Skip to main content
Log in

Effects of Pore on Thermal Diffusivity and Thermal Radiation Properties of C/SiC Composites at High Temperatures

  • Published:
Applied Composite Materials Aims and scope Submit manuscript

Abstract

The effects of pore in C/SiC composites on thermal diffusivity and thermal radiation properties were investigated systematically. Pores were introduced into C/SiC by oxidizing carbon phase at 700 °C and damaged the thermal properties of C/SiC composites. Because of little changes in the pore shape and the pore orientation in C/SiC, thermal diffusivity of samples increased linearly with porosity. The pores within C/SiC absorbed and reflected the radiated heat, decreasing spectral emissivity. However, the temperature dependence of spectral emissivity didn’t change by the pore. With measurement temperature increasing, the pores weakened the thermal radiation property of samples gradually. A linear relation was suggested to quantify the negative effect of pores on the total emissivity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Cheng, L., Xu, Y., Zhang, L., Luan, X.: Corrosion of a 3D-C/SiC composite in salt vapor environments. Carbon. 40, 877–882 (2002)

    Article  CAS  Google Scholar 

  2. Hatta, H., Aoki, T., Kogo, Y., Yarii, T.: High-temperature oxidation behavior of SiC-coated carbon fiber-reinforced carbon matrix composites. Compos. A: Appl. Sci. Manuf. 30, 515–520 (1999)

    Article  Google Scholar 

  3. Chiang, Y.: On fiber debonding and matrix cracking in fiber-reinforced ceramics. Compos. Sci. Technol. 61, 1743–1756 (2001)

    Article  CAS  Google Scholar 

  4. Liu, Y., Fu, Q.G., Guan, Y.W., Wang, B.B., Shen, Q.L.: Ablation behavior of sharp-shape C/C-SiC-ZrB2 composites under oxyacetylene flame. J. Alloy. Compd. 713, 19–27 (2017)

    Article  CAS  Google Scholar 

  5. Padture, N.P.: Advanced structural ceramics in aerospace propulsion. Nat. Mater. 15, 804–809 (2016)

    Article  CAS  Google Scholar 

  6. Padovano, E., Badini, C., Mergia, K., Barcena, J.: Thermophysical and radiative properties of pressureless sintered SiC and ZrB2-SiC laminates. Ceram. Int. 44, 15050–15057 (2018)

    Article  CAS  Google Scholar 

  7. Luan, X.G., Zhang, J., Cheng, L.: Effects of water vapor on corrosion behaviors of C/SiC in oxidizing atmosphere containing Na2SO4 vapor. Compos. Part B. 43, 2968–2972 (2012)

    Article  CAS  Google Scholar 

  8. Wang, F., Cheng, L., Liang, Sh.: Effects of microstructure defects on the internal friction of C/SiC composites. Mater. Sci.  Eng. A 750, 1–6 (2019)

  9. Chen, J., Wang, Y., Cheng, L., Zhang, L.: Thermal diffusivity of three-dimensional needled C/SiC–TaC composites. Ceram. Int. 37, 3095–3099 (2011)

    Article  CAS  Google Scholar 

  10. Cheng, L., Xu, Y., Zhang, Q., Zhang, L.: Thermal diffusivity of 3D C/SiC composites from room temperature to 1400 °C. Carbon. 41, 707–711 (2003)

    Article  CAS  Google Scholar 

  11. Tang, S., Deng, J., Wang, S., Liu, W.: Comparison of thermal and ablation behaviors of C/SiC composites and C/ZrB2-SiC composites. Corros. Sci. 51, 54–61 (2009)

    Article  CAS  Google Scholar 

  12. Farooqi, J.K., Sheikh, M.A.: Finite element modelling of thermal transport in ceramic matrix composites. Comput. Mater. Sci. 37, 361–373 (2006)

    Article  CAS  Google Scholar 

  13. Tawil, H., Bentsen, L., Baskaran, S., Hasselman, D.P.H.: Thermal diffusivity of chemically vapour deposited silicon carbide reinforced with silicon carbide or carbon fibres. J. Mater. Sci. 20, 3201–3212 (1985)

    Article  CAS  Google Scholar 

  14. McDonald, K.R., Dryden, J.R., Zok, F.W.: Effects of matrix cracks on the thermal diffusivity of a Fiber-reinforced ceramic composite. J. Am. Ceram. Soc. 84, 2015–2021 (2001)

    Article  CAS  Google Scholar 

  15. Youngblood, G.E., Senor, D.J., Jones, R.H., Graham, S.: The transverse thermal conductivity of 2D-SiCf/SiC composites. Compos. Sci. Technol. 62, 1127–1139 (2002)

