Abstract
The chemical behaviour of the95Nb atoms formed by the beta decay of the95Zr-Alizarin S and95Zr-TTA (2-thenoyltrifluoracetone) complexes were investigated. The retention values of95Nb which not complexed with organic reagents at working pH were determined. The values observed were 100% and 80%, respectively. The results are discussed and interpreted to explain the different behaviour on the basis of internal energy values and solvent effects.
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T. MUTO, H. EBIHARA, J. Inorg. Nucl. Chem., 43 (1981) 2617.
R. EDWARDS, T. DAVIES, Nucleonics, 2 (1976) 44.
S. WEXLER, Chemical Effect of Nuclear Transformations, Vol. 1 IAEA, 1961, p. 114.
A. CARLSON, Chemical Effects of Nuclear Transformations in Inorganic Systems, G. HARBOTTLE, A. G. MADDOCK (Eds), North Holland Publ., Amsterdam, 1979.
L. YAFFE, Nuclear Chemistry, Vol. 2. Academic Press, New York, 1968, p. 186.
K. SIEGBHAN, Alpha,- Beta,- and Gamma-Ray Spectroscopy, Vol 2, North Holland, Amsterdam, 1966.
A. HALPERN, G. STÖCKIN, Rad. Envir. Biophys. 14 (1977) 167.
S. WEXLER, G. ANDERSEN, L. SINGER, J. Phys. Chem., 32 (1960) 417.
B. ALIPRANDI, F. CACACE, A. GUARINO, Chemical Effects of Nuclear Transformations, Vol. 2, IAEA, 1965, p. 471.
I. KAPLAN, Nuclear Physics, Addison-Wesley, Publ. Inc., 1955.
D. L. BAULCH, J. F. DUNCAN, Proc. Conf. on Peaceful Uses of Atomic Energy Vol. 29, 1958, p. 400.
D. BAULCH, J. DUNCAN, F. THOMAS, Chemical Effects of Nuclear Transoformations, Vol. 2, IAEA, 1961, p. 169.
C. HSIUNG, A. A. GORDUS, Chemical Effects of Nuclear Transformations, Vol. 2, IAEA, 1965, p. 461.
H. MORIYAMA, Radiochim. Acta 34 (1983) 117.
T. SHIOKAWA, H. KUDO, T. OMORI, Bull. Chem. Soc. Japan, 38 (1965) 1340.
A. H. MYPNH et al.: Chemical Effects of Nuclear Transformations, Vol. 2, IAEA, 1961, p. 183.
F. BAUMGÄRTNER, Chemical Effects of Nuclear Transformations, Vol. 2, IAEA, 1965, p. 507.
E. LARSEN, S. HIROZAWA, J. Inorg. Nucl. Chem., 3 (1956) 198.
H. LIEBHAFSKY, E. WINSLOW, J. Am. Chem. Soc., 60 (1938) 1776.
E. B. SANDELL, Colorimetric Determinations of Traces of Metals Intersc. Publ. New York, 1959.
R. CONNICK, W. McVAY, J. Am. Chem. Soc., 71 (1949) 3182.
F. L. MOORE, Anal. Chem., 28 (1956) 997.
A. NICOLAS, A. TRIFONE, S. J. NASSIFF, Chemical Effects of Beta Decay in95Zr-Alizarin S System. XVII Congr. Arg. Qca. B. Blanca. Rep. Argentina, 1985.
J. G. MOORE, J. Inorg. Nucl. Chem., 20 (1961) 166.
R. B. HAHN, P. T. JOSEPH, G. SALCICCIOLI, Talanta 11 (1964) 747.
L. BROMAN, S. BOREVING, Arkiv Fys., 34 (1967) No. 23, 259.
C. M. LEDERER, V. S. SHIRLEY (Eds), Table of Isotopes 7th. ed. J. Wiley and Sons Inc., New York, 1978.
P. GLENTWORTH, C. L. WRIGHT, J. Inorg. Nucl. Chem., 31 (1969) 1263.
Nuclear Data Sheets 38, (1) 1983. Academic Press, Inc.
T. ASANO, S. OKADA, H. SAKAMOTO, S. TANIGUCHI, Y. KOBAYASHI, J. Inorg. Nucl. Chem., 36 (1974) 1433.
J. I. VARGAS, A. G. MADDOCK, Chemical Effects of Nuclear Transformations in Inorganic Systems, G. HARBOTTLE, A. G. MADDOCK (Eds), North Holland, Amsterdam, 1979. Chapt. 26.
M. HILLMAN, Chemical Effects of Nuclear Transformations in Inorganic Systems, G. HARBOTTLE, A. G. MADDOCK (Eds), North Holland, Amsterdam, 1979, Chapt. 25.
H. MÜLLER, Chemical Effects of Nuclear Transformations in Inorganic Systems, G. HARBOTTLE, A. G. MADDOCK (Eds), North Holland, Amsterdam, Chapt. 25, 1979.
W. F. LIBBY, Am. Chem. Soc., 69 (1947) 2523.
A. WAHL, N. BONNER, Radioactivity Applied to Chemistry. Chapt. 8, J. Wiley and Sons: Inc., New York, 1951.
P. GLENTWORTH, R. BETTS, Can. J. Chem., 39 (1961) 1049.
T. MUTO, H. EBIHARA, Radiochim. Acta, 39 (1985) 11.
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Nicolás, A.M., Trifone, A. & Nassiff, S.J. Chemical effects of β-decay in95Zr-Alizarin S and95Zr-TTA complexes. Journal of Radioanalytical and Nuclear Chemistry, Articles 125, 473–480 (1988). https://doi.org/10.1007/BF02041704
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DOI: https://doi.org/10.1007/BF02041704