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High-efficiency ozone generation via electrochemical oxidation of water using Ti anode coated with Ni–Sb–SnO2

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Abstract

Ozone (O3) has been generated on Ni–Sb–SnO2/Ti electrode as anode immersed in acidic media at 25 °C by electrochemical process. The anode was electrochemically characterized by cyclic voltammetry and morphologically characterized by scanning electron microscopy (SEM) and X-ray diffraction. The concentration of dissolved ozone was determined by a UV/Vis spectrophotometer. The type of electrode with different times coating on the titanium mesh and different acid type and various concentrations (C acid) were used, and the stability of the electrode was investigated under the experimental conditions by SEM images. Results shows that higher efficiency (53.7%) for O3 generation by electrochemical oxidation of water were obtained in HClO4 (1 M) and an applied potential of 2.4 V vs. Ag/AgCl in 150 ml volume undivided electrochemical cell.

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References

  1. Arihara K, Terashima C, Fujishima A (2007) J Electrochem Soc 154:E71–E75

    Article  CAS  Google Scholar 

  2. Pichet P, Hurtubise C (1975) Proceedings of second international symposium on ozone technology, Montreal, Canada, 11–14 May, 1975

  3. Meng MX, Hsieth JJ (2000) Tappi J 83:67–72

    CAS  Google Scholar 

  4. Da Silva LM, De Faria LA, Boodts JFC (2003) Electrochim Acta 48:699–709

    Article  Google Scholar 

  5. Stucki S, Theis G, Kötz R, Devantay H, Christen H (1985) J Electrochem Soc 132:367–371

    Article  CAS  Google Scholar 

  6. Awad MI, Sata S, Kaneda K, Ikematsu M, Okajima T, Ohsaka T (2006) Electrochem Commun 8:1263–1269

    Article  CAS  Google Scholar 

  7. Santana MHP, De Faria LA, Boodts JFC (2004) Electrochim Acta 49:1925–1935

    Article  CAS  Google Scholar 

  8. Foller PC, Tobias W (1982) J Electrochem Soc 129:506–515

    Article  CAS  Google Scholar 

  9. Chernik AA, Drozdovich VB, Zharskii IM (1997) Russ J Electrochem 33:259–264

    CAS  Google Scholar 

  10. Wang YH, Cheng S, Chan KY, Li XY (2005) J Electrochem Soc 152:D197–D200

    Article  Google Scholar 

  11. Da Silva LM, De Faria LA, Boodts JFC (2001) Pure Appl Chem 73:1871–1884

    Article  Google Scholar 

  12. Tatapudi P, Fenton JW (1993) J Electrochem Soc 140:3527–3530

    Article  CAS  Google Scholar 

  13. Foller PC, Tobias W (1981) J Phys Chem 85:3238–3244

    Article  CAS  Google Scholar 

  14. Chen QY, Shi DD, Zhang YJ, Wang YH (2010) Water Sci Technol 62:2090–2095

    Article  CAS  Google Scholar 

  15. Lipp L, Pletcher D (1997) Electrochim Acta 42:1091–1099

    Article  CAS  Google Scholar 

  16. Christensen PA, Lin WF, Christensen H, Imkum A, Jin JM, Li G, Dyson CM (2009) Ozone Sci Eng 31:287–293

    Article  CAS  Google Scholar 

  17. Bader H, Hoigne J (1981) Water Res 15:449–456

    Article  CAS  Google Scholar 

  18. Awad MI, Saleh MM (2010) J Solid State Electrochem 14:1877–1883

    Article  CAS  Google Scholar 

  19. Cheng SA, Chan KY (2004) Electrochem Solid State Lett 7:D4–D6

    Article  CAS  Google Scholar 

  20. Fernando JB (2004) Ozone reaction kinetics for water and wastewater systems. Lewis, Boca Raton

    Google Scholar 

  21. Jolivet JP (2000) Metal oxide chemistry and synthesis: from solution to oxide. Wiley, New York

    Google Scholar 

  22. He D, Mho S (2004) J Electroanal Chem 568:19–27

    Article  CAS  Google Scholar 

  23. Michaud PA, Mahe E, Haenni W, Perret A, Comninellis Ch (2000) Electrochem Solid State Lett 3:77–79

    Article  CAS  Google Scholar 

  24. Michaud PA, Panniza M, Outattara L, Daiaco T, Foti G, Comninellis Ch (2003) J Appl Electrochem 33:151–154

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Faculty of Chemistry, Applied Chemistry Department, Bu-Ali Sina University, Hamedan, 65178, Iran

    Jalal Basiriparsa & Mahmoud Abbasi

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  1. Jalal Basiriparsa
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  2. Mahmoud Abbasi
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Correspondence to Jalal Basiriparsa.

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Basiriparsa, J., Abbasi, M. High-efficiency ozone generation via electrochemical oxidation of water using Ti anode coated with Ni–Sb–SnO2 . J Solid State Electrochem 16, 1011–1018 (2012). https://doi.org/10.1007/s10008-011-1440-6

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  • DOI: https://doi.org/10.1007/s10008-011-1440-6

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