Summary
-
1.
The IR spectra of triphenyloxonium, diphenylchloronium, diphenylbromonium, and diphenyliodonium compounds were investigated in the region of 750-400 cm−1.
-
2.
Differences were established in the spectral characteristics of triphenyloxonium and diphenylhalonium compounds with respect to the corresponding initial monohalobenzenes or diphenyl oxide.
-
3.
These data give no basis for ascribing a different molecular structure to borofluorides and halides of diphenylhaloniums.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
F. M. Beringer and I. Lillien, J. Amer. Chem. Soc.82, 5135 (1960).
A. N. Nesmeyanov, T. P. Tolstaya, and L. S. Isaeva, Dokl. AN SSSR,104, 872 (1955); A. N. Nesmeyanov and T. P. Tolstaya, Dokl. AN SSSR,105, 95 (1955);117, 626 (1957).
W. V. Mendlin, J. Amer. Chem. Soc.57, 1026 (1935).
T. L. Khotsyanova, Kristallografiya1, 524 (1956).
T. L. Khotsyanova and Yu. T. Struchkov, Kristallografiya1, 384 (1957).
Yu. T. Struchkov and T. O. Khotsyanova, Izv. AN SSSR, Otd. Khim. N.1960, 821.
M. R. Padhye and B. G. Viladkar, J. Sci. Ind. Res.188. 504 (1959).
R. R. Randle and D. H. Whiffen, Molecular Spectroscopy, Inst. of Petr., London (1955), p. 111.
D. H. Whiffen, J. Chem. Soc.1956, 350.
L. M. Épshtein and N. T. Yaroslavskii, Dokl. AN SSSR49, 865 (1963).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Nesmeyanov, A.N., Épshtein, L.M., Isaeva, L.S. et al. Infrared spectra of diphenylhalonium and triphenyloxonium salts in the region of 400–750 cm−1 . Russ Chem Bull 13, 574–577 (1964). https://doi.org/10.1007/BF00845298
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00845298