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Effect of LiYO2 on the synthesis and pressureless sintering of Y2SiO5

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Abstract

Y2SiO5 has potential applications as a high-temperature structural ceramic and environmental/thermal barrier coating. In this work, we synthesized single-phase Y2SiO5 powders utilizing a solid–liquid reaction method with LiYO2 as an additive. The reaction path of the Y2O3/SiO2/LiYO2 mixture with variation in temperatures and the role of the LiYO2 additive on preparation process were investigated in detail. The powders obtained by this method have good sinterability. Through a pressureless sintering process, almost fully dense Y2SiO5 bulk material was achieved with a very high density of 99.7% theoretical.

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References

  1. J. Warshaw, R. Roy: Crystal chemistry of rare earth sesquioxides, aluminates and silicates. Prog. Sci. Technol. Rare Earths 1, 203 1963

    Google Scholar 

  2. S.H. Shin, D.Y. Jeon, K.S. Suh: Emission band shift of the cathodoluminescence of Y2SiO5:Ce phosphor affected by its concentration. Jpn. J. Appl. Phys. 40, 4715 2001

    Article  CAS  Google Scholar 

  3. T. Bottger, Y. Sun, G.J. Reinemer, R.L. Core: Diode laser frequency stabilization to transient spectral holes and spectral diffusion in Er3+:Y2SiO5 at 1536 nm. J. Lumin. 94–95, 565 2001

    Article  Google Scholar 

  4. C. Deka, B. Chai, Y. Shimony, X. Zhang, E. Munin, M. Bass: Laser performance of Cr4+:Y2SiO5. Appl. Phys. Lett. 61, 2141 1992

    Article  CAS  Google Scholar 

  5. F.F. Lange, S.C. Singhal, R.C. Kuznicki: Phase relations and stability studies in the Si3N4–SiO2–Y2O3 pseudoternary system. J. Am. Ceram. Soc. 60, 249 1977

    Article  CAS  Google Scholar 

  6. L.J. Gauckler, H. Hohnke, T.Y. Tien: The system Si3N4–SiO2–Y2O3. J. Am. Ceram. Soc. 63, 35 1980

    Article  CAS  Google Scholar 

  7. E.M. Levin, C.R. Robbins, H.F. McMurdie: Phase Diagrams for Ceramists—1969 Supplement The American Ceramic Society, Inc. Columbus, OH 1969 Fig. 2388, p. 76

    Google Scholar 

  8. S. Wagner, H.J. Seifert, F. Aldinger: High-temperature reaction of C/C-SiC composites with ceramic coatings, in Proceedings of the 10th International Conference on Advan. in Mater. & Mater. Proc. (ICAMMP-2002) Tata McGraw-Hill, New Delhi, 2002 71

  9. Y. Ogura, M. Kondo, T. Morimoto, A. Notomi, T. Sekigawa: Oxygen permeability of Y2SiO5. Mater. Trans. 42, 1124 2001

    Article  CAS  Google Scholar 

  10. J.W. Nowok, J.P. Kay, R.J. Kulas: Thermal expansion and high-temperature phase transformation of the yttrium silicate Y2SiO5. J. Mater. Res. 16, 2251 2001

    Article  CAS  Google Scholar 

  11. J. Wang, S. Tian, G. Li, F. Liao, X. Jing: Preparation and x-ray characterization of low-temperature phases of R2SiO5 (R = rare earth elements). Mater. Res. Bull. 36, 1855 2005

    Article  CAS  Google Scholar 

  12. H.J. Seifert, S. Wagner, O. Fabrichnaya, H. Lukas, F. Aldinger, T. Ullmann, M. Schmucker, H. Schneider: Yttrium silicate coatings on chemical vapor deposition–SiC-precoated C/C–SiC: Thermodynamic assessment and high-temperature investigation. J. Am. Ceram. Soc. 88, 424 2005

    Article  CAS  Google Scholar 

  13. B. Matovic, G. Rixecker, F. Aldinger: Densification of Si3N4 with LiYO2 additive. J. Am. Ceram. Soc. 87, 546 2004

    Article  CAS  Google Scholar 

  14. B. Matovic, G. Rixecker, S. Boskovic, F. Aldinger: Effect of LiYO2 addition on sintering behavior and indentation properties of silicon nitride ceramics. Int. J. Mater. Res. 97, 1268 2006

    Article  CAS  Google Scholar 

  15. K. Fukuda, H. Matrubara: Anisotropic thermal expansion in yttrium silicate. J. Mater. Res. 18, 1715 2003

    Article  CAS  Google Scholar 

  16. S. Kim, T. Sanders: Thermodynamic modeling of phase diagrams in binary alkali silicate system. J. Am. Ceram. Soc. 74, 1833 1991

    Article  CAS  Google Scholar 

  17. I.A. Bondar, N.K. Koroleva ACerS–NIST Phase Equilibria Diagrams, CD-ROM database, V3.0.1 (ACS, Westerville, OH, 2004 Fig. 06576

    Google Scholar 

  18. Y. Zhou, A. Petric: Thermodynamic stability of the lithium zirconates and lithium yttrium. J. Phys. Chem. Solids 55, 493 1994

    Article  Google Scholar 

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Acknowledgments

This work was supported by the National Outstanding Young Scientist Foundation for Y.C. Zhou (Grant 59925208), Natural Sciences Foundation of China (Grants 50232040, 50302011, and 90403027), and The “863” Project.

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Correspondence to Yanchun Zhou.

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Sun, Z., Zhou, Y. & Li, M. Effect of LiYO2 on the synthesis and pressureless sintering of Y2SiO5. Journal of Materials Research 23, 732–736 (2008). https://doi.org/10.1557/JMR.2008.0085

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  • DOI: https://doi.org/10.1557/JMR.2008.0085

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