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X-ray photoelectron study of the structure and composition of organometal cluster systems

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Abstract

This paper gives the results of the study of the structure and composition of copper- and cobalt-containing complex compounds synthesized using acetylacetone and triethyleneglycoldimethacrylate as complexons. It was established by X-ray photoelectron, IR, UV, and ESR spectroscopy that the cluster nuclei differ in size from each other by about a factor of three. When acetylacetonate is used as a complexon, the nature of the metal determines the character of interactions during structure formation of cluster systems. In the case of triethyleneglycoldimethacrylate, the character of metal-complexon interactions is determined from the variation of the X-ray photoelectron spectrum of oxygen.

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References

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Authors and Affiliations

  1. Department for Physical Chemistry and Mechanics of Polymers, Izhevsk State Technical University, USSR

    V. I. Kodolov, I. N. Shabanova, S. N. Babushkina, E. I. Chirkova & N. V. Keller

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  1. V. I. Kodolov
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  2. I. N. Shabanova
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  3. S. N. Babushkina
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  4. E. I. Chirkova
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  5. N. V. Keller
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Additional information

Translated fromZhumal Struktumoi Khimii, Vol. 39, No. 6, pp. 1107–1112, November–December, 1998.

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Kodolov, V.I., Shabanova, I.N., Babushkina, S.N. et al. X-ray photoelectron study of the structure and composition of organometal cluster systems. J Struct Chem 39, 912–916 (1998). https://doi.org/10.1007/BF02903604

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  • DOI: https://doi.org/10.1007/BF02903604

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