Abstract
High fluoride groundwater occurs in Maku area, in the north of West Azarbaijan province, northwest of Iran. Groundwater is the main source of drinking water for the area residents. Groundwater samples were collected from 72 selected points including 40 basaltic and 32 nonbasaltic springs and wells, in two stages, during June and August 2006. The areas with high fluoride concentrations have been identified, and the possible causes for its variation have been investigated. Regional hydrogeochemical investigation indicates that water-rock interaction is probably the main reason for the high concentration of ions in groundwater. The concentration of F− in groundwater is positively correlated with that of HCO3 − and Na+, indicating that groundwater with high HCO3 − and Na+ concentrations help to dissolve some fluoride-rich minerals. All of the water samples, collected from the basaltic areas do not meet the water quality standards for fluoride concentration and some other parameters. Hence, it is not suitable for consumption without any prior treatment. Inhabitants of the area that obtain their drinking water supplies from basaltic springs and wells are suffering from dental fluorosis. The population of the study area is at a high risk due to excessive fluoride intake especially when they are unaware of the amount of fluoride being ingested due to lack of awareness.
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References
American Public Health Association (1998) Standard method for the examination of water and wastewater. 17th edn. (Washington, DC)
Asghari Moghaddam A, Jomeiri R, Mohamadi A (2005) Investigation of hydrogeological characteristics of Maku area basaltic rocks for optimum groundwater management using geophysical, RS and GIS methods (report in Persian). University of Tabriz, Tabriz, Iran
Asghari Moghaddam A, Fijani E (2007) Hydrogeological and hydrochemical studies of Maku area basaltic and karstic aquifers in relation to geological formations (paper in persian). Sci Q J Geosci (in press)
Bell MC, Ludwig TG (1970) The supply of fluoride to man: ingestion from water. Fluoride and human health. WHO monograph series, Geneva: World Health Organization
Carrillo-Rivera JJ, Cardona A, Edmunds WM (2002) Use of abstraction regime and knowledge of hydrogeological conditions to control high-fluoride concentration in abstracted groundwater: San Luis Potosi basin, Mexico. J Hydrol 261:24–47
Chandra SJ, Thergaonkar VP, Sharma R (1981). Water quality and dental fluorosis. Ind J Public Health 25:47–51
Cruz JV, Amaral CS (2004) Major ion of groundwater from preched-water bodies of the Azores (Portugal) volcanic archipelago. Appl Geochem 19:445–459
Farooqi A, Masuda H, Firdous N (2007) Toxic fluoride and arsenic contaminated groundwater in the Lahore and Kasur districts, Punjab, Pakistan and possible contaminant sources. J Environ Pollut 145:839–849
Fetter CW (1988) Applied hydrogeology. 2nd edn. Charles E. Merrill, London, p 592
Gaciri SJ, Davies TC (1993) The occurrence and geochemistry of fluoride in some natural waters of Kenya. J of Hydrol 143:395–412
Gizaw B (1996) The origin of high bicarbonate and fluoride concentrations in waters of the main Ethiopian Rift Valley. J Afr Earth Sci 22:391–402
Guo Q, Wang Y, Ma T, Ma R (2007) Geochemical processes controlling the elevated fluoride concentration in groundwaters of the Taiyuan Basin, Northern China. J Geochem Explor 93:1–12
Gupta SK, Deshpande RD, Agarwal M, Raval BR (2005) Origin of high fluoride in groundwater in the North Gujarat-Cambay region, India. Hydrogeol J 13:596–605
Hounslow AW (1995) Water quality data: analysis and interpretation, CRC Press LLC, Lewis publishers, p 397 p
Jacks G, Bhattacharya P, Chaudhary V, Singh KP (2005) Controls on the genesis of high-fluoride groundwaters in India. Appl Geochem 20:221–228
Kim K, Jeong YG (2005) Factors influencing natural occurrence of fluoride-rich ground waters: a case study in the southeastern part of the Korean Peninsula. Chemosphere 58:1399–1408
Mahramanlioglu M, Kizilcikli I, Bicer IO (2002) Adsorption of fluoride from aqueous solution by acid treated spent bleaching earth. J Fluor Chem 115:41–47
Meenakshi RC (2006) Fluoride in drinking water and its removal. J Hazard Mater B137:456–463
Meenakshi VK, Garg, Kavita, Renuka, Anju Malik (2004) Groundwater quality in some villages of Haryana, India: focus on fluoride and fluorosis. J Hazard Mater 106B:85–97
Nanyaro JT, Aswathanarayana U, Mungere JS, Lahermo P (1984) A geochemical model for the abnormal fluoride concentrations in waters in parts of northern Tanzania. J Arf Earth Sci 2:129–140
Oruc N (2003) Problems of high fluoride waters in Turkey (hydrogeology and health aspects). The short course on medical geology-health and environment. Canberra, Australia
Tekle-Haimanot R, Melaku Z, Kloos H, Reiman C, Fantaye W, Zerihun L, Bjorvatn K (2006) The geographic distribution of fluoride in surface and groundwater in Ethiopia with an emphasis on the Rift Valley. J Sci Total Environ 367:182–190
Sorg TJ (1978) Treatment technology to meet the interim primary drinking water regulations for inorganics. J Am Water Works Assoc 70(2):105–111
Subba Rao N, John Devadas D (2003) Fluoride incidence in groundwater in an area of peninsular India. Environ Geol 45:243–251
Susheela A, Kumar AK, Bhatnagar M, Bahadur M (1993) Prevalence of endemic fluorosis with gastro-intestinal manifestations in people living in some north-Indian villages. Fluoride 26:97–104
Totsche KU, Wilcke W, Korbus M, Kobaza J, Zech W (2000) Evaluation of fluoride-induced metal mobilization in soil columns. J Environ Qual 29:454–459
Wang Y, Reardon EJ (2001) Activation and regeneration of a soil sorbent for defluoridation of drinking water. Appl Geochem 6:531–539
WHO (2006) Guidelines for drinking-water quality. First addendum to third edition, Volume 1, Recommendations. World Health Organization
Zhang B, Hong M, Zhao Y, Lin X, Zhang X, Dong J (2003) Distribution and risk assessment of fluoride in drinking water in the west plain region of Jilin Province, China. Environ Geochem Health 25:421–31
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The authors would like to thank Mike Streetly of ESI Ltd for reading the manuscript and making helpful comments
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Asghari Moghaddam, A., Fijani, E. Distribution of fluoride in groundwater of Maku area, northwest of Iran. Environ Geol 56, 281–287 (2008). https://doi.org/10.1007/s00254-007-1163-2
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DOI: https://doi.org/10.1007/s00254-007-1163-2