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Photo-induced living cationic copolymerization of isobutyl vinyl ether and vinyl ether with carbazolyl groups

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Abstract

In this work, a fluorescent monomer 2-(9-carbazolyl) ethyl vinyl ether (CEVE) was synthesized in our lab, and its photo-induced living cationic copolymerization behavior with isobutyl vinyl ether (IBVE) was investigated in detail using diphenyliodonium chloride (DPICl)/2,2-dimethoxy-2-phenylacetophenone (DMPA) and zinc bromide (ZnBr2) initiating system in dichloromethane solution at 5 °C, −5 °C, and −15 °C, respectively. The living nature of this copolymerization system was confirmed by adding fresh comonomer method after the copolymerization almost finished. In addition, the obtained fluorescent copolymer poly(IBVE-co-CEVE) has a low glass transition temperature (T g), below −10 °C.

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Authors and Affiliations

  1. Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, China

    Ming Li, Li-fen Zhang  (张丽芬), Mei-xia Tao, Zhen-ping Cheng  (程振平) & Xiu-lin Zhu

Authors
  1. Ming Li
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  2. Li-fen Zhang  (张丽芬)
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  3. Mei-xia Tao
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  4. Zhen-ping Cheng  (程振平)
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  5. Xiu-lin Zhu
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Corresponding authors

Correspondence to Li-fen Zhang  (张丽芬) or Zhen-ping Cheng  (程振平).

Additional information

This work was financially supported by the National Natural Science Foundation of China (Nos. 21174096, 21274100 and 21234005), the Project of International Cooperation of the Ministry of Science and Technology of China (No. 2011DFA50530), and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

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Li, M., Zhang, Lf., Tao, Mx. et al. Photo-induced living cationic copolymerization of isobutyl vinyl ether and vinyl ether with carbazolyl groups. Chin J Polym Sci 32, 1564–1574 (2014). https://doi.org/10.1007/s10118-014-1540-8

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  • DOI: https://doi.org/10.1007/s10118-014-1540-8

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