Skip to main content
Log in

Nonvolatile memory MOS capacitors made of CdSe embedded ZrHfO high-k gate dielectric

  • Published:
MRS Online Proceedings Library Aims and scope

Abstract

MOS capacitor composed of nc-CdSe embedded ZrHfO high-k gate dielectric stack was fabricated and characterized for nonvolatile memory functions. Detailed material and electrical properties have been investigated. With a large charge trapping capability, this kind of device can trap electrons or holes depending on the polarity and magnitude of the applied gate voltage. For the same stress time, the device trapped more holes than electrons under the same magnitude of gate voltage but different polarity. The negative differential resistance peak was observed at the room temperature due to the Coulomb blockade effect. The charge trapping mechanism was delineated with the constant voltage stress test. After 10 years of storage, about 56% of trapped charges still remain in the device.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S. Tiwari, F. Rana, H. Hanafi, A. Hartstein, E. F. Cabbe, and K. Chan, Appl. Phys. Lett. vol. 68, p. 1377, 1996.

    CAS  Google Scholar 

  2. C. H. Lin, Y. Kuo, J. Electrochem. Soc. vol. 158, H756, 2011.

    Article  CAS  Google Scholar 

  3. The International Technology Roadmap for Semiconductors. Semiconductor Industry Association, December 2003.

  4. Y. Kuo, J. Lu, S. Chatterjee, J. Yan, H. C. Kim, T. Yuan, W. Kuo, J. Paterson, and M. Gardner, Electrochem. Soc. Trans. vol. 1, p. 447, 2006.

    CAS  Google Scholar 

  5. J. Yan, Y. Kuo, and J. Lu, Electrochem. Solid-State Lett. vol. 10, H8199 2007.

    Google Scholar 

  6. J. J. Lee and D. L. Kwong, IEEE Trans. Electron Devices vol. 52, p. 507, 2005.

    Article  Google Scholar 

  7. C. C. Lin and Y. Kuo, J. Solid State Sci. and Technol. vol. 2, Q16, 2013.

    Article  CAS  Google Scholar 

  8. N. I. Dovgoshei, M. V. Shtilikha, and D. V. Chepur, Izvestiya VUZ. Fizika vol. 11, p. 132, 1968.

    CAS  Google Scholar 

  9. J. Hauser and K. Ahmed, Characterization and Metrology for ULSI Technology p. 235, AIP, New York 1998.

  10. N. Zhan, M. C. Poon, C. W. Kok, K. L. Ng, and H. Wong, J. Electrochem. Soc. vol. 150, F200, 2003.

    Article  CAS  Google Scholar 

  11. C. Morant, L. Galan, and J. M. Sanz, Surf. and Interface Anal. vol. 16, p. 304, 1990.

    Article  CAS  Google Scholar 

  12. M. H. Cho, Y. S. Roh, C. N. Roh, K. Roh, S. W. Nahm, D. H. Nahm, J. H. Lee, N. I. Lee, and K. Fujihara, Appl. Phy. Lett. vol. 81 p. 472, 2002.

    Article  CAS  Google Scholar 

  13. C. C. Lin and Y. Kuo, J. Vac. Sci. Technol. B vol. 31, p. 030605, 2013.

    Article  Google Scholar 

  14. J. E. B. Katari, V. L. Colvin, A. P. Alivisatos, J. Phys. Chem. vol. 98, p. 4109, 1994.

    Article  CAS  Google Scholar 

  15. X. S. Peng, J. Zhang, X. F. Wang, Y. W. Wang, L. X. Zhao, G. W. Meng, L. D. Zhang, Chem. Phys. Lett. vol. 343 p. 470, 2001.

    Article  CAS  Google Scholar 

  16. C. J. Vesely and D. W. Langer, Phys. Rev. B vol. 4, p. 451, 1971.

    Article  Google Scholar 

  17. C. H. Lin and Y. Kuo, Electrochem. Solid-State Lett. vol. 13, H83, 2010.

    Article  CAS  Google Scholar 

  18. C. H. Lin and Y. Kuo, J. Appl. Phys. vol. 110, p. 024101, 2011.

    Article  Google Scholar 

  19. J. Lu, C. H. Lin, and Y. Kuo, J. Electrochem. Soc. vol. 155, H386, 2008.

    Article  CAS  Google Scholar 

  20. M. Shalchian, J. Grisolia, G. Ben Assayag, H. Coffin, S. M. Atarodi, A. Claverie, Solid State Electronics. vol. 49, p. 1198, 2005.

    Article  CAS  Google Scholar 

  21. C. H. Yang, Y. Kuo, C. H. Lin, and W. Kuo, Mater. Res. Soc. Symp. Proc. vol. 1337, Q01, 2011.

    Article  Google Scholar 

  22. Y. Kuo, X. Liu, C. H. Yang, and C. C. Lin, Mater. Res. Soc. Symp. Proc. vol. 1430, p. 21, 2012.

    Article  Google Scholar 

  23. C. H. Yang, Y. Kuo, C. H. Lin, and W. Kuo, Electrochem. Solid-State Lett. vol. 14, H50, 2011.

    Article  CAS  Google Scholar 

  24. J. Lu, C. H. Lin, and Y. Kuo, J. Electrochem. Soc. vol. 155, H386, 2008.

    Article  CAS  Google Scholar 

  25. K. K. Likharev, Proc. IEEE vol. 87, p. 606, 1999.

    Article  CAS  Google Scholar 

  26. M. Shalchian, J. Grisolia, G. B. Assayag, H. Coffin, S. M. Atarodi, and A. Claverie, Solid-State Electronics vol. 49, p. 1198 2005.

    Article  CAS  Google Scholar 

  27. D. N. Kouvatsos, V. Ioannou-Souloeridis, and A. G. Nassiopoulou, Appl. Phys. Lett. vol. 82, p. 397, 2003.

    Article  CAS  Google Scholar 

  28. T. Hiramoto, H. Majima, M. Saitoh, Mater. Sci. and Eng. B vol. 101, p. 24, 2003.

    Article  Google Scholar 

  29. C. C. Lin and Y. Kuo, J. Solid State Sci. and Technol. vol. 2, Q16, 2013.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lin, CC., Kuo, Y. Nonvolatile memory MOS capacitors made of CdSe embedded ZrHfO high-k gate dielectric. MRS Online Proceedings Library 1562, 5 (2013). https://doi.org/10.1557/opl.2013.642

Download citation

  • Published:

  • DOI: https://doi.org/10.1557/opl.2013.642

Navigation