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Synthesis of poly[6-(2,6-bis(1′-methylbenzimidazolyl)pyridin-4-yloxy)hexyl acrylate] (PBIP) and magnetic property of its neodymium complex (PBIP-Nd3+)

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Abstract

Homopolymer (PBIP) containing 2,6-bis(1′-methylbenzimidazolyl)pyridine (MeBIP) ligands in the side chain was synthesized by RAFT polymerization and its kinetics was studied. Polymeric complex PBIP-Nd3+ was prepared by chelating PBIP with lanthanide ion Nd3+. The homopolymers and PBIP-Nd3+ complex were investigated by NMR, FTIR, GPC and TGA. The optical property of PBIP-Nd3+ complex was characterized by UV-Vis spectroscopy. The magnetic property of PBIP-Nd3+ complex was measured as a function of temperature (5 K to 300 K) and as a function of field (−3.98 × 106 A/m to 3.98 × 106 A/m). These results indicated that PBIP-Nd3+ complex is paramagnetic.

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Authors and Affiliations

  1. MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027, China

    Di-zheng Liu, Wei-lin Sun  (孙维林), Rong Ren, Yan-hua Wang & Zhi-quan Shen

Authors
  1. Di-zheng Liu
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  2. Wei-lin Sun  (孙维林)
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  3. Rong Ren
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  4. Yan-hua Wang
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  5. Zhi-quan Shen
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Corresponding author

Correspondence to Wei-lin Sun  (孙维林).

Additional information

This work was financially supported by the National Natural Science Foundation of China (No. 21174129).

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Liu, Dz., Sun, Wl., Ren, R. et al. Synthesis of poly[6-(2,6-bis(1′-methylbenzimidazolyl)pyridin-4-yloxy)hexyl acrylate] (PBIP) and magnetic property of its neodymium complex (PBIP-Nd3+). Chin J Polym Sci 34, 910–918 (2016). https://doi.org/10.1007/s10118-016-1804-6

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  • DOI: https://doi.org/10.1007/s10118-016-1804-6

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