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Synthesis and Characterization of Cu–Mn Substituted SrFe12O19 Hexaferrites

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Abstract

In this study, bimetallic (Cu–Mn) substituted SrFe12O19 hexaferrites [Sr1−2xMnxCuxFe12O19 (0.0 ≤ x ≤ 0.1)] were synthesized via sol–gel auto-combustion approach. The effect of bimetallic substitution on structure, morphology and magnetism of SrFe12O19 was investigated. SEM images divulge the nano-size of the prepared products with speck morphology. X-ray powder diffraction analysis affirmed their complete conversion to SrFe12O19 hexagonal crystal phase. The results from 57Fe Mössbauer suggested that all five important sextets of Sr1−2xMnxCuxFe12O19 hexaferrites effected due to the substitution of Cu and Mn ions. Cation distribution calculation showed that as the percentage of Mn and Cu increased in Sr1−2xMnxCuxFe12O19 (0.0 ≤ x ≤ 0.1), particularly for x = 0.03 the relative area of 12k and 4f2 site increased. This indicates that Fe ions are migrated towards 12k and 4f2 octahedral site.

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Acknowledgements

Prof. Baykal acknowledges the University of Dammam for their research facilities and support.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Engineering, Istanbul University, Avcilar, 34320, Istanbul, Turkey

    Md. Amir

  2. Department of Nano-Medicine Research, Institute for Research & Medical Consultations (IRMC), University of Dammam, P. O. Box 1982, Dammam, 31441, Saudi Arabia

    A. Baykal, S. Asiri & I. Ercan

  3. Department of Physics, Hitit University, ÇevreYolu, 19030, Bulvarı-Çorum, Turkey

    H. Gungunes

  4. School of Materials Science and Engineering, The University of New South Wales, Sydney, NSW, 2052, Australia

    S. E. Shirsath

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Amir, M., Baykal, A., Gungunes, H. et al. Synthesis and Characterization of Cu–Mn Substituted SrFe12O19 Hexaferrites. J Inorg Organomet Polym 28, 212–222 (2018). https://doi.org/10.1007/s10904-017-0691-9

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  • DOI: https://doi.org/10.1007/s10904-017-0691-9

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