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Magnetic birefringence effect in solutions of paramagnetic substances. 5. Structure of adducts of certain α-epoxides and keto derivatives with Dy(III) dipivaloylmethanate

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Adduct formation of Dy(DPM)3 and Eu(DPM)3 with propylene oxide, 3-carene trans- and cis-oxides, cyclohexanone, d- and ℓ-camphor, ℓ-α-bromocamphor, and DMF has been studied using paramagnetic birefringence and polarimetry. The orientation of the chelate rings in Ln(DPM)3 and the composition and structure of the adducts formed were determined.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center, Academy of Sciences of the USSR, USSR

    I. R. Abdullin, S. G. Vul'fson, É. Kh. Kazakova & A. N. Vereshchagin

Authors
  1. I. R. Abdullin
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  2. S. G. Vul'fson
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  3. É. Kh. Kazakova
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  4. A. N. Vereshchagin
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Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1979–1985, September, 1991.

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Abdullin, I.R., Vul'fson, S.G., Kazakova, É.K. et al. Magnetic birefringence effect in solutions of paramagnetic substances. 5. Structure of adducts of certain α-epoxides and keto derivatives with Dy(III) dipivaloylmethanate. Russ Chem Bull 40, 1749–1754 (1991). https://doi.org/10.1007/BF00960397

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  • DOI: https://doi.org/10.1007/BF00960397

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