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Analysis of varying Gd3+ concentrations on the structure and optical properties of ZnAl2O4:0.1% Eu3+; x% Gd3+ (0 ≤ x ≤ 1.2) synthesized via citrate sol–gel method

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Abstract

We report the preparation of 0.1% Eu3+; x% Gd3+ (0 ≤ x ≤ 1.2) ZnAl2O4 phosphors using the citrate sol–gel method. X-ray diffraction (XRD) data revealed that all annealed samples consisted of the single phase of cubic ZnAl2O4 structure. The scanning electron microscopic (SEM) images indicated pronounced effect of dual doping on the surface morphology of the phosphor. The estimated crystal sizes estimated by the XRD was confirmed by the high-resolution transmission electron microscopy (HR-TEM) to be approximately around 20 nm. The photoluminescence (PL) spectroscopy results revealed four distinct emission peaks located at 393, 400, 578 and 618 nm. The peaks at around 393 and 400 nm were attributed to the defect levels located at different positions on the host material (ZnAl2O4). The emission peak at 578 and 618 nm were attributed to the 5D0 → 7F1 and 2D0 → 7F2 characteristic transition within the Eu3+ ions. The International Commission on Illumination (CIE) colour coordinates revealed that the emission colour was not influenced by varying the concentration of Gd3+.

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Acknowledgements

This work was supported by the South African National Research Foundation (NRF) Thuthuka programme (Fund number: UID99266) and NRF incentive funding for rated researchers (IPRR) (Grant no: 114924). The author would also like to acknowledge Mr. T.M Manamela for the sample synthesis and Dr James Wesley-Smith at Electron Microscopy Unit at Sefako Makgatho Health Science University for the SEM and TEM imaging.

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Authors and Affiliations

  1. Department of Physics, Sefako Makgatho Health Science University, PO Box 94, Medunsa, 0204, South Africa

    V. M. Maphiri & S. V. Motloung

  2. Department of Physics, National Institute of Technology Kurukshetra, Kurukshetra, Haryana, 136119, India

    Y. Dwivedi

  3. Department of Physics, University of the Free State (Qwaqwa Campus), Private Bag X13, Phuthaditjhaba, 9866, South Africa

    L. F. Koao

  4. Department of Physics, University of the Free State, PO Box 339, Bloemfontein, 9300, South Africa

    R. E. Kroon

  5. Department of Physics, Nelson Mandela University, PO Box 77000, Port Elizabeth, 6031, South Africa

    S. V. Motloung

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  1. V. M. Maphiri
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  2. Y. Dwivedi
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  3. L. F. Koao
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  4. R. E. Kroon
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  5. S. V. Motloung
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Correspondence to V. M. Maphiri or S. V. Motloung.

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Maphiri, V.M., Dwivedi, Y., Koao, L.F. et al. Analysis of varying Gd3+ concentrations on the structure and optical properties of ZnAl2O4:0.1% Eu3+; x% Gd3+ (0 ≤ x ≤ 1.2) synthesized via citrate sol–gel method. Appl. Phys. A 126, 73 (2020). https://doi.org/10.1007/s00339-019-3260-y

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