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57Fe- and119Sn-Mössbauer effect of oxide glasses

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Abstract

Coordination number of network-former (NWF) and formation of nonbridging oxygen (NBO) at the site neighboring to NWF can be estimated from Mössbauer measurements, since small amounts of Fe3+ and Sn4+ substitute NWF in several oxide glasses. Gamma-ray or thermal neutron irradiation of oxide glasses causes electron or charge transfer from oxygen to the Mössbauer ions, and the probability depends on the fraction of NBO. On the contrary, γ-ray irradiation of phosphate glasses results in oxidation of Fe2+ to Fe3+ since iron plays a role of network modifier (NWM) at interstitial sites. Debye temperature θD obtained from low-temperature Mössbauer measurements reflects the site occupation of Mössbauer ions in glasses. A linear relationship between glass transition temperature (T g ) and quadrupole splitting (Δ) of Fe3+,T g —Δ rule, is also effective for determining the site occupation of Mössbauer ions.

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  1. Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki, Higashiku, 812, Fukuoka, Japan

    T. Nishida

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Nishida, T. 57Fe- and119Sn-Mössbauer effect of oxide glasses. Journal of Radioanalytical and Nuclear Chemistry, Articles 182, 451–476 (1994). https://doi.org/10.1007/BF02037523

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