Conclusions
A study was made of the alkylation of isobutane with 1-butene, a mixture of n-butenes, isobutylene, and 2-methyl-2-butene in the presence of zeolite catalysts at 100° and a pressure of 20 atm. In contrast to acids, the alkylation of n-butanes with butylenes proceeds on zeolite catalysts. The “autoalkylation” reaction also takes place, the same as in the presence of acid catalysts.
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E. S. Mortikov, S. M. Zen'kovskii, N. V. Mostovoi, Kh. M. Minachev, N. F. Kononov, L. I. Golomshtok, and S. S. Kurdyumov, Khim. i Tekhnol. Topliv i Masel, 13 (1974).
J. E. Hofmann and A. Schriesheim, J. Am. Chem. Soc.,84, 957 (1962).
A. Z. Dorogochinskii, A. V. Lyuter, and E. G. Vol'pova, Sulfuric Acid Alkylation of Isoparaffins with Olefins [in Russian], Khimiya (1970), p. 142.
C. P. Cupit, J. E. Gwin, and E. C. Jernigan, Petroleum Management,33, 43, 54 (1961);34, 49, 58 (1962).
J. E. Hofmann, J. Org. Chem.,29, 1497 (1964).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1551–1554, July, 1974.
A. M. Dotsenko and s. S. Kurdyumov assisted in the work.
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Mortikov, E.S., Zen'kovskii, S.M., Mostovoi, N.V. et al. Alkylation of isoparaffin hydrocarbons with olefins on zeolite catalysts. Russ Chem Bull 23, 1469–1471 (1974). https://doi.org/10.1007/BF00929654
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DOI: https://doi.org/10.1007/BF00929654