Abstract
The interfacial fracture toughness of sintered hybrid silver nanoparticles (AgNPs) on both Au and Cu substrates is studied as a function of sintering temperature. Interfacial microstructure and porosity evolution of Au/AgNPs and Cu/AgNPs are observed to impact the fracture toughness. An Au–Ag interfacial diffusion layer is resolved at the interface of Au/AgNPs interconnects, while an oxide layer is found at the interface of Cu/AgNPs interconnects. Both porosity and pore sizes of the sintered silver interconnects are analyzed across the micro- and macro-length scales and related to the interfacial fracture toughness. The experimental observations can be theoretically described, which permits to predict the fracture toughness of the sintered silver interconnects.
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This study was funded by the National Natural Science Foundation of China (Nos. 11572249, 11772257) and the Alexander von Humboldt Foundation (Fellowship for Experienced Researchers).
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Wang, S., Kirchlechner, C., Keer, L. et al. Interfacial fracture toughness of sintered hybrid silver interconnects. J Mater Sci 55, 2891–2904 (2020). https://doi.org/10.1007/s10853-019-04212-1
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DOI: https://doi.org/10.1007/s10853-019-04212-1