Abstract
Synthesis and ion transport properties of hot-pressed solid polymer electrolytes (SPEs), (1−x) PEO: x KI, where x is the content of KI in wt%, are reported. A hot-press technique has been used for the formation of the polymeric membranes in place of the usual solution cast method. The composition (80 PEO:20 KI) was identified as the highest conducting polymer electrolyte on the basis of compositional dependent conductivity studies of PEO:KI films. A conductivity enhancement of more than two orders of magnitude from that of the pure PEO was achieved. Materials characterization and ion transport mechanism were explained by using various experimental techniques.
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Mahan, G.D. and Roth, W.L., “Superionic conductors”, Plenum Press, New York, 1976
Chandra, S., “Superionic solids-principal and applications”, North Holland, Amsterdam, 1981
Laskar, A.L. and Chandra, S., “Superionic solids and solid electrolytes-recent trends”, Academic Press, New York, 1989
Chowdary, B.V.R., “Solid state ionics-95”, North Holland, Amsterdam, 1995
Maier, J., “Solid state ionics-2000”, North Holland, Amsterdam, 2000
Badwal, S.P.S., “Solid State Ionics-2002”, North Holland, Amsterdam, 2002
Gray, F.M., “Polymer electrolytes”, Royal Society of Chemistry, Letchworth HN, 1997
Fenton, D.E., Parker J.M. and Wrigth, P.V., Polymer, 1973, 14: 589
Armand, M.B., Adv. Mat., 1990, 2: 278
Croce, F., Appetecchi, G.B., Persi, L. and Scrosati, B., Nature, 1998, 394: 456
Andreev, Y.G., Seneviratne, V., Khan, M., Henderson, W.A., Frech, R.E. and Bruce, P.G., Chem. Mater., 2005, 17: 767
Stoeva, Z., Litas, I.M., Staunton, E., Andreev, Y.G. and Bruce, P.G., J. Am. Chem. Soc., 2003, 125: 4619
Croce, F., Serraino-Fiory, F., Persi, L. and Scrosati, B., Electrochem. Solid-State Lett., 2001, 4: A121
Bhide, A. and Hariharan, K., J. Power Sources, 2006, 159: 1450
Appetecchi, G.B., Croce, F., Hasson, J., Scrosati, B., Salomon, M. and Cassel, F., J. Power Sources, 2003, 114: 105
Pandey, G.P., Hashmi, S.A. and Agrawal, R.C., Solid State Ionics, 2008, 179: 543
Chandra, A., Eur. Phys. J. Appl. Phys., 2010, 50: 21103
Agrawal, R.C. and Mahipal, Y.K., Int. J. Electrochem. Sci., 2011, 6: 867
Choudhary, S. and Sengwa, R.J., Indian J. Pure & Apply. Phys., 2011, 49: 204
Ahmad, S., Deepa, M. and Agnihotry, S.A., Sol. Energy Mater. Sol. Cells, 2008, 92: 184
Agrawal, R.C. and Chandra, A., J. Phys. D: Appl. Phys., 2007, 40: 7024
Chandra, A. and Chandra, A., “Hot-pressed solid polymer electrolytes: synthesis and characterization”, Lambert Academic Pub., Germany, 2010
Watanable, M., Sanui, K., Ogata, N., Kobayashi, T. and Ontaki, Z., J. Appl. Phys., 1985, 57: 123
Chandra, S., Tolpadi, S.K. and Hashmai, S.A., Solid State Ionics, 1988, 28–30: 651
Hashmi, S.A. and Chandra, S., Mater. Sci. Eng. B, 1995, 34: 18
Wen, S.J., Richrdson, T.J., Gantous, D.I., Striebel, K.A., Ross, P.N. and Cairns, E.J., J. Electroanal. Chem., 1996, 408: 113
Stephan, A.M., Kumar, T.P., Kulandainathan, M.A. and Lakshmi, N.A., J. Phys. Chem. B, 2009, 113: 1963
Dey, A., Karan, S. and De, S.K., Solid State Commu., 2009, 149: 1282
Chu, P.P., Reddy, J.M. and Kao, H.M., Solid State Ionics, 2003, 156: 141
Chandra, A., Chandra, A. and Thakur, K., Int. J. Appl. Phys., 2012, 2: 69
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The work was financially supported by DST, New Delhi through the ‘Fast Track Young Scientist Research Project’ (No. SR/FTP/PS-23/2009).
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Chandra, A., Chandra, A. & Thakur, K. Synthesis, characterization and ion transport properties of hot-pressed solid polymer electrolytes (1−x) PEO:x KI. Chin J Polym Sci 31, 302–308 (2013). https://doi.org/10.1007/s10118-013-1223-x
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DOI: https://doi.org/10.1007/s10118-013-1223-x