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Influence of the adsorption on the oxidation of oxalic acid on a gold electrode in acid media

Der Einfluß der Adsorption auf die Oxidation von Oxalsäure an der Goldelektrode in saurem Medium

  • Anorganische Und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary

The influence of an adsorption process on the oxidation of oxalic acid on a gold electrode has been analysed. To disclose this influence, different supporting electrolytes have been used with different adsorption of the anion (SO 2−4 , NO −3 and ClO −4 ). Moreover, it has been studied the modifications produced in the oxidation process by the presence of some species in solution with a strong adsorption (halides), but at low concentration levels.

Zusammenfassung

Um den Einfluß der Adsorption auf die Oxidation von Oxalsäure an der Goldelektrode in saurem Medium zu untersuchen, wurden Support-Elektrolyten mit verschiedener Anionenadsorption verwendet (SO 2−4 , NO −3 und ClO −4 ). Außerdem wurden Modifikationen des Oxidationsprozesses in der Gegenwart von stark adsorbierten Spezies, diese allerdings in geringen Konzentrationen, untersucht (Halogenide).

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References

  1. Crepy G., Lamy C., Maximovitch S. (1974) J. Electroanal. Chem.54: 161

    Google Scholar 

  2. Besenhard J. O., Parsons R., Reeves R. M. (1979) J. Electroanal. Chem.96: 57

    Google Scholar 

  3. Vazhev V. V., Mardashev Y. S. (1980) Electrokhimiya16: 1757

    Google Scholar 

  4. Clavilier J., Van Huong C. N. (1977) J. Electroanal. Chem.80: 101

    Google Scholar 

  5. Johnson J. W., Mueller S. C., James W. J. (1971) Trans. Faraday Soc.67: 2167

    Google Scholar 

  6. Vassiliev Yu. B., Sarghisyan S. A. (1986) Electrochim. Acta31: 645

    Google Scholar 

  7. Sarghisyan S. A., Vassiliev Yu. B. (1982) Electrokhimiya18: 845

    Google Scholar 

  8. Vassiliev Yu. B., Sarghisyan S. A. (1982) Electrokhimiya18: 961

    Google Scholar 

  9. Gaur J. N., Schmid G. M. (1970) J. Electroanal. Chem.24: 279

    Google Scholar 

  10. Cadle S. H., Bruckenstein S. (1973) J. Electroanal. Chem.48: 325

    Google Scholar 

  11. Herrera J., Castellano C. E., Calandra A. J., Arvia A. J. (1975) J. Electroanal. Chem.66: 207

    Google Scholar 

  12. Frankenthal R. P., Thompson D. E. (1976) J. Electrochem. Soc.123: 799

    Google Scholar 

Download references

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Authors and Affiliations

  1. Departament de Química física, Universitat de Barcelona, E-08028, Barcelona, Catalunya, Spain

    Rosa Albalat, Elvira Gómez, Maria Sarret & Elisa Vallés

Authors
  1. Rosa Albalat
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  2. Elvira Gómez
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  3. Maria Sarret
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  4. Elisa Vallés
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Albalat, R., Gómez, E., Sarret, M. et al. Influence of the adsorption on the oxidation of oxalic acid on a gold electrode in acid media. Monatsh Chem 120, 651–659 (1989). https://doi.org/10.1007/BF00809955

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  • DOI: https://doi.org/10.1007/BF00809955

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