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Mechanical annealing of Cu-Si nanowires during high-cycle fatigue

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Abstract

Monotonic and cyclic tension-tension tests with an upper stress in the GPa regime have been performed on Cu-Si nanowires. The results show that the exceptional high strength of these nanomaterials is maintained or even improved upon cyclic loading. Post-mortem transmission electron microscopy gives insight in the microstructural evolution. Fatigue-induced grain growth correlates with an observed increase in compliance, the formation of dislocation networks, and an increase in tensile strength.

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References

  1. J.R. Greer, W.C. Oliver, and W.D. Nix: Size dependence in mechanical properties of gold at the micron scale in the absence of strain gradients. Acta Mater. 54, 1705 (2006).

    Article  CAS  Google Scholar 

  2. A. Sedlmayr, E. Bitzek, D.S. Gianola, G. Richter, R. Monig, and O. Kraft: Existence of two twinning-mediated plastic deformation modes in Au nanowhiskers. Acta Mater. 60, 3985 (2012).

    Article  CAS  Google Scholar 

  3. P.G. Sanders, J.A. Eastman, and J.R. Weertman: Elastic and tensile behavior of nanocrystalline copper and palladium. Acta Mater. 45, 4019 (1997).

    Article  CAS  Google Scholar 

  4. O. Kraft, P.A. Gruber, R. Monig, and D. Weygand: Plasticity in confined dimensions. Annu. Rev. Mater. Res. 40, 293 (2010).

    Article  CAS  Google Scholar 

  5. E. Arzt: Size effects in materials due to microstructural and dimensional constraints: a comparative review. Acta Mater. 46, 5611–5626 (1998).

    Article  CAS  Google Scholar 

  6. C. Peng, Y.J. Zhan, and J. Lou: Size-dependent fracture mode transition in copper nanowires. Small 8, 1889–1894 (2012).

    Article  CAS  Google Scholar 

  7. C. Schopf, M. Schamel, H.P. Strunk, and G. Richter: Ultrahigh strength single crystalline nanowhiskers grown by physical vapor deposition. Adv.Eng. Mater. 14, 975 (2012).

    Article  CAS  Google Scholar 

  8. E. Bitzek: Atomistic study of twinning in gold nanowhiskers. J. Solid Mech. Mater. Eng. 6, 99 (2012).

    Article  Google Scholar 

  9. S.R. Agnewand J.R. Weertman: Cyclic softening of ultrafine grain copper. Mater. Sci. Eng. A 244, 145 (1998).

    Article  Google Scholar 

  10. A.B. Witney, P.G. Sanders, J.R. Weertman, and J.A. Eastman: Fatigue of nanocrystalline copper. Scr. Metall. Mater. 33, 2025 (1995).

    Article  CAS  Google Scholar 

  11. R. Schwaiger, G. Dehm, and O. Kraft: Cyclic deformation of polycrystalline Cu film. Phil. Mag. 83, 693 (2003).

    Article  CAS  Google Scholar 

  12. B. Yang, C. Motz, W. Grosinger, and G. Dehm: Stress-controlled fatigue behaviour of micro-sized polycrystalline copper wires. Mater. Sci. Eng. A 515, 71 (2009).

    Article  Google Scholar 

  13. G. Khatibi A. Betzwar-Kotas, V. Groger, and B. Weiss: A study of the mechanical and fatigue properties of metallic microwires. Fatigue Fract. Eng. Mater. Struct. 28, 723 (2005).

    Article  CAS  Google Scholar 

  14. R. Hofbeck, K. Hausmann, B. Ilschner, and H.U. Kunzi: Fatigue of very thin copper and gold wires. Scr. Metall. 20, 1601 (1986).

    Article  CAS  Google Scholar 

  15. G.P. Zhang and Z.G. Wang: Fatigue of small-scale metal materials: from micro- to nano-scale, in Multiscale Fatigue Crack Initiation and Propagation of Engineering Materials: Structural Integrity and Microstructural Worthiness, edited by G.C. Sih (Springer, Netherlands, 2008), p. 275.

    Chapter  Google Scholar 

  16. H.A. Padilla and B.L. Boyce: A review of fatigue behavior in nanocrystalline metals. Exp. Mech. 50, 5 (2010).

    Article  CAS  Google Scholar 

  17. S.S. Brenner: Plastic deformation of copper and silver whiskers. J. Appl. Phys. 28, 1023 (1957).

    Article  CAS  Google Scholar 

  18. D. Kiener, W. Grosinger, G. Dehm, and R. Pippan: A further step towards an understanding of size-dependent crystal plasticity: in situ tension experiments of miniaturized single-crystal copper samples. Acta Mater. 56, 580 (2008).

