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Synthesis of 1-arylsulfonyl-1,2,3-triazoles from (Z)-arylvinyl bromides by sequential elimination–cycloaddition reaction

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Chemistry of Heterocyclic Compounds Aims and scope

Efficient synthesis of 1-arylsulfonyl-1,2,3-triazoles from easily available (Z)-arylvinyl bromides is described. The sequential reaction involves elimination of HBr from (Z)-arylvinyl bromides promoted by KOH and copper-catalyzed (3+2) cycloaddition reaction between the alkyne intermediates and sulfonyl azides.

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This work was supported by Foundation of Henan Scientific and Technological Committee (No. 162300410270).

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Authors and Affiliations

  1. School of Science, Jiaozuo Teachers’ College, Shanyang Road 998, Jiaozuo, 454000, China

    Wensheng Zhang & Wenjing Xu

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  1. Wensheng Zhang
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  2. Wenjing Xu
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Correspondence to Wensheng Zhang.

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Published in Khimiya Geterotsiklicheskikh Soedinenii, 2016, 52(3), 192–195

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Zhang, W., Xu, W. Synthesis of 1-arylsulfonyl-1,2,3-triazoles from (Z)-arylvinyl bromides by sequential elimination–cycloaddition reaction. Chem Heterocycl Comp 52, 192–195 (2016). https://doi.org/10.1007/s10593-016-1859-x

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  • DOI: https://doi.org/10.1007/s10593-016-1859-x

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