    Article  CAS  Google Scholar 

  16. Alfano, D., Scatteia, L., Cantoni, S., Balat-Pichelin, M.: Emissivity and catalycity measurements on SiC-coated carbon fibre reinforced silicon carbide composite. J. Eur. Ceram. Soc. 29, 2045–2051 (2009)

    Article  CAS  Google Scholar 

  17. Wang, F.Y., Cheng, L.F., Zhang, Q., Zhang, L.T.: Effect of surface morphology and densification on the infrared emissivity of C/SiC composites. Appl. Surf. Sci. 313, 670–676 (2014)

    Article  CAS  Google Scholar 

  18. Wang, F.Y., Cheng, L.F., Xiang, L.Y., Zhang, Q., Zhang, L.T.: Effect of SiC coating and heat treatment on the thermal radiation properties of C/SiC composites. J. Eur. Ceram. Soc. 34, 1667–1672 (2014)

    Article  CAS  Google Scholar 

  19. Liu, Z., Sun, Q., Song, Y., Yang, J., Chen, X., Wang, H., Jiang, Z.: High-emissivity composite-oxide fillers for high temperature stable aluminum-chromium phosphate coating. Surf. Coat. Technol. 349, 885–893 (2018)

    Article  CAS  Google Scholar 

  20. Cheng, L., Xu, Y., Zhang, L., Yin, X.: Oxidation behavior from room temperature to 1500 °C of 3D C/SiC composites with different coatings. J. Am. Ceram. Soc. 85, 989–991 (2010)

    Article  Google Scholar 

  21. Mei, H., Zhang, D., Xia, J.C., Yu, C.K., Cheng, L.F.: The effect of hole defects on the oxidation behaviour of two-dimensional C/SiC composites. Ceram. Int. 42, 15479–15484 (2016)

    Article  CAS  Google Scholar 

  22. Filipuzzi, L., Naslain, R., Jaussaud, C.: Oxidation kinetics of SiC deposited from CH3SiCl3 /H2 under CVI conditions. J. Mater. Sci. 27, 3330–3334 (1992)

    Article  CAS  Google Scholar 

  23. Luo, R., Liu, T., Li, J., Zhang, H., Chen, Z., Tian, G.: Thermophysical properties of carbon/carbon composites and physical mechanism of thermal expansion and thermal conductivity. Carbon. 42, 2887–2895 (2004)

    Article  CAS  Google Scholar 

  24. Jia, Y., Li, K., Xue, L., Huang, L., Ren, J., Zhang, S.: Thermophysical properties of carbon fiber reinforced multilayered (PyC-SiC)(n) matrix composites. J. Eur. Ceram. Soc. 37, 3255–3261 (2017)

    Article  CAS  Google Scholar 

  25. Hu, L.F., Wang, C.A., Hu, Z.J., Lu, S., Sun, C.C., Huang, Y.: Porous yttria-stabilized zirconia ceramics with ultra-low thermal conductivity. Part II: temperature dependence of thermophysical properties. J. Mater. Sci. 46, 623–628 (2011)

    Article  CAS  Google Scholar 

  26. Han, Y., Li, C., Bian, C., Li, S., Wang, C.: Porous anorthite ceramics with ultra-low thermal conductivity. J. Eur. Ceram. Soc. 33, 2573–2578 (2013)

    Article  CAS  Google Scholar 

  27. Siegel, R., Howell, J.R.: Thermal Radiation Heat Transfer. Taylor & Francis, New York (2002)

    Google Scholar 

  28. Spitzer, W.G., Kleinman, D., Walsh, D.: Infrared properties of hexagonal silicon carbide. Phys. Rev. 113, 127–132 (1959)

    Article  CAS  Google Scholar 

  29. Xian, L., Tao, X., Dong, W., Xu, X., Guo, A., Liu, J., Du, H.: Gradient MoSi2-borosilicate glass high emissivity coating with enhanced contact and impact damage resistance. Ceram. Int. 44, 16333–16341 (2018)

    Article  CAS  Google Scholar 

  30. Zhao, C.Y., Lu, T.J., Hodson, H.P.: Thermal radiation in ultralight metal foams with open cells. Int. J. Heat Mass Tran. 47, 2927–2939 (2004)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors thank the support from the China Postdoctoral Science Foundation (No. 2018M643816XB).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Fuyuan Wang.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, F., Cheng, L. & Liang, S. Effects of Pore on Thermal Diffusivity and Thermal Radiation Properties of C/SiC Composites at High Temperatures. Appl Compos Mater 26, 1411–1422 (2019). https://doi.org/10.1007/s10443-019-09787-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10443-019-09787-1

Keywords

Navigation