Reaction of 5-dimethylaminotetrazolo[1,5-а][1,3,5]triazin-7-one tetrabutylammonium salt with allyl bromide in acetonitrile proceeds with the formation of 3-allyl-5-dimethylaminotetrazolo[1,5-a][1,3,5]triazin-7-one (N-alkylation), 6-allyloxy-4-azido-N,N-dimethyl-1,3,5-triazin-2-amine (O-alkylation), and 2-(1-allyl-1H-tetrazol-5-yl)-1,1-dimethylguanidine as the product of hydrolysis of N-alkylated tetrazolo[1,5-a][1,3,5]triazin-7-one. The structure of the reaction products was confirmed by IR, 1H and 13C NMR spectroscopy as well as elemental and X-ray structural analysis data.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2015, 51(8), 745–748
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Bakharev, V.V., Parfenov, V.E., Gidaspov, A.A. et al. Alkylation of 5-dimethylaminotetrazolo-[1,5-a][1,3,5]triazin-7-one. Chem Heterocycl Comp 51, 745–748 (2015). https://doi.org/10.1007/s10593-015-1768-4
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DOI: https://doi.org/10.1007/s10593-015-1768-4