Abstract
In the present work, the glass systems 0.70TeO2–0.30MO and 0.65TeO2–0.35MO (M = Ba, Sr) were prepared and characterized by X-ray diffraction, Fourier transform infrared spectroscopy, UV–vis spectroscopy and differential scanning calorimetry. The structural studies show that amorphous alkaline tellurite glasses are made up of vibrational units of molecular water group, hydroxyl bonding, symmetrical stretching vibration of Te–Oax bonds in the deformed TeO4 and stretching and bending vibration of Te–O–Te linkages in TeO4/TeO3 + d polyhedra/TeO3. In the X-ray diffractograms, shifting of amorphous peak was observed towards higher angle side with the strontium substitution in comparison to barium substitution due to lower ionic radii. The optical band gap of investigated glasses was found to lie in the range 2.94–3.31 eV and was found to be lower in SrO added glasses than that of BaO added glasses. This may be due to the presence of more number of non-bridging oxygen in Sr substituted glasses than Ba substituted glasses. The Ba substituted samples were observed to be denser than Sr substituted glasses. Ultrasonic longitudinal and sheer velocities were found in the range of 3160–3210 and 1785–1850 m/s, respectively and were observed to be higher in Ba substituted glasses. The ac conductivity spectra were found to follow Jonscher power law and conduction mechanism is governed by overlapping large polaron tunneling model created with non-bridging oxygen and Tellurium ions.
Similar content being viewed by others
References
C.R. Kesavulu, C.K. Jayasankar, J. Lumin. 132, 2802 (2012)
A. Chagraoui, Z. Ramzi, A. Tairi, A. Mandil, M. Talibouridah, K. Ajebli, Y. Abboud, Synthesis and characterization of new amorphous and crystalline phases in Bi2O3–SrO–TeO2 system. J. Mater. Process. Technol. 209, 3111–3116 (2009)
J.-C. Sabadel, P. Armand, F. Terki, J. Pelous, D. Cachau-Herreillat, E. Philippot, J. Phys. Chem. Solids 61, 1745–1750 (2000)
R.D. Shannon, C.T. Prewitt, Acta Crystallogr. B 25, 925–945 (1969)
K. Tanaka, T. Yoko, K. Kamiya, H. Yamada, S. Sakka, J. Non-Cryst. Solids 135, 211 (1991)
J. Dexpert-Ghys, B. Piriou, S. Rossignol, J.M. Reau, B. Tanguy, J.J. Videau, J. Portier, J. Non-Cryst. Solids 170, 167 (1994)
A. Pan, A. Ghosh, Activation energy and conductivity relaxation of sodium tellurite glasses. Phys. Rev B 59, 899–904 (1999)
S. Suresh, M. Prasad, V. Chandra Mouli, AC conductivity and impedance measurements in alkali boro-tellurite glasses. J. Non-Cryst. Solids 356, 1599–1603 (2010)
P.A. Jha, A.K. Yadav, P.K. Jha, P. Singh, AC conductivity and ion dynamics of alkaline earth metal substituted telluride glasses. J. Non-Cryst. Solids 452, 203–209 (2016)
A. Jha, B.D.O. Richards, G. Jose, T. Toney Fernandez, C.J. Hill, J. Lousteau, P. Joshi, Review on structural, thermal, optical and spectroscopic properties of tellurium oxide based glasses for fibre optic and waveguide applications. Int. Mater. Rev. 57, 357–382 (2012)
Z.A.S. Mahraz, M.R. Sahar, S.K. Ghoshal, Band gap and polarizability of boro-tellurite glass: influence of erbium ions. J. Mol. Struct. 1072, 238–241 (2014)
E.A. Davis, N. Mott, Conduction in non-crystalline systems V. Conductivity, optical absorption and photoconductivity in amorphous semiconductors. Phil. Mag. 22, 903–922 (1970)
V. Dimitrov, S. Sakka, J. Appl. Phys. 79, 1736 (1996)
C.R. Gautam, A.K. Yadav, A.K. Singh, A review on infrared spectroscopy of borate glasses with effects of different additives. ISRN Ceram. 2012, 1–17 (2012)
