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Multi-conformational compounds with two absorbing groups

IV. 2-Fluoroacetaldehyde and 2-fluorocarbonyl compounds

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Abstract

The series of rotational isomers obtainable from 2-fluoroacetaldehyde has been studied by the CNDO/2 method and by an SCF-CI technique. Correlations concerning relative stabilities within the series, dipole moments, spectra and the transmission of electronic effects, are presented.

Zusammenfassung

Die Reihe von Rotationsisomeren, die man vom 2-Fluoracetaldehyd gewinnen kann, wurde mit Hilfe der CNDO/2-Methode und einer SCF-CI-Technik untersucht. ZusammenhÄnge, welche die relativen StabilitÄten innerhalb der Reihe sowie die Dipolmomente, Spektren und die Leitung elektronischer Effekte betreffen, werden dargelegt.

Résumé

On étudie la série des isomères rotationnels concevables pour le fluoro-2 acétaldehyde, par la méthode CNDO/2 et par une technique SCF-CI. Les calculs permettent d'établir des corrélations entre les stabilités relatives, les moments dipolaires, les spectres et la transmission des effets électroniques dans cette série.

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  1. Department of Organic Chemistry, Hebrew University, Jerusalem

    Amatzya Y. Meyer

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  1. Amatzya Y. Meyer
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Additional information

For part III, see Ref. [1].

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Meyer, A.Y. Multi-conformational compounds with two absorbing groups. Theoret. Chim. Acta 16, 226–238 (1970). https://doi.org/10.1007/BF00527567

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  • DOI: https://doi.org/10.1007/BF00527567

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