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Asymmetric aminoacid synthesis by catalytic reduction of azlactones of substituted acylaminoacrylic acids Communication 17. Reaction of PdCl2 with S-(-)-α-phenylmethylamine under reducing conditions

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

When PdCl2 is reduced by hydrogen in the presence of S-(-)-α-phenylethylamine in chloroform, zero-valent complexes of Pd with S-(-)-α-phenylethylamine are formed. These are enantioselective catalysts for the reductive aminolysis of the azlactones of dehydroacyl-aminoacids.

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Literature cited

  1. E. I. Karpeiskaya, L. F. Godunova, E. S. Neupokoeva, and E. I. Klabunovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1104 (1978).

  2. E. I. Karpeiskaya, E. S. Neupokoeva, L. F. Godunova, I. P. Murina, A. P. Kharchevnikov, and E. I. Klabunovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1368 (1978).

  3. E. S. Neupokoeva, E. I. Karpeiskaya, L. F. Godunova, and E. I. Klabunovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 139 (1979).

  4. G. V. Chel'tsova, E. I. Karpeiskaya, L. N. Kaigorodova, and E. I. Klabunovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 65 (1983).

  5. I. É. Khatskevich, I. K. Kalnin', E. I. Karpeiskaya, and E. I. Klabunovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 366 (1983).

  6. E. S. Levitina, L. F. Godunova, E. I. Karpeiskaya, and E. I. Klabunovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1740 (1983).

  7. A. S. Berenblyum, A. G. Knizhnik, S. L. Mund, and I. I. Moiseev, Izv. Akad. Nauk SSSR, Ser. Khim., 1687 (1979).

  8. D. T. Clark, D. B. Adams, and D. Briggs, Chem. Commun., 602 (1971).

  9. V. I. Nefedov, I. A. Zakharova, I. I. Moiseev, M. A. Porai-Koshits, M. N. Vargaftik, and A. P. Melov, Zh. Neorg. Khim.,18, 3264 (1973).

    Google Scholar 

  10. C. H. Perry, D. P. Athans, E. F. Yong, I. R. Durig, and B. R. Mitchell, Spectrochim. Acta,23A, 1137 (1967).

    Google Scholar 

  11. R. I. Goodfellow and P. L. Goggin, J. Chem. Soc. A, 1897 (1967).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    E. I. Karpeiskaya, L. F. Godunova, E. S. Levitina, M. R. Lyubeznova, E. I. Klabunovskii, E. D. Lubuzh & A. I. Lutsenko

Authors
  1. E. I. Karpeiskaya
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  2. L. F. Godunova
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  3. E. S. Levitina
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  4. M. R. Lyubeznova
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  5. E. I. Klabunovskii
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  6. E. D. Lubuzh
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  7. A. I. Lutsenko
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 85–90, January, 1984.

The authors thank B. B. Lyusenbina for obtaining the RFE spectra, and A. V. Kucherov for the EPR study.

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Karpeiskaya, E.I., Godunova, L.F., Levitina, E.S. et al. Asymmetric aminoacid synthesis by catalytic reduction of azlactones of substituted acylaminoacrylic acids Communication 17. Reaction of PdCl2 with S-(-)-α-phenylmethylamine under reducing conditions. Russ Chem Bull 33, 73–78 (1984). https://doi.org/10.1007/BF00956233

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  • DOI: https://doi.org/10.1007/BF00956233

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