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Structural Studies of Submonolayers of Carbon Atoms on Graphite

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Submonolayer coverages of carbon adsorbed on highly-oriented pyrolytic graphite were examined by scanning tunneling microscopy under ultra-high vacuum condition. Linear carbon wires were found on atomically flat graphite surfaces. The wires had different thicknesses, from single atomic width to about lnm. The long wires extended to over several hundred nanometers. Two directions, graphite β-β direction and 30° rotated, were preferred for the long wire orientation. Parallel wire alignment, with several nanometers of inter-wire spacings were observed. Carbon particles, from 0.7 to 2 nm in diameter were found to be attached to the carbon wires. Particles from different wires formed parallel linear chains about perpendicular to the wire direction.

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References

  1. H. W. Kroto, J. R. Heath, S. C. O'Brien, R. F. Curl, and R. E. Smally, Nature318, 162 (1985)

    Article  CAS  Google Scholar 

  2. W. Krätschmer, L. D. Lamb, K. Forstiropoulos, and D. R. Huffman, Nature347, 354 (1990)

    Article  Google Scholar 

  3. H. W. Kroto, A. W. Allaf, and S.P. Balm, Chem. Rev.91,1213 (1991)

    Article  CAS  Google Scholar 

  4. S. Iijima, Nature354, 56 (1991)

    Article  CAS  Google Scholar 

  5. J. W. Mintmire, B. I. Dunlap, and C. T. White, Phys. Rev. Lett. B631, 68, 631 (1992)

    Google Scholar 

  6. D. Vanderbilt, and J. Tersoff, Phys. Rev. Lett.68, 511 (1992)

    Article  CAS  Google Scholar 

  7. E. A. Rohfing, D. M. Cox, and A. Kaldor, J. Chem. Phys.81,3322 (1984)

    Article  Google Scholar 

  8. E. A. Rohlfing, J. Chem. Phys.93, 7851 (1990)

    Article  CAS  Google Scholar 

  9. M. E. Geusic, M. F. Jarrold, J. T. Mcllrath, L. A. Bloomfield, R. R. Freeman, and W. L. Brown, Z. Phys. D3, 309 (1986)

    Article  CAS  Google Scholar 

  10. D. Tomanek, M. A. Schluter, Phys. Rev. Lett.67, 2331 (1991)

    Article  CAS  Google Scholar 

  11. K. Raghavachari and J. S. Binkley, J. Chem. Phys.87(4), 2191 (1987)

    Article  CAS  Google Scholar 

  12. D. H. Magers, R. J. Harrison, and R. J. Bartlett, J. Chem. Phys.84, 3284 (1986)

    Article  CAS  Google Scholar 

  13. D. W. Ewing and G. V. Preiffer, Chem. Phys. Lett.134,413 (1987)

    Article  CAS  Google Scholar 

  14. D. W. Ewing and G. V. Preiffer, Chem. Phys. Lett.86, 365 (1982)

    Article  CAS  Google Scholar 

  15. J. Bernholc and J. C. Philips, Phys. Rev. B33, 7395 (1986)

    Article  CAS  Google Scholar 

  16. D. Tomanek, S. G. Louie, H.J. Mamin, D. W. Albraham, R. E. Thomson, and E. Ganz, J. Clarke, Phys. Rev. B35, 7790 (1987)

    Article  CAS  Google Scholar 

  17. J. Xhie, K. Sattler, U. Muller, N. Venkateswaran, and G. Raina, Phy. Rev. B43, 8917 (1991)

    Article  CAS  Google Scholar 

  18. H. A. Mizes, and J. S. Foster, Science244, 559 (1989)

    Article  CAS  Google Scholar 

  19. T. R. Albrecht, H. A. Mizes, J. Nogami, S.I. Park, and C. F. Quate, Appl. Phys. Lett.52, 362 (1988)

    Article  CAS  Google Scholar 

  20. J. P. Rabe, M.Sano, D. Batchelder, and A. A. Kalatchev, J. Microsc. (Oxford)152, 573 (1988)

    Article  Google Scholar 

  21. M. Ge, K. Sattler, J. Xhie, and N. Venkateswaran, submitted for publication

Download references

Acknowledgement

Financial support from the Ollice 01 Technology Transfer and Economic Development (OTTED) of the University of Hawaii, from the research Council of University of Hawaii, and from the US National Science Foundation, grant No. DMR-9106304, is gratefully acknowledged.

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Ge, M., Sattler, K., Xhie, J. et al. Structural Studies of Submonolayers of Carbon Atoms on Graphite. MRS Online Proceedings Library 270, 109–113 (1992). https://doi.org/10.1557/PROC-270-109

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  • DOI: https://doi.org/10.1557/PROC-270-109

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