Abstract
The photoreduction of methylene blue (MB), in methylene blue sensitized gelatin (MBG) solutions and films, was studied for the first time with time-resolved laser spectroscopy. The dependence of the lifetime of the triplet state precursor was estimated by varying the pH, and the efficiency of this photoprocess was evaluated in solid thin films. This work constitutes the first step towards improving the holographic recording speed of MBG.
Similar content being viewed by others
References
T. Kubota, T. Ose, M. Sasaki, K. Honda: Hologram formation with red light in methylene blue sensitized dichromated gelatin. Appl. Opt. 25, 556 (1976)
A. Graube: Dye-sensitized dichromated gelatin for holographic optical element fabrication. Photo. Sci. Eng. 22, 37 (1978)
T. Kubota, T. Ose: Methods of increasing the sensitivity of methylene blue sensitized dichromated gelatin. Appl. Opt. 18, 2538 (1979)
C. Solano, R.A. Lessard, P.C. Roberge: Methylene blue sensitized gelatin as a photosensitive medium for conventional and polarizing holography. Appl. Opt. 26, 1989 (1987)
N. Capolla, R.A. Lessard: Processing of holograms recorded in methylene blue sensitized gelatin: Appl. Opt. 27, 3008 (1988)
N. Capolla, R.A. Lessard: Real-time bleaching of methylene blue or thionine sensitized gelatin. Appl. Opt. (in press)
N. Capolla, C. Carre, D.J. Lougnot, R.A. Lessard: Methylene blue sensitized gelatin: evidence of photodemethylation. Appl. Opt. 28, 4050 (1989)
J.P. Fouassier, D.J. Lougnot, J. Faure: Etude photophysique d'une série de cyanines; Partie 1: Processus d'évolution des états excités. J. Chim. Phys. 74, 23 (1977)
P.V. Kamat, N.N. Lichtin: Electron transfer in the quenching of protonated triplet methylene blue by ground state molecules of the dye. J. Phys. Chem. 85, 814 (1981)
M. Koisumi, H. Obata, S. Hayashi: Studies of the photoreduction of thiazine dyes in aqueous solutions. Bull. Chem. Soc. Jpn. 37, 108 (1964)
R.M. Danziger, K.H. Bar-Eli, K. Weiss: The laser photolysis of methylene blue. J. Phys. Chem. 71, 2633 (1967)
A.M. Braun, M.Y. Maurette, E. Oliveros: Technologie photochimique (Presses polytechniques romandes, Lausanne 1986) p. 27
C. Carre, D.J. Lougnot: A photochemical study in methylene blue/acrylamide system in view of its use for holographic recording under red illumination. J. Chim. Phys. 85, 485 (1988)
R. Bonneau: Application de la spectroscopie par éclairs à l'étude des propriétés physicochimiques des états excités des colorants thiaziniques et de quelques hydrocarbures aromatiques. Ph.D. thesis, Université de Bordeaux (1971)
C. Carre, C. Reichardt, D.J. Lougnot: Etude physicochimique d'une série de cyanines; Partie VII: Rendement en état triplet et photosensibilisation de l'oxygène singulet. J. Chim. Phys. 84, 577 (1987)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Capolla, N., Lessard, R.A., Carré, C. et al. Studies of the photoreduction of methylene blue in gelatin solutions and films with a view to improving the holographic recording process at 633 nm. Appl. Phys. B 52, 326–330 (1991). https://doi.org/10.1007/BF00325490
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00325490