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Free-radical intermediates in the electrochemical reduction of α,β derivatives of β-(5-nitro-2-furyl)-α-cyanoethylene

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

It was found by cyclic voltammetry and ESR that the excitation of the molecules of α,Β derivatives of Β-(5-nitro-2-furyl)-α-cyanoethylene in the radical-anion state by one-electron electrochemical reduction promotes chemical transformation of the other reaction centers, while preserving the nitrofuran group.

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Authors and Affiliations

  1. Institute of Organic Synthesis, Latvian Academy of Sciences, Riga

    R. A. Gavar, Ya. P. Stradyn', L. Kh. Baumane & K. Enish

  2. Central Institute of Organic Chemistry, Berlin Academy of Sciences, Berlin-Adlershof

    R. A. Gavar, Ya. P. Stradyn', L. Kh. Baumane & K. Enish

Authors
  1. R. A. Gavar
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  2. Ya. P. Stradyn'
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  3. L. Kh. Baumane
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  4. K. Enish
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1636–1639, December, 1991.

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Gavar, R.A., Stradyn', Y.P., Baumane, L.K. et al. Free-radical intermediates in the electrochemical reduction of α,β derivatives of β-(5-nitro-2-furyl)-α-cyanoethylene. Chem Heterocycl Compd 27, 1312–1315 (1991). https://doi.org/10.1007/BF00515575

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  • DOI: https://doi.org/10.1007/BF00515575

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