Abstract
The present paper describes an unconventional approach to fabricate superhydrophilic-superhydrophobic template on the TiO2 nanotube structured film by a combination of electrochemical anodization and photocatalytic lithography. Based on template with extreme wetting contrast, various functional nanostructures micropattern with high resolution have been successfully fabricated. The resultant micropattern has been characterized with scanning electron microscopy, optical microscopy, X-ray photoelectron spectroscopy. It is shown that functional nanostructures can be selectively grown at superhydrophilic areas which are confined by the hydrophobic regions, indicating that the combined process of electrochemically self-assembly and photocatalytic lithography is a very promising approach for constructing well-defined templates for various functional materials growth.
Similar content being viewed by others
References
R. Wang, K. Hashimoto, A. Fujishima, M. Chikuni, E. Kojima, A. Kitamura, M. Shimohigoshi, and T. Watanabe, Nature 388, 431 (1997).
K. Ichimura, S.K. Oh, and M. Nakagawa, Science 288, 1624 (2000).
Y.K. Lai, X.F. Gao, H.F. Zhuang, J.Y. Huang, C.J. Lin, and L. Jiang, Adv. Mater. 21, 3799 (2009).
X.F. Gao, and L. Jiang, Nature 432, 36 (2004).
A. Lafuma, and D. Quéré, Nat. Mater. 2, 457 (2003).
X.J. Liu, Q.A. Ye, B. Yu, Y.M. Liang, W.M. Liu, and F. Zhou, Langmuir 26, 12377 (2010).
A. Kumar, H.A. Biebuyck, N.L. Abbott, and G.M. Whitesides, J. Am. Chem. Soc. 114, 9188 (1992).
Y. Yang, Y.K. Lai, Q.Q. Zhang, K. Wu, L.H. Zhang, C.J. Lin, and P.F. Tang, Colloids Surf. B 79, 309 (2010).
Y.K. Lai, Y.C. Chen, Y.X. Tang, D.G. Gong, Z. Chen, and C.J. Lin, Electrochem. Commun. 11, 2268 (2009).
P.L. Jae, and M.S. Myung, J. Am. Chem. Soc. 126, 28 (2004).
S. Xu, and G.Y. Liu, Langmuir 13, 127 (1997).
X.T. Zhang, O. Sato, and A. Fujishima, Langmuir 20, 6065 (2004).
K. Teshima, H. Sugimura, A. Takano, Y. Inoue, and O. Takai, Chem. Vapor Depos. 11, 347 (2005).
K. Tadanaga, J. Morinaga, A. Matsuda, and T. Minami, Chem. Mater. 12, 590 (2000).
E. Balaur, J.M. Macak, L. Taveira, and P. Schmuki, Electrochem. Commun. 7, 1066 (2005).
J.C. Zhao, T.X. Wu, K.Q. Wu, K. Oikawa, H. Hidaka, and N. Serpone, Environ. Sci. Technol. 32, 2394 (1998).
Y.K. Lai, L. Sun, Y.C. Chen, H.F. Zhuang, C.J. Lin, and J.W. Chin, J. Electrochem. Soc. 153, D123 (2006).
H.F. Zhuang, C.J. Lin, Y.K. Lai, L. Sun, and J. Li, Environ. Sci. Technol. 41, 4735 (2007).
F.B. Li, and X.Z. Li, Appl. Catal. A 228, 15 (2002).
L. Sirghi, M. Nakamura, Y. Hatanaka, and O. Takai, Langmuir 17, 8199 (2001).
H. Yoshitake, T. Sugihara, and T. Tatsumi, Chem. Mater. 14, 1023 (2002).
T.R.B. Foong, Y.D. Shen, X. Hu, and A. Sellinger, Adv. Funct. Mater. 20, 1390 (2010).
V. Zwilling, M. Aucouturier, and E. Darque-Ceretti, Electrochim. Acta 45, 921 (1999).
D.W. Gong, C.A. Grimes, and O.K. Varghese, J. Mater. Res. 16, 3331 (2001).
Y.K. Lai, H.F. Zhuang, K.P. Xie, D.G. Gong, Y.X. Tang, L. Sun, C.J. Lin, and Z. Chen, New J. Chem. 34, 1335 (2010).
Y.K. Lai, J.Y. Huang, H.F. Zhuang, V.P. Subramaniam, Y.X. Tang, D.G. Gong, L. Sundar, L. Sun, Z. Chen, and C.J. Lin, J. Hazard. Mater. 184, 855 (2010).
Z.Q. Lin, Y.K. Lai, R.G. Hu, J. Li, R.G. Du, and C.J. Lin, Electrochim. Acta 55, 8717 (2010).
Y.K. Lai, L. Sun, C. Chen, C.G. Nie, J. Zuo, and C. J. Lin, Appl. Surf. Sci. 252, 1101 (2005).
Y.K. Lai, C.J. Lin, J.Y. Huang, H.F. Zhuang, L. Sun, and T. Nguyen, Langmuir 24, 3867 (2008).
Y.K. Lai, C.J. Lin, H. Wang, J.Y. Huang, H.F. Zhuang, and L. Sun, Electrochem. Commun. 10, 387 (2008).
R. Hu, C.J. Lin, and H.Y. Shi, J. Biomed. Mater. Res. Part A 80, 687 (2007).
H. Wang, C.J. Lin, and R. Hu, Appl. Surf. Sci. 255, 4074 (2009).
Y.K. Lai, J.Y. Huang, J.J. Gong, Y.X. Huang, C.L. Wang, Z. Chen, and C.J. Lin, J. Electrochem. Soc. 156, D480 (2009).
Y.K. Lai, H.F. Zhuang, L. Sun, Z. Chen, and C.J. Lin, Electrochim. Acta 54, 6536 (2009).
J.P. Lee, H.K. Kim, C.R. Park, G. Park, H.T. Kwak, S.M. Koo, and M.M. Sung, J. Phys. Chem. B 107, 8997 (2003).
Y.K. Lai, Z.Q. Lin, J.Y. Huang, L. Sun, Z. Chen, and C.J. Lin, New J. Chem. 34, 44 (2010).
K. Yasuda, J.M. Macak, S. Berger, A. Ghicov, and P. Schmuki, J. Electrochem. Soc. 154, C472 (2007).
Y.K. Lai, Z.Q. Lin, Z. Chen, J.Y. Huang, and C.J. Lin, Mater. Lett. 64, 1309 (2010).
Y.X. Huang, Y.K. Lai, L.X. Lin, L. Sun, and C.J. Lin, Acta Phys. -Chim. Sin. 26, 2057 (2010).
Y.K. Lai, Y.X. Huang, J.Y. Huang, H. Wang, Z. Chen, and C.J. Lin, Colliods Surf. B 76, 117 (2010)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Lai, K.Y., Yang, Y., Huang, X.Y. et al. Wetting Pattern on TiO2 Nanostructure Films and its Application as a Template for Selective Materials Growth. MRS Online Proceedings Library 1316, 611 (2011). https://doi.org/10.1557/opl.2011.422
Published:
DOI: https://doi.org/10.1557/opl.2011.422