Abstract
Ir(IV) chloride complexes in aqueous solutions are found to catalyze the oxidation of alkanes by chromic acid. The reaction is first order with respect to the hydrocarbon concentration. The rate of C−H bond oxidation increases in the series primary C−H<secondary C−H<tertiary C−H.
Abstract
Обнаружено, что хлоридные комплексы Ir(IV) в водных растворах ускоряют окисление алканов хромовой кислотой, являясь катализаторами процесса. Реакция, имеет первый порядок по концентрации углеводорода. Скорость окисления C−H связи увеличивается в ряду: перв. −C−H<втор. −C−H<трет. −C−H.
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References
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Arzamaskova, L.N., Romanenko, A.V. & Yermakov, Y.I. Oxidation of saturated hydrocarbons by chromic acid in the presence of Ir(IV) chloride complexes. React Kinet Catal Lett 13, 391–394 (1980). https://doi.org/10.1007/BF02065705
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DOI: https://doi.org/10.1007/BF02065705