technol., 7.N4, 637 (1999).

    Google Scholar 

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Authors and Affiliations

  1. Research Institute for Solvothermal Technology, 2217–43 Hayashi, 761-0301, Takamatsu, Kagawa, Japan

    S. Srikanta Swamy

  2. Center for Materials Design, Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagasuta, 2226-8503, Midori-ku, Yokohama, Japan

    Jose Maria Calderon-Moreno & Masahiro Yoshimura

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  1. S. Srikanta Swamy
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  2. Jose Maria Calderon-Moreno
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  3. Masahiro Yoshimura
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Swamy, S.S., Calderon-Moreno, J.M. & Yoshimura, M. Stability of single-wall carbon nanotubes under hydrothermal conditions. Journal of Materials Research 17, 734–737 (2002). https://doi.org/10.1557/JMR.2002.0106

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  • DOI: https://doi.org/10.1557/JMR.2002.0106

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