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Ecofriendly and efficient procedure for hetero-Michael addition reactions with an acidic ionic liquid as catalyst and reaction medium

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Abstract

1-Methylimidazolium trifluoroacetate ([Hmim]TFA) is reported as a cost-effective catalyst for a simple and environmentally benign hetero-Michael reaction. [Hmim]TFA works both as reaction medium and catalyst. The reaction is applicable to various aromatic sulfur and nitrogen nucleophiles. This method has advantages such as high yields, short reaction time, and simple workup. The catalyst could be recycled several times without any loss of activity.

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Acknowledgments

The authors would like to acknowledge financial support from the Research Council of Shahid Beheshti University.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Shahid Beheshti University, G. C., Evin, 1983963113, Tehran, Iran

    Minoo Dabiri, Mahboobeh Bahramnejad & Mostafa Baghbanzadeh

  2. Department of Phytochemistry, Medicinal Plants and Drugs Research Institute, Shahid Beheshti University, G. C., Evin, 1983963113, Tehran, Iran

    Peyman Salehi

Authors
  1. Minoo Dabiri
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  2. Peyman Salehi
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  3. Mahboobeh Bahramnejad
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  4. Mostafa Baghbanzadeh
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Correspondence to Minoo Dabiri or Peyman Salehi.

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Dabiri, M., Salehi, P., Bahramnejad, M. et al. Ecofriendly and efficient procedure for hetero-Michael addition reactions with an acidic ionic liquid as catalyst and reaction medium. Monatsh Chem 143, 109–112 (2012). https://doi.org/10.1007/s00706-011-0570-y

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  • DOI: https://doi.org/10.1007/s00706-011-0570-y

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