Skip to main content
SpringerLink
Log in

Covalently interconnected and separated vanadosilicate shells

  • Articles
  • Published:
MRS Online Proceedings Library Aims and scope

Abstract

Four new compounds containing vanadosilicate clusters have been synthesized by hydrothermal reactions The clusters are derived from the [V18O42] Keggin cluster by substitution of V=O caps by Si2O(O,OH)2 species. In Cs9[(V15Si6O46(OH)2Cl)(V2O4)](H2O)6.2, 1, the [V15Si6O46(OH)2] cluster shells are covalently interconnected by VO4 tetrahedra to form an infinite layer. In ((CH3)4N)4[V15Si6O42(OH)6(H2O)](H2O)20, 2, and ((CH3)4N)4(V(H2O)6)2/3 [V15Si6O42(OH)6 (H2O)](H2O), 3, separated [V15Si6O42(OH)6] cluster shells are interlinked by hydrogen bonds to form frameworks with wide channel systems. The separated cluster shell in ((CH3)4N)4((CH3)2NH2)((CH3)2NH) [V14Si8O42(OH)8(HCO2)] (H2O)4.7, 4, has four Si2O(OH)2 species in a tetrahedral configuration. The 2D structure of 1 and 0D structures of 2-4 complement the known 1D and 3D structures formed from such vanadosilicate shells.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. T. Pope, Compr. Coord. Chem. II 4, 635 (2004).

    CAS  Google Scholar 

  2. C. L. Hill and G. C. White, Chem. Rev. 98, 1 (1998).

    Article  CAS  Google Scholar 

  3. X.-J. Kong, L.-S. Long, Z. Zheng, R.-B. Huang, and L.-S. Zheng, Acc. Chem. Res. 43, 201 (2009).

    Article  Google Scholar 

  4. D.-L. Long, R. Tsunashima, and L. Cronin, Angew. Chem., Int. Ed. 49, 1736 (2010).

    Article  CAS  Google Scholar 

  5. M. I. Khan, E. Yohannes, and R. J. Doedens, Angew. Chem., Int. Ed. 38, 1292 (1999).

    Article  CAS  Google Scholar 

  6. M. I. Khan, J. Solid State Chem. 152, 105 (2000).

    Article  CAS  Google Scholar 

  7. N. Mizuno, S. Uchida, and K. Uehara, Pure Appl. Chem. 81, 2369 (2009).

    Article  CAS  Google Scholar 

  8. A. Dolbecq, E. Dumas, C. R. Mayer, and P. Mialane, Chem. Rev. 110, 6009 (2010).

    Article  CAS  Google Scholar 

  9. T. Whitfield, X. Wang, and A. J. Jacobson, Inorg. Chem. 42, 3728 (2003).

    Article  CAS  Google Scholar 

  10. X. Wang, L. Liu, G. Zhang, and A. J. Jacobson, Chem. Commun. , 2472 (2001).

  11. A. Tripathi, T. Hughbanks, and A. Clearfield, J. Am. Chem. Soc. 125, 10528 (2003).

    Article  CAS  Google Scholar 

  12. M. R. S. A. Janjua, Z.-M. Su, W. Guan, A. Irfan, S. Muhammad, and M. Iqbal, Can. J. Chem. 88, 434 (2010).

    Article  CAS  Google Scholar 

  13. A. Mueller, R. Sessoli, E. Krickemeyer, H. Boegge, J. Meyer, D. Gatteschi, L. Pardi, J. Westphal, K. Hovemeier, R. Rohlfing, J. Doering, F. Hellweg, C. Beugholt, and M. Schmidtmann, Inorg. Chem. 36, 5239 (1997).

    Article  CAS  Google Scholar 

  14. V. M. F. Hammer, E. Libowitzky, and G. R. Rossman, Am. Mineral. 83, 569 (1998).

    Article  CAS  Google Scholar 

  15. E. Kahrovic, P. Orioli, B. Bruni, M. Di Vaira, and L. Messori, Inorg. Chim. Acta 355, 420 (2003).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Houston, Houston, TX, 77204-5003, USA

    Xiqu Wang, Lumei Liu & Allan J Jacobson

Authors
  1. Xiqu Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Lumei Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Allan J Jacobson
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, X., Liu, L. & Jacobson, A.J. Covalently interconnected and separated vanadosilicate shells. MRS Online Proceedings Library 1309, 25 (2011). https://doi.org/10.1557/opl.2011.105

Download citation

  • Published:

  • DOI: https://doi.org/10.1557/opl.2011.105

Search

Navigation