Y. Kawagucho et al., Moisture absorbing formed article. European Patent, EP 1788034A2, 23 May 2007
A.K. Yadav, P. Singh, RSC Adv 5, 67583–67609 (2015)
N.F. Mott, E.A. Davis, Electronic Processes in Non-Crystalline Materials, 2nd edn. (Clarendon Press, Oxford, 1979)
P.G. Pavani, K. Sadhana, V.C. Mouli, Optical, physical and structural studies of boro-zinc tellurite glasses. Phys B 406, 1242–1247 (2011)
J. Duffy, M. Ingram, An interpretation of glass chemistry in terms of the optical basicity concept. J. Non-Cryst. Solids 21, 373–410 (1976)
J. Duffy, M. Ingram, Establishment of an optical scale for lewis basicity in inorganic oxyacids, molten salts, and glasses. J. Am. Chem. Soc. 93, 6448–6454 (1971)
R.R. Reddy, Y.N. Ahammed, P.A. azeem, K.R. Gopal, T.V.R. Rao, Electronic polarizibility and optical basicity properties of oxide glasses through average electronegativity. J. Non-Cryst. Solids 286, 169–180 (2001)
J.A. Duffy, Chemical bonding in the oxides of the elements: a new appraisal. J. Solid State Chem. 62, 145–157 (1986)
V. Dimitrov, S. Sakka, Electronic oxide polarizability and optical basicity of simple oxides. I. J. Appl. Phys. 79, 1736 (1996)
B. Eraiah, Optical properties of samarium doped zinc–tellurite glasses. Bull. Mater. Sci. 29, 375–378 (2006)
A. Lagashetty, H. Vijayanand, S. Basavaraja, N.N. Mallikarjuna, A. Venkataraman, Lead adsorption study on combustion derived γ–Fe2O3 surface. Bull. Mater. Sci. 33, 1–6 (2010)
R. El Mallawany, The optical properties of tellurite glasses. J. Appl. Phys 72, 1774 (1992)
A. Ibanez, T. Ericsson, O. Lindqvist, D. Bazin, E. Philippot, J. Mater. Chem 4(7), 1101 (1994)
A.N. Begum, V. Rajendran, Structure investigation of TeO2–BaO glass employing ultrasonic study. Mater. Lett. 61, 2143–2146 (2007)
N. Manikandan, A. Ryasnyanskiy, J. Toulouse, J. Non-Cryst. Solids 358, 947–951 (2012)
E.R. Shaaban, Y.B. Saddeek, M. Abdel Rafe, Philos. Phenomenol. 89, 27–39 (2009)
M.A.P. Silva, Y. Messaddeq, S.J.L. Ribeiro, M. Poulain, F. Villain, V. Briris, J. Phys. Chem. Solids 62, 1055 (2001)
T. Sekiya, N. Mochida, A. Otsuka, J. Non-Cryst. Solids 168, 106 (1994)
B.V.R. Chowdari, R. Gopalakrishnan, J. Non-Cryst. Solids 105, 269 (1988)
B. Bridge, N.D. Patel, D.N. Waters, On the elastic constants and structure of the pure inorganic oxide glasses. Phys. Status Solidi A 77(2), 655–668 (1983)
A.K. Jonsher, Nature 267, 673 (1977)
S.R. Elliot, A.C. Conduction in amorphous chalcogenide and pnictide semiconductors. Adv. Phys. 36, 135–217 (1987)
A.K. Yadav, P.A. Jha, S. Murugavel, P. Singh, Synthesis, characterization and AC conductivity of alkali metal substituted telluride glasses. Solid State Ion. 296, 54–62 (2016)
A.K. Yadav, P. Singh, Impedance spectroscopic studies of mixed alkali telluride glasses. J. Mater. Sci. Mater. Electron. 26, 9443–9450 (2015)
H. Inaba, H. Tagawa, Ceria based Solid electrolytes. Solid State Ion. 83, 1–16 (1996)
F.M. Ezz Eldin, N.A. EI Alaily, Electrical Conductivity of some alkali silicate glasses. Mater. Chem. Phys. 52, 175–179 (1998)
Acknowledgements
The authors are gratefully acknowledging to the CSIR, New Delhi, (India) for financial support under project No. 03(1300)/13/EMR-II.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Yadav, A.K., Jha, P.A. & Singh, P. A comparative of structural, optical, mechanical and electrical properties of alkaline earth metal substituted tellurite glasses. J Mater Sci: Mater Electron 28, 7419–7428 (2017). https://doi.org/10.1007/s10854-017-6431-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-017-6431-7