Abstract
An amphiphilic peroxovanadium polyoxometalate {[C16H33N(CH3)3]5[PMo10V2O38(O2)2]} (abbreviated as C16PMo10V2(O2)2) was fabricated using surfactant and peroxovanadium polyoxometalate as precursors. It was used as a reverse-micellar catalyst for efficient oxidative desulfurization (ODS) using oxygen as an oxidant under mild conditions (atmospheric pressure, 70 °C). Dibenzothiophene removal could reach 98 % with sulfone 100 % selectivity for 4 h. The catalyst provided a means for improving reaction rates and easy recovery in ODS.
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The authors are grateful for the financial supported by the National Natural Science Foundation of China (51078066 and 20871026), the foundation of Jilin Provincial Environmental Protection Bureau (No. 200929).
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Tao, M., Zheng, H., Shi, J. et al. Oxidative Desulfurization by Oxygen Using Amphiphilic Quaternary Ammonium Peroxovanadium Polyoxometalates. Catal Surv Asia 19, 257–264 (2015). https://doi.org/10.1007/s10563-015-9197-z
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DOI: https://doi.org/10.1007/s10563-015-9197-z