    Article  CAS  Google Scholar 

  19. A.T. Jennings and J.R. Greer: Tensile deformation of electroplated copper nanopillars. Phil. Mag. 91, 1108 (2011).

    Article  CAS  Google Scholar 

  20. G. Richter, K. Hillerich, D.S. Gianola, R. Monig, O. Kraft, and C.A. Volkert: Ultrahigh strength single crystalline nanowhiskers grown by physical vapor deposition. Nano Lett. 9, 3048 (2009).

    Article  CAS  Google Scholar 

  21. S. Lee, J. Im, Y. Yoo, E. Bitzek, D. Kiener, G. Richter, B. Kim, and S.H. Oh: Reversible cyclic deformation mechanism of gold nanowires by twinning-detwinning transition evidenced from in situ TEM. Nat. Commun. 5, 3033 (2014).

    Article  Google Scholar 

  22. M. Schamel, C. Schopf, D. Linsler, S.T. Haag, L. Hofacker, C. Kappel, H. P. Strunk, and G. Richter: The filamentary growth of metals. Int. J. Mater. Res. 102, 828 (2011).

    Article  CAS  Google Scholar 

  23. S.T. Boles, A. Sedlmayr, O. Kraft, and R. Monig: In situ cycling and mechanical testing of silicon nanowire anodes for lithium-ion battery applications. Appl. Phys. Lett. 100, 243901 (2012).

    Article  Google Scholar 

  24. D.S. Gianola, A. Sedlmayr, R. Monig, C.A. Volkert, R.C. Major, E. Cyrankowski, S.A.S. Asif, O.L. Warren, and O. Kraft: In situ nanome-chanical testing in focused ion beam and scanning electron microscopes. Rev. Sci. Instrum. 82, 063901 (2011).

    Article  CAS  Google Scholar 

  25. R.E. Boroch, R. Mijller-Fiedler, J. Bagdahn, and P. Gumbsch: High-cycle fatigue and strengthening in polycrystalline silicon. Scr. Mater. 59, 936 (2008).

    Article  CAS  Google Scholar 

  26. Z.W. Shan, R.K. Mishra, S.A.S. Asif, O.L. Warren, and A.M. Minor: Mechanical annealing and source-limited deformation in submicrometrediameter Ni crystals. Nat. Mater. 7, 115 (2008).

    Article  CAS  Google Scholar 

  27. D. Zhang, J.-M. Breguet, R. Clavel, L. Philippe, I. Utke, and J. Michler: In situ tensile testing of individual Co nanowires inside a scanning electron microscope. Nanotechnology 20, 365706 (2009).

    Article  Google Scholar 

  28. H.B. Huang and F. Spaepen: Tensile testing of free-standing Cu.Ag and AI thin films and Ag/Cu multilayers. Acta Mater. 48, 3261 (2000).

    Article  CAS  Google Scholar 

  29. G.P. Zhang, C.A. Volkert, R. Schwaiger, P. Wellner, E. Arzt, and O. Kraft: Length-scale-controlled fatigue mechanisms in thin copper films. Acta Mater. 54, 3127 (2006).

    CAS  Google Scholar 

  30. U. Holzwarth and U. Essmann: Transformation of dislocation patterns in fatigued copper single crystals. Mater. Sci. Eng. A 164, 206 (1993).

    Article  Google Scholar 

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Acknowledgments

The authors thank Wenting Huang and Gunther Richter (Max Planck Institute for Intelligent Systems, Stuttgart, Germany) for preparation of the nanowires. This work has been supported by the Robert Bosch Foundation which is gratefully acknowledged. Furthermore, the work was supported by the Project Based Personnel Exchange Program between the China Scholarship Council (CSC) and the German Academic Exchange Service (DAAD).

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Correspondence to Reinhard Schneider.

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For supplementary material for this article, please visit http://dx.doi.org/10.1557/mrc.2014.18

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Ensslen, C., Kraft, O., Monig, R. et al. Mechanical annealing of Cu-Si nanowires during high-cycle fatigue. MRS Communications 4, 83–87 (2014). https://doi.org/10.1557/mrc.2014.